As a new form of cleaning agent, effervescent cleaning tablets have high cleaning efficiency.Although there has been extensive research on shell-based cleaning agents, there is no reported research on shell-based effervescent tablet cleaning agents yet.To address this limitation,this study used calcined limpet shell powder as the raw material to develop a new type of effervescent tablet cleaner.The optimal preparation process was established by assessing disintegration time and effervescence.Cherry tomatoes were selected as the cleaning substrate to systematically evaluate the microbial removal efficiency of the cleaning agent, as well as its effects on the sensory and nutritional attributes of the tomatoes.The results indicated that mussel shell powder calcined at 850 ℃ for a duration of 2 hours, combined with a formulation consisting of 35% shell powder, 60% disintegrant (sodium bicarbonate∶citric acid at a ratio of 0.4∶1), 3% binder, and 2% lubricant, yields effervescent tablets that are characterized by a white color, smooth texture, and vigorous effervescence.When applied at a mass concentration of ≤2 g/100 mL for ≤20 min, the cleaning agent achieved a microbial removal rate exceeding 91.3%, while preserving over 93.8% of titratable acid, 89.8% of vitamin C, 94.0% of total phenols, and 96.0% of total flavonoids, thereby maintaining the color and firmness of the tomatoes.In conclusion, the shell powder effervescent tablet cleaning agent demonstrates considerable promise as an environmentally friendly and sustainable product, with significant potential applications in the cleaning industry, thereby offering new opportunities for the high-value utilization of shell materials.
[1] 王洪波. 废弃贝壳资源化利用现状及研究进展[J].水产养殖, 2021, 42(5):15-19.
WANG H B.The current situation and research progress of resource utilization of waste mollusk shell[J].Journal of Aquaculture, 2021, 42(5):15-19.
[2] CHENG M Q, LIU M, CHANG L R, et al.Overview of structure, function and integrated utilization of marine shell[J].Science of the Total Environment, 2023, 870:161950.
[3] 王权. 基于紫贻贝壳的果蔬清洗剂制备及其吸附性能研究[D].舟山:浙江海洋大学, 2021.
WANG Q.Preparation and adsorption properties of fruit and vegetable detergent based on Mytilus edulis shell powder[D].Zhoushan:Zhejiang Ocean University, 2021.
[4] 王雅颖. 海洋微纳米果蔬清洗剂的制备及性能研究[D].舟山:浙江海洋学院, 2015.
WANG Y Y.Study on preparation and properties of micro-nano shell powder purifier for fruits and vegetables[D].Zhoushan:Zhejiang Ocean University, 2015.
[5] 杨丽梅, 刘烨.果蔬洗涤盐泡腾片的开发[J].中国井矿盐, 2017, 48(4):4-5;11.
YANG L M, LIU Y.The exploitation of garden stuff washing salt effervescent tablets[J].China Well and Rock Salt, 2017, 48(4):4-5;11.
[6] 孙燕达. 复合亚氯酸钠果蔬清洗泡腾片的制备与质量评价[D].石家庄:河北科技大学, 2019.
SUN Y D.Preparation and quality evaluation of composite sodium chlorite cleaning effervescent tablets for fruits and vegetables[D].Shijiazhuang:Hebei University of Science and Technology, 2019.
[7] SUN W H.Development of effervescent tablets containing elderberry vine tea compound and evaluation of their antioxidant activity[J].Journal of Food Processing and Preservation, 2023, 2023:4312278.
[8] 唐婧红, 范可帷, 张素, 等.黑曲霉泡腾片制备工艺优化[J].中国酿造, 2018, 37(10):186-189.
TANG J H, FAN K W, ZHANG S, et al.Preparation process optimization of Aspergillus niger effervescent tablets[J].China Brewing, 2018, 37(10):186-189.
[9] 国家药典委员会. 中华人民共和国药典[M].北京:中国医药科技出版社, 2020.
National Pharmacopoeia Commission.Pharmacopoeia of the People’s Republic of China[M].Beijing:China Medical Science and Technology Press, 2020.
[10] 曹建康, 姜微波, 赵玉梅.果蔬采后生理生化实验指导[M].北京:中国轻工业出版社, 2007, 24-41.
CAO J K, JIANG W B, ZHAO Y M.Guidance of Postharvest Physiological and Biochemical Experiments of Fruits and Vegetables[M].Beijing:China Light Industry Press, 2007, 24-41.
[11] 刘心建, 李梦雪, 王泽云, 等.浅谈消毒泡腾片[J].日用化学品科学, 2020, 43(10):44-47.
LIU X J, LI M X, WANG Z Y, et al. Brief discussion on the disinfection effervescent tablets[J].Detergent & Cosmetics, 2020, 43(10):44-47.
[12] 王艳, 万庆家, 廖海慧, 等.芦荟泡腾片的制备[J].食品工业, 2022, 43(1):9-12.
WANG Y, WAN Q J, LIAO H H, et al.Preparation of Aloe vera effervescent tablets[J].The Food Industry, 2022, 43(1):9-12.
[13] 王媛媛, 郝璟嵘, 闫思颖, 等.沙棘冻干粉泡腾片的制备工艺优化及其品质分析[J].食品工业科技, 2023, 44(10):235-241.
WANG Y Y, HAO J R, YAN S Y, et al.Optimization of preparation process and quality analysis of seabuckthorn lyophilized powder effervescent tablets[J].Science and Technology of Food Industry, 2023, 44(10):235-241.
[14] 邸玲. 贝壳粉涂料的研究[D].长春:吉林建筑大学, 2018.
DI L.Research for shell powder coating[D].Changchun:Jilin Jianzhu University, 2018.
[15] XIAO J, HU R, CHEN G C.Micro-nano-engineered nitrogenous bone biochar developed with a ball-milling technique for high-efficiency removal of aquatic Cd(Ⅱ), Cu(Ⅱ) and Pb(Ⅱ)[J].Journal of Hazardous Materials, 2020, 387:121980.
[16] TAN J, LIU Z X, WANG D H, et al.A facile and universal strategy to endow implant materials with antibacterial ability via alkalinity disturbing bacterial respiration[J].Biomaterials Science, 2020, 8(7):1815-1829.
[17] GEDDA G, PANDEY S, LIN Y C, et al.Antibacterial effect of calcium oxide nano-plates fabricated from shrimp shells[J].Green Chemistry, 2015, 17(6):3276-3280.
[18] ADEKUNTE A O, TIWARI B K, CULLEN P J, et al.Effect of sonication on colour, ascorbic acid and yeast inactivation in tomato juice[J].Food Chemistry, 2010, 122(3):500-507.
[19] WANG J, WANG J, YE J H, et al.Influence of high-intensity ultrasound on bioactive compounds of strawberry juice:Profiles of ascorbic acid, phenolics, antioxidant activity and microstructure[J].Food Control, 2019, 96:128-136.
[20] 潘永贵, 谢江辉.现代果蔬采后生理[M].北京:化学工业出版社, 2009.
PAN Y G, XIE J H.Postharvest Physiology of Modern Fruits and Vegetables[M].Beijing:Chemical Industry Press, 2009.
[21] WANG J, MUJUMDAR A S, WANG H, et al.Effect of drying method and cultivar on sensory attributes, textural profiles, and volatile characteristics of grape raisins[J].Drying Technology, 2021, 39(4):495-506.
[22] TOIVONEN P M A, BRUMMELL D A.Biochemical bases of appearance and texture changes in fresh-cut fruit and vegetables[J].Postharvest Biology and Technology, 2008, 48(1):1-14.
[23] 邱雪. 钙处理对灵武长枣质地品质与细胞壁多糖纳米结构的影响研究[D].银川:宁夏大学, 2020.
QIU X.Effects of calcium treatment on the quality and cell wall polysaccharides nanostructure of Lingwu Long-Jujube[D].Yinchuan:Ningxia University, 2020.
[24] 经亚丽, 王梦真, 庄英钰, 等.薄荷提取液对巴梨采后品质的影响[J].核农学报, 2025, 39(5):983-990.
JING Y L, WANG M Z, ZHUANG Y Y, et al.Effect of peppermint extract on postharvest quality of bartlett[J].Journal of Nuclear Agricultural Sciences, 2025, 39(5):983-990.
[25] 苏玮. 利用初榨草莓汁探究pH对果胶酶活性的影响[J].中学生物学, 2016, 32(5):47-48.
SU W.The effect of pH on pectinase activity was explored using freshly squeezed strawberry juice[J].Middle School Biology, 2016, 32(5):47-48.
[26] 兰文忠, 冀利, 贺晓芳, 等.冬枣汁与金丝小枣汁总酚、总黄酮含量及抗氧化性能的比较研究[J].食品与发酵科技, 2021, 57(1):90-94.
LAN W Z, JI L, HE X F, et al.Comparative study on the contents of total phenols, flavonoids and antioxidant activity of winter jujube juice and golden-silk jujube juice[J].Food and Fermentation Sciences & Technology, 2021, 57(1):90-94.
