3D printing is a technology based on digital model, which produces pre-designed 3D objects by layering adhesive materials. Different from the traditional manufacturing methods, 3D printing technology has been greatly developed in recent years due to its potential advantages, such as customized geometry, reduced production cost, shortened manufacturing cycle and almost unconstrained appearance complexity, which are considered to be likely to promote the third industrial revolution. Food 3D printing is a new food processing technology. Due to the advantages of functionalization, customization, personalized nutrition design, simplified supply chain and broadening existing food materials, 3D printing has been widely studied in food industry in the past decade. At present, there are four types of 3D printing technologies for food processing: extrusion-based printing, selective laser sintering, adhesive spraying and inkjet printing. Among them, 3D printing based on extrusion is the most widely used, which can be further divided into room temperature extrusion, melt deposition manufacturing and gel forming extrusion according to different printing material states. In the extrusion process, the rheological properties of materials are very important for providing proper extrudability, bonding different food layers together and supporting the weight of the deposited layer. Gels with fast and reversible modulus are suitable for direct writing in 3D printing, because they are easily extruded from the nozzle tip and can maintain enough mechanical integrity to support the next printing layer without deformation. In food printing, soft materials such as dough and meat paste have been used to print 3D objects. Apparent viscosity is an important factor, which should be low enough to allow an easy extrusion process and high enough to adhere to previously deposited layers. Thus, it can be seen that the rheological properties of food have an important influence on the extrusion 3D printing characteristics. However, the traditional rheometer method takes a long time to characterize the rheological properties of materials and the sample processing is complicated. Near infrared spectroscopy (NIR)detection has the advantages of low technical cost, high detection speed, no sample damage and no pretreatment. In the near infrared spectrum, the relative contribution of reflected and absorbed radiation depends on the chemical composition, physical parameters and microstructure of the product. Many reports show that there is a significant correlation between the concentration of chemical components and NIR spectrum estimation. The present study was aimed at establishing a novel testing method for fast and nondestructive evaluation of food printing characteristics of surimi gel system. The ink with different printing characteristics was built with surimi gel systems with different water content and salt content, the rheological properties and near infrared spectra of samples were measured, and the pretreatment methods of different spectra were compared. Through NIR parameters, the 3D qualitative classification prediction model of surimi gel system and the quantitative prediction model of rheological parameters were established. The results show that multivariate scattering correction and standard normal variable transformation pretreatment are suitable for processing the infrared spectrum of surimi gel system to judge its printing characteristic grade by establishing PCA-LDA model, and the correct rate of judgment is 100%. The centralized pretreatment is most suitable for predicting the rheological parameter K of surimi gel system, and the determination coefficient R2p of the corresponding PLSR model test set is 0.9446, and the root mean square error RMSEP is 67.43. The modeling effect of rheological parameters G′-10、G″-10、G*-10 of spectral data preprocessed by means of multivariate scattering correction combined with mean centralization and standard normal variable transformation combined with mean centralization is similar and superior to other preprocessing methods.
FAN Dongcui
,
LIU Wenchao
,
CHEN Huizhi
,
ZHANG Min
. 3D printing characteristics and rheological properties of surimi gel based on near infrared spectroscopy[J]. Food and Fermentation Industries, 2022
, 48(9)
: 163
-169
.
DOI: 10.13995/j.cnki.11-1802/ts.030281
[1] 徐广通, 袁洪福, 陆婉珍.现代近红外光谱技术及应用进展[J].光谱学与光谱分析, 2000, 20(2):134-142.
XU G T, YUAN H F, LU W Z.Development of modern near infrared spectroscopic techniques and its applications[J].Spectroscopy and Spectral Analysis, 2000, 20(2):134-142.
[2] 刘建学, 尹晓慧, 韩四海, 等.便携式近红外光谱仪研究进展[J].河南农业大学学报, 2019, 53(4):662-670.
LIU J X, YIN X H, HAN S H, et al.Review of portable near-infrared spectrometers[J].Journal of Henan Agricultural University, 2019, 53(4):662-670.
[3] LIU Z B, ZHANG M, YANG C H.Dual extrusion 3D printing of mashed potatoes/strawberry juice gel[J].LWT, 2018, 96:589-596.
[4] LIU Z B, ZHANG M, BHANDARI B.Effect of gums on the rheological, microstructural and extrusion printing characteristics of mashed potatoes[J].International Journal of Biological Macromolecules, 2018, 117:1 179-1 187.
[5] YANG F L, GUO C F, ZHANG M, et al.Improving 3D printing process of lemon juice gel based on fluid flow numerical simulation[J].LWT, 2019, 102:89-99.
[6] LIU Z B, BHANDARI B, PRAKASH S, et al.Linking rheology and printability of a multicomponent gel system of carrageenan-xanthan-starch in extrusion based additive manufacturing[J].Food Hydrocolloids, 2019, 87:413-424.
[7] SWEENEY M, CAMPBELL L L, HANSON J, et al.Characterizing the feasibility of processing wet granular materials to improve rheology for 3D printing[J].Journal of Materials Science, 2017, 52(22):13 040-13 053.
[8] FENG L, ZHANG M, BHANDARI B, et al.Determination of postharvest quality of cucumbers using nuclear magnetic resonance and electronic nose combined with chemometric methods[J].Food and Bioprocess Technology, 2018, 11(12):2 142-2 152.
[9] DE LIMA G F, ANDRADE S C, DA SILVA V H, et al.Multivariate classification of UHT milk as to the presence of lactose using benchtop and portable NIR spectrometers[J].Food Analytical Methods, 2018, 11(10):2 699-2 706.
[10] LIU W C, ZHANG M, BHANDARI B, et al.A novel combination of LF-NMR and NIR to intelligent control in pulse-spouted microwave freeze drying of blueberry[J].LWT, 2021, 137:110455.
[11] CHEN J L, ZHANG M, DEVAHASTIN S, et al.Novel alternative use of near-infrared spectroscopy to indirectly forecast 3D printability of purple sweet potato pastes[J].Journal of Food Engineering, 2021, 296:110464.
[12] HUANG Y P, LU R F, CHEN K J.Prediction of firmness parameters of tomatoes by portable visible and near-infrared spectroscopy[J].Journal of Food Engineering, 2018, 222:185-198.
[13] SILVA L C R, FOLLI G S, SANTOS L P, et al.Quantification of beef, pork, and chicken in ground meat using a portable NIR spectrometer[J].Vibrational Spectroscopy, 2020, 111:103158.
[14] 魏雨晴, 王毓宁, 李绍佳, 等.基于自制便携式近红外光谱仪的枇杷果实可溶性固形物无损检测及年度重复验证[J].浙江大学学报(农业与生命科学版), 2020, 46(1):119-125.
WEI Y Q, WANG Y N, LI S J, et al.Non-destructive detecting and annual duplicate verification of loquat fruit’s total soluble solids based on self-developed portable near-infrared spectrometer[J].Journal of Zhejiang University (Agriculture and Life Sciences), 2020, 46(1):119 -125.
[15] 邹涛. 基于便携式近红外光谱仪快速检测大豆蛋白优化方法的研究[D].镇江:江苏大学, 2019.
ZOU T.Study on optimization method for rapid detection of soybean protein based on portable near infrared spectrometer[D].Zhenjiang:Jiangsu University, 2019.
[16] 李鸿博. 基于近红外光谱的红松子品质检测模型研究[D].沈阳:东北林业大学, 2021.
LI H B.Research on the quality detection model of red pine nuts based on near-infrared spectroscopy[D].Shenyang:Northeast Forestry University, 2021.
[17] 刘泽宇. 基于便携式近红外光谱和嗅觉可视化的啤酒分类与品质检测研究[D].镇江:江苏大学, 2019.
LIU Z Y.Beer classification and qualification detection based on portable near infrared spectroscopy and olfactory visualization[D].Zhenjiang:Jiangsu University, 2019.
[18] 吴磊. 基于计算机视觉和近红外光谱技术的鱼新鲜度检测方法研究[D].镇江:江苏大学, 2013.
WU L.Study on detection method for fish freshness based on computer vision and near infrared spectroscopy[D].Zhengjiang:Jiangsu University, 2013.
[19] ZHANG L, WANG S S, DING Y F, et al.Discrimination of transgenic rice based on near infrared reflectance spectroscopy and partial least squares regression discriminant analysis[J].Rice Science, 2015, 22(5):245-249.