Research on a method for preparing plywood adhesives using prolamin extracted from distilled spent grains of Baijiu

  • LI Ting ,
  • XU Yan ,
  • FAN Wenlai
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  • 1(Lab of Brewing Microbiology and Applied Enzymology, School of Biotechnology, Jiangnan University, Wuxi 214122, China)
    2(Key Laboratory of Industrial Biotechnology of Ministry of Education (Jiangnan University), Wuxi 214122, China)

Received date: 2025-02-24

  Revised date: 2025-03-24

  Online published: 2025-08-01

Abstract

Distilled spent grains (DSG) are the largest by-product in Baijiu (Chinese liquor) production.They are rich in nutrients and have the potential to serve as cheap and high-quality raw materials for other industrial products.In this study, the soy sauce aroma and flavor type of prolamin was extracted.The prolamin was modified with sodium dodecyl sulfate, and then a cross-linking agent and a coupling agent KH-791 were added.The effects of the denaturant, cross-linking agent, and coupling agent on the adhesive properties were systematically investigated.The research results indicated that the modification leads to the formation of β-turn and β-sheet structures through molecular rearrangement after the swelling of prolamin, which increased the protein crystallinity of the adhesive.The interaction after the exposure of the internal groups of the protein significantly enhanced the performance of the adhesive.The adhesive became smoother and denser, and its water resistance and adhesion strength were stronger.In addition, this study provides new ideas and methods for the high-value-added application of DSG.

Cite this article

LI Ting , XU Yan , FAN Wenlai . Research on a method for preparing plywood adhesives using prolamin extracted from distilled spent grains of Baijiu[J]. Food and Fermentation Industries, 2025 , 51(14) : 28 -34 . DOI: 10.13995/j.cnki.11-1802/ts.042489

References

[1] YANG S Q, FAN W L, XU Y. Melanoidins from Chinese distilled spent grain: Content, preliminary structure, antioxidant, and ACE-inhibitory activities in vitro[J]. Foods, 2019, 8(10):516.
[2] LIU Z Y, ZHONG X X, YAO Y C, et al. Biological feed of white distiller’s grains and its application status in swine production[J]. Chinese Journal of Animal Nutrition, 2020, 32(1):15-20.
[3] 刘林培, 管秀琼, 何明雄, 等. 利用好氧堆肥法协同处理多种酒业固废的原料配比[J]. 食品与发酵工业, 2022, 48(5):116-122.
LIU L P, GUAN X Q, HE M X, et al. Optimization of raw materials ratio using aerobic composting method to synergistically treat a variety of wine industry solid waste[J]. Food and Fermentation Industries, 2022, 48(5):116-122.
[4] 李嘉琳. 酿酒废弃物催化热解及其产物资源化利用研究[D]. 哈尔滨:哈尔滨工业大学,2021.
LI J L. Study on catalytic pyrolysis and resource utilization of distillers’ grains[D]. Harbin: Harbin Institute of Technology, 2021.
[5] 侯梦媛, 范文来, 徐岩. 白酒酒糟中醇溶蛋白的提取及性质比较[J]. 食品与发酵工业, 2020, 46(19):99-103.
HOU M Y, FAN W L, XU Y. Extraction and characterization comparison of prolamin from wet and dried distiller’s grains of Baijiu[J]. Food and Fermentation Industries, 2020, 46(19):99-103.
[6] ZHANG L P, ZHANG B H, FAN B, et al. Liquefaction of soybean protein and its effects on the properties of soybean protein adhesive[J]. Pigment & Resin Technology, 2017, 46(5):399-407.
[7] MO J L, WANG F, XU Z, et al. Characterization and performance of soybean protein modified by tyrosinase[J]. International Journal of Adhesion and Adhesives, 2019, 92:111-118.
[8] YAO J C, CHEN Z G, XU C, et al. Cottonseed protein bioadhesive with high adhesion performance achieved by a synergistic dual-crosslinking strategy[J]. International Journal of Adhesion and Adhesives, 2023, 127:103514.
[9] QU Y, LI T, HUANG X G, et al. Developing multifunctional and environmental-friendly hot-pressed peanut meal protein adhesive based on peanut waste[J]. Chemical Engineering Journal, 2023, 471:144207.
[10] ZHOU T T, HU W K, YANG Z B, et al. Study on nutrients, non-volatile compounds, volatile compounds and antioxidant capacity of oyster mushroom cultivated with corn distillers’ grains[J]. LWT, 2023, 183:114967.
[11] 徐颖莹, 崔政, 李一凡, 等. 复合变性对大豆蛋白胶粘剂耐水胶接性的影响[J]. 热固性树脂, 2018, 33(5):51-55.
XU Y Y, CUI Z, LI Y F, et al. Effect of compound denaturation on the water resistance of the resultant adhesives[J]. Thermosetting Resin, 2018, 33(5):51-55.
[12] 张二兵, 朱志强, 涂伊静, 等. PVA-ECH接枝改性脱脂豆粉制备高性能木材胶粘剂[J]. 中国胶粘剂, 2021, 30(3):30-35.
ZHANG E B, ZHU Z Q, TU Y J, et al. Preparation of high performance wood adhesive modified by defatted soybean flour grafting with PVA-ECH[J]. China Adhesives, 2021, 30(3):30-35.
[13] XU Y T, XU Y C, HAN Y F, et al. The effect of enzymolysis on performance of soy protein-based adhesive[J]. Molecules, 2018, 23(11):2752.
[14] LI H R, FAN R C, ZHANG F D, et al. A spider-silk-inspired soybean protein adhesive with high-strength and mildew-resistant via synergistic effect of MXene nanosheets and chitosan[J]. Industrial Crops and Products, 2023, 193:116252.
[15] TAYLOR J R N, TAYLOR J. Do kafirin bioplastic materials have unique functional characteristics?[J]. Cereal Chemistry, 2023, 100(3):539-555.
[16] LI N B, WANG Y, TILLEY M, et al. Adhesive performance of sorghum protein extracted from sorghum DDGS and flour[J]. Journal of Polymers and the Environment, 2011, 19(3):755-765.
[17] XU Y, LI J J, YU D G, et al. Influence of the drug distribution in electrospun gliadin fibers on drug-release behavior[J]. European Journal of Pharmaceutical Sciences, 2017, 106:422-430.
[18] BALAGUER M P, GÓMEZ-ESTACA J, GAVARA R, et al. Functional properties of bioplastics made from wheat gliadins modified with cinnamaldehyde[J]. Journal of Agricultural and Food Chemistry, 2011, 59(12):6689-6695.
[19] LIU Z, KOU F J, DUAN Y C, et al. Preparation and investigation of distillers-dried grains with solubles-based wood adhesive[J]. Journal of Forestry Engineering, 2021, 6(1):105-111.
[20] ZHONG C L, HOU X F, PENG S, et al. Acrylamide macromolecules modified wine lees-soy protein wood adhesive[J]. Journal of Applied Polymer Science, 2024, 141(32): e55819.
[21] CONNOLLY J M, ALFERIEV I, EIDELMAN N, et al. Triglycidylamine crosslinking of porcine aortic valve cusps or bovine pericardium results in improved biocompatibility, biomechanics, and calcification resistance chemical and biological mechanisms[J]. The American Journal of Pathology, 2005, 166(1):1-13.
[22] ZHANG Y, ZHANG M, CHEN M S, et al. Preparation and characterization of a soy protein-based high-performance adhesive with a hyperbranched cross-linked structure[J]. Chemical Engineering Journal, 2018, 354:1032-1041.
[23] SUN Z X, CHANG Z W, BAI Y M, et al. Effects of working time on properties of a soybean meal-based adhesive for engineered wood flooring[J]. The Journal of Adhesion, 2022, 98(12):1916-1935.
[24] PANG H W, MA C, ZHANG S F. Conversion of soybean oil extraction wastes into high-performance wood adhesives based on mussel-inspired cation-π interactions[J]. International Journal of Biological Macromolecules, 2022, 209:83-92.
[25] HETTIARACHCHY N S, KALAPATHY U, MYERS D J. Alkali-modified soy protein with improved adhesive and hydrophobic properties[J]. Journal of the American Oil Chemists’ Society, 1995, 72(12):1461-1464.
[26] 张学军. 纳米材料对大豆蛋白生物胶黏剂的影响研究[D].无锡: 江南大学, 2008.
ZHANG X J. Studies on the effect of nano materials on adhesive properties of soy bean proteins as bioingredients[D]. Wuxi: Jiangnan University, 2008.
[27] LI J J, LUO J, LI X N, et al. Soybean meal-based wood adhesive enhanced by ethylene glycol diglycidyl ether and diethylenetriamine[J]. Industrial Crops and Products, 2015, 74:613-618.
[28] LI Y Y, GUO X L, LIN P F, et al. Preparation and functional properties of blend films of gliadins and chitosan[J]. Carbohydrate Polymers, 2010, 81(2):484-490.
[29] XU Y T, HAN Y F, CHEN M S, et al. Constructing a triple network structure to prepare strong, tough, and mildew resistant soy protein adhesive[J]. Composites Part B: Engineering, 2021, 211:108677.
[30] ZHANG Y, SHI R Q, XU Y C, et al. Developing a stable high-performance soybean meal-based adhesive using a simple high-pressure homogenization technology[J]. Journal of Cleaner Production, 2020, 256:120336.
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