Analysis of aroma components in different satsuma juices by HS-SPME-GC-MS combined with multivariate statistical methods

  • ZHOU Qi ,
  • YI Xin ,
  • OUYANG Zhu ,
  • LI Guijie ,
  • ZHU Xiajian ,
  • FAN Jiaying ,
  • LI Zeling ,
  • TAN Anqun ,
  • HUANG Linhua ,
  • WANG Hua
Expand
  • 1(Citrus Research Institute, Southwest University, Chinese Academy of Agricultural Sciences, Chongqing 400712, China)
    2(Chongqing Collaborative Innovation Center for Functional Food, Chongqing University of Education, Chongqing 400067, China)

Received date: 2020-02-03

  Online published: 2020-06-17

Abstract

A total of 18 satsumas were extracted from the especial-early, early, medium and late-ripening varieties. The aroma components of juice were qualitatively and quantitatively analyzed by using headspace solid phase microextraction-gas chromatography-mass spectrometry (HS-SPME-GC-MS) and principal component analysis (PCA) was used to compare and distinguish. Results showed that a total of 60 aroma components were detected in 18 kinds of satsuma juice, and 29 characteristic aroma was determined according to the odor activity value (OAV), among which the number and content of aroma component in 2003-4 Wenzhoumigan were the highest. The analysis showed that allo-ocimene, trans-2-hexenal, L-carvone, dodecanal, perilla aldehyde, β-citronellol and thyme camphor are characteristic components of a few varieties. The distribution of characteristic aroma components in different kinds of satsuma is characteristic, which can be amplified by principal component analysis. Hence, 2003-4 Wenzhoumigan and Ninghong 73-19 Wenzhoumigan have better aroma compositions than other varieties, but the quality of their juice is also influenced by factors such as producing area,cultivation and weather.

Cite this article

ZHOU Qi , YI Xin , OUYANG Zhu , LI Guijie , ZHU Xiajian , FAN Jiaying , LI Zeling , TAN Anqun , HUANG Linhua , WANG Hua . Analysis of aroma components in different satsuma juices by HS-SPME-GC-MS combined with multivariate statistical methods[J]. Food and Fermentation Industries, 2020 , 46(10) : 248 -254 . DOI: 10.13995/j.cnki.11-1802/ts.023501

References

[1] 沈兆敏. 世界柑橘生产的变化及对我国柑橘发展的启示[J]. 果农之友, 2018(9):1-4.
[2] 沈勇根, 朱凤妮, 卢剑青, 等. 宽皮柑橘品质特性及加工适性研究进展[J]. 江西农业大学学报, 2017,39(4):669-677.
[3] 成传香, 王鹏旭, 贾蒙, 等. 三个中国主栽宽皮柑橘品种制汁品质评价[J]. 食品与发酵工业,2019,45(24):173-178.
[4] 金润楠, 李子函, 赵开丽, 等. 基于气质联用的不同产地温州蜜柑香气成分比较分析[J]. 食品与发酵工业,2020,46(2):252-260.
[5] 吴曲阳. 不同品种宽皮柑橘果汁特征香气成分研究[D]. 上海:上海应用技术大学, 2017.
[6] CHOI Y, KIM S S, PARK K J. Changes in volatile components of satsuma mandarin(Citrus unshiu Marc.) fruit during ripening stages in Korea[J]. Hortscience, 2019,54S(9):214.
[7] CUEVAS F J, PEREIRA-CARO G, MORENO-ROJAS J M, et al. Assessment of premium organic orange juices authenticity using HPLC-HR-MS and HS-SPME-GC-MS combining data fusion and chemometrics[J]. Food Control, 2017,82:203-211.
[8] YU Y, BAI J, CHEN C, et al. Comparative analysis of juice volatiles in selected mandarins, mandarin relatives and other citrus genotypes[J]. Journal of the science of food and agriculture, 2018,98(3):1 124-1 131.
[9] DREHER J G, ROUSEFF R L, NAIM M. GC-olfactometric characterization of aroma volatiles from the thermal degradation of thiamin in model orange juice[J]. Journal of Agricultural and Food Chemistry, 2003,51(10):3 097-3 102.
[10] 王珺, 黄林华, 马亚琴, 等. 杀菌方式对酶法去皮全果橙汁挥发性风味的影响[J]. 食品与发酵工业, 2017,43(2):122-128.
[11] SHUI M, FENG T, TONG Y, et al. Characterization of key aroma compounds and construction of flavor base module of Chinese sweet oranges[J]. Pubmed,2019,24(13):238 413.
[12] 郭莉, 吴厚玖, 王华, 等. 加工单元操作对血橙汁香气成分的影响[J]. 食品科学, 2015,36(24):137-141.
[13] GENEVA N U C U. Flavor net and human odor space[EB/OL]. http://www.flavornet.org/flavornet.html.
[14] XIAO Z, WU Q, NIU Y, et al. Characterization of the key aroma compounds in five varieties of mandarins by gas chromatography-olfactometry, odor activity values, aroma recombination, and omission analysis[J]. Journal of Agricultural and Food Chemistry, 2017,65(38):8 392-8 401.
[15] 冯桂蓉, 谢姣, 邓丽莉, 等. 柑橘果实萜烯类挥发性物质研究进展[J]. 食品与机械, 2017,33(10):200-204.
[16] 成传香, 王鹏旭, 贾蒙, 等. 基于GC-MS结合多元统计方法分析不同种类柑橘汁中香气物质[J]. 食品与发酵工业,2019,45(21):236-243.
[17] 陈光静, 郑炯, 丁涌波, 等. 顶空-固相微萃取-气相色谱-质谱联用结合嗅闻法分析异味薏米的异味成分[J]. 食品与发酵工业, 2018,44(1):230-237.
[18] BAZEMORE R, GOODNER K, ROUSEFF R. Volatiles from unpasteurized and excessively heated orange juice analyzed with solid phase microextraction and GC-olfactometry[J]. Journal of Food Science, 1999,64(5):800-803.
[19] PLOTTO A, MARGARIA C A, GOODNER K L, et al. Odour and flavor thresholds for key aroma components in an orange juice matrix: terpenes and aldehydes[J]. Flavour and Fragrance Journal, 2004,19(6):491-498.
[20] PINO J A, MESA J. Contribution of volatile compounds to mango (Mangifera indica L.) aroma[J]. Flavour and Fragrance Journal, 2006,21(2):207-213.
[21] 李贵节, 张群琳, 何雅静, 等. 三种晚熟甜橙冷磨精油挥发性及主体香气成分的比较分析[J]. 食品与发酵工业,2020,46(5):284-291.
[22] ZHU J, XIAO Z. Characterization of the major odor-active compounds in dry jujube cultivars by application of gas chromatography-olfactometry and odor activity value[J]. Journal of Agricultural and Food Chemistry, 2018,66(29):7 722-7 734.
[23] VAN G L J. Complications of Odor Threshold Values in Air, Water and Other Media[M]. Houten:Van Setten Kwadraat, 2003.
[24] FENG S, SUH J H, GMITTER F G, et al. Differentiation between flavors of sweet orange(Citrus sinensis) and mandarin(Citrus reticulata)[J]. Journal of Agricultural and Food Chemistry, 2018,66(1):203-211.
Outlines

/