In this study, the pre-fermentative addition of 150 mg/L of caffeic acid and rosmarinic acid in Cabernet Sauvignon red winemaking was performed. The influence of phenolic compounds addition on wine color parameters and aroma components was monitored after 6 months of aging using UPLC-MS and GC-MS technologies. The results showed that the L* value of the treated samples was decreased by 0.9-1.5 a.u. and the a* value was increased by 1.0-1.3 a.u.. Among them, the rosmarinic acid treatment had a better effect. Meanwhile, the results showed that the mean total anthocyanin and total phenol concentrations of the treated samples increased significantly by about 70 and 580 mg/L, respectively. The results of UHPLC-MS showed that although there was no difference in the types of anthocyanins in the tested samples, the addition of phenolic compounds could significantly improve their content, especially the type of acylated anthocyanins after rosmarinic acid treatment. The analysis of aroma components showed that caffeic acid treatment increased the content of esters, acids and terpenes in wine, while rosmarinic acid treatment increased the content of esters and decreased the concentration of other types of aroma components.
[1] BIMPILAS A, PANAGOPOULOU M, TSIMOGIANNIS D, et al. Anthocyanin copigmentation and color of wine: The effect of naturally obtained hydroxycinnamic acids as cofactors[J]. Food Chemistry, 2016, 197: 39-46.
[2] 刘丽媛, 刘延琳, 李华. 葡萄酒香气化学研究进展[J]. 食品科学, 2011,32 (5): 310-316.
[3] PAMÉLA N, CHARLÈNE M, ANGERS P, et al. Co-fermentation of red grapes and white pomace: A natural and economical process to modulate red hybrid wine composition[J]. Food Chemistry, 2017, 242: 481-490.
[4] 张波, 祝霞, 盛文军, 等. 红葡萄酒中花色苷辅色化反应研究进展[J]. 中国农业科技导报, 2017,19(8): 92-104.
[5] HERAS-ROGER J, ROMERO C D, DARIAS-MARTIN J. What gives a wine its strong red color? Main correlations affecting copigmentation[J]. Journal of Agricultural and Food Chemistry, 2016, 64(34): 6 567-6 574.
[6] LAMBERT S G, ASENSTORFER R E, WILLIAMSON N M, et al. Copigmentation between malvidin-3-glucoside and some wine constituents and its importance to colour expression in red wine[J]. Food Chemistry, 2011, 125(1):106-115.
[7] ZHANG B, HE F, LIU Y, et al. Impact of adding ellagic acid to red grapes on the phenolic composition and chromatic quality of Cabernet Sauvignon wines from a warm climate[J]. Journal of Food Processing and Preservation, 2017, 41(4): e13 080.
[8] GÒMEZ-MÍGUEZ, M, GONZÁLEZ-MANZANO, S, ESCRIBANO-BAILóN, M T, et al. Influence of different phenolic copigments on the color of malvidin 3-glucoside[J]. Journal of Agricultural and Food Chemistry, 2006, 54(15):5 422-5 429.
[9] TEIXEIRA N, CRUZ L, BRÁS N F, et al. Structural features of copigmentation of oenin with different polyphenol copigments[J]. Journal of Agricultural and Food Chemistry, 2013, 61(28):6 942-6 948.
[10] DUFOUR C, BAYONOVE C L. Interactions between wine polyphenols and aroma substances. An insight at the molecular level[J]. Journal of Agricultural and Food Chemistry, 1999, 47(2): 678-684.
[11] ARONSON J, EBELER S E. Effect of polyphenol compounds on the headspace volatility of flavors[J]. American Journal of Enology and Viticulture, 2004, 55(1): 13-21.
[12] ESCALONA H, HOMMAN-LUDIYE M, PIGGOTT J R, et al. Effect of potassium bitartrate, (+)catechin and wood extracts on the volatility of ethyl hexanaote and octanal in ethanol/water solutions[J]. LWT-Food Science and Technology, 2001, 34(2): 76-80.
[13] CHENG Y, HUYNH-BA T, BLANK I, et al. Temporal changes in aroma release of longjing tea infusion: Interaction of Volatile and nonvolatile tea components and formation of 2-butyl-2-octenal upon aging[J]. Journal of Agricultural and Food Chemistry, 2008,4 156(6): 2 160-2 169.
[14] CHEN K, ESCOTT C, LOIRA I, et al. The effects of pre-fermentative addition of oenological tannins on wine components and sensorial qualities of red wine[J]. Molecules, 2016, 21(11): 1 445-1 452.
[15] VILLAMOR R R, ROSS C F. Wine matrix compounds affect perception of wine aromas[J]. Annual Review of Food Science and Technology, 2013, 4(1):1-20.
[16] 糜川清. 感官分析及仪器分析在葡萄酒香气研究中的应用[J]. 食品科学, 2012, 33(23):351-355.
[17] 王昶森, 杨志伟, 刘亚新, 等. UHPLC-MS/MS方法在葡萄酒花色苷鉴定过程中对两种锦葵色素同分异构体的分离[J]. 酿酒科技, 2018, 288(6): 63-66.
[18] 曹鹏, 张波, 张欣珂, 等. 陈酿前添加咖啡酸对干红葡萄酒颜色品质及多酚构成的影响[J]. 中国食品学报, 2019, 19(7): 153-160.
[19] 张明霞, 吴玉文, 段长青. 葡萄与葡萄酒香气物质研究进展[J]. 中国农业科学, 2008,41(7): 227-233.
[20] BOULTON R. The copigmentation of anthocyanins and its role in the color of red wine: A critical review[J]. American Journal of Enology and Viticulture, 2001, 522(2): 98-165.
[21] 陈欣然, 张波, 张欢,等. 红葡萄酒中花色苷的超高效液相色谱串联三重四级杆质谱检测方法建立[J]. 食品与发酵工业, 2019, 45(7): 262-268.
[22] 鲁榕榕, 马腾臻, 张波, 等. 不同澄清剂对起泡葡萄酒原酒的澄清作用及对香气品质的影响[J]. 食品科学, 2018, 39(12): 146-153.
[23] ZHANG B, WANG Q, ZHOU P P. et al. Copigmentation evidence of oenin with phenolic compounds: A comparative study of spectrographic, thermodynamic and theoretical data[J]. Food Chemistry, 2020, 313: 126 163.
[24] GORDILLO B, RODRÍGUEZ-PULIDO F J, ESCUDERO-GILETE M L, et al. Comprehensive colorimetric study of anthocyanic copigmentation in model solutions. Effects of pH and molar ratio[J]. Journal of Agricultural and Food Chemistry, 2012, 60(11): 2 896-2 905.
[25] 张波, 韩舜愈, 马腾臻, 等. 红葡萄酒中花色苷衍生物结构研究进展[J]. 食品科学, 2018, 39(5): 284-295.
[26] ALCALDE-EON C, BOIDO E, CARRAU F, et al. Pigment profiles in monovarietal wines produced in Uruguay[J]. American Journal of Enology and Viticulture, 2006, 57 (4): 449-459.
[27] 王玉华, 盛文军, 李敏, 等. 耐热克鲁维酵母和粟酒裂殖酵母顺序接种发酵对美乐干红葡萄酒品质的影响[J]. 食品科学, 2019, 40(8): 102-111.
[28] 牛见明, 张波, 史肖, 等. 三种澄清方式对‘美乐’甜型桃红葡萄酒品质的影响[J]. 食品与发酵工业, 2019, 45(16): 129-138.
[29] LI Y K, MARIO P, MARIROSA T, et al. Oenin and quercetincopigmentation: Highlights from density functional theory[J]. Frontiers in Chemistry, 2018, 6: 245.
[30] FIGUEIREDO-GONZÁLEZ M, CANCHOGRANDE B, SIMAL-GÁNDARA. Effects on colour and phenolic composition of sugar concentration processes in dried-on- or dried-off-vine grapes and their aged or not natural sweet wines[J]. Trends in Food Science & Technology, 2013, 31(1): 36-54.