Automatic graphite digestion and inductively coupled plasma massspectrometry for monitoring lead, arsenic, aluminum, chromium, iron, andcopper in dried aquatic products

  • ZHANG Hongyan ,
  • DING Wu ,
  • WU Fuxiang ,
  • WANG Xiaoqiao ,
  • LIU Xiaoxiao ,
  • MIAO Qian ,
  • ZHANG Jie
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  • 1(Lanzhou Food and Drug Inspection Institute, Lanzhou 730050,China)
    2(Northwest Agricultural and Forestry University of Science and Technology,Yangling 712100,China)

Received date: 2018-03-15

  Online published: 2019-03-11

Abstract

This study aimed to establish a method that uses inductively coupled plasma mass spectrometry (ICP-MS) to simultaneously determine lead, arsenic, aluminum, chromium, iron, and copper in dried aquatic products. Samples were digested in automatic graphite digestion, followed by quantitative tests using internal standard method by ICP-MS. The results showed that the concentrations of lead, arsenic, aluminum, chromium, iron, and copper showed good linear relationships in the range of 0.25-25 μg/L, with correlation coefficients (R2) higher than 0.990. The detection limits for lead,arsenic,aluminum,chromium,iron,and copper were 0.02 μg/L, 0.08 μg/L, 0.12 μg/L, 0.10 μg/L, 0.03 μg/L, and 0.05 μg/L, respectively. The recovery rate was 84.0%-108.4%. The relative standard deviation of reproducibility was less than 10% (n=6). This method was proved to be simple, accurate, with low detection limits and good reproducibility, which can be used to detect metals in dried aquatic products.

Cite this article

ZHANG Hongyan , DING Wu , WU Fuxiang , WANG Xiaoqiao , LIU Xiaoxiao , MIAO Qian , ZHANG Jie . Automatic graphite digestion and inductively coupled plasma massspectrometry for monitoring lead, arsenic, aluminum, chromium, iron, andcopper in dried aquatic products[J]. Food and Fermentation Industries, 2019 , 45(3) : 266 -269 . DOI: 10.13995/j.cnki.11-1802/ts.017281

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