Food and Fermentation Industries >

2022 , Vol. 48 >Issue 7: 258 - 263

DOI: https://doi.org/10.13995/j.cnki.11-1802/ts.029077

Highly sensitivity determination of mineral oil hydrocarbons in commercial alcoholic beverages

  • LIU Lingling ,
  • LI Bingning ,
  • YANG Mengqi ,
  • YANG Ming ,
  • WU Yanwen
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  • 1(Institute of Analysis and Testing,Beijing Academy of Science and Technology(Beijing Center for Physical and Chemical Analysis),Beijing100094,China)
    2(Beijing Food Safety Analysis and Testing Engineering Research Center,Beijing100094,China)

Received date: 2021-08-20

  Revised date: 2021-10-17

  Online published: 2022-04-27

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Abstract

Liquid-liquid extraction combined with on-line coupled high performance liquid chromatography-gas chromatography was proposed for highly sensitive determination of trace mineral oil saturated hydrocarbons (MOSH) and aromatic hydrocarbons (MOAH) in Baijiu, beer and wine. The limit of quantification (LOQ) was 0.05 mg/L, the recovery was 87%-107% and the relative standard deviation (RSD) was 1.9%-4.9%. The results showed that no contaminants were detected in all beer and wine samples. MOSH were detected in five Baijiu samples with contents ranging from 0.06 to 2.74 mg/L. MOAH of 0.11 and 1.24 mg/L were detected in two Baijiu samples, respectively. The contamination of these positive samples was positively correlated with the alcohol contents which might come from the packaging metal cans.

Key words： Baijiu; mineral oil hydrocarbons; on-line coupled high performance liquid chromatography-gas chromatography (HPLC-GC); alcohol content; metal can

Cite this article

LIU Lingling , LI Bingning , YANG Mengqi , YANG Ming , WU Yanwen . Highly sensitivity determination of mineral oil hydrocarbons in commercial alcoholic beverages[J]. Food and Fermentation Industries, 2022 , 48(7) : 258 -263 . DOI: 10.13995/j.cnki.11-1802/ts.029077

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