Preparation of citral emulsion stabilized by β-cyclodextrin and its stability

  • WANG Xiangfan ,
  • LI Xuehong ,
  • YU Guoqiang ,
  • DING Hongying ,
  • YANG Feng ,
  • XU Hongtao
Expand
  • 1 (Henan Cigarette Industrial Reconstituted Tobacco Sheet Co., Ltd., Xuchang 461100,China)
    2 (Department of Food and Bioengineering, Zhengzhou University of Light Industry, Zhengzhou 450000, China)

Received date: 2019-04-20

  Online published: 2020-02-10

Abstract

This study focuses on the preparation of citral Pickering emulsion stabilized by β-cyclodextrin, the stability of such emulsion and its influence factors. Using nano-particle inclusion complex of β-cyclodextrin with citral as emulsion stablizer, the citral Pickering emulsion was prepared by high-speed homogeneous shearing method. The microstructure of the emulsion was then observed and its particle size and Zeta potential were measured, and the effects of system pH value and xanthan gum on emulsion stability were investigated. The results showed that a stable oil-in-water type Pickering emulsion can be formed by stable emulsification with β-CD, where the oil particle is standard spherical and of several hundred nanometers in particle size. An acidic or alkaline environment, or addition of xanthan gum, was favorable to the stability of the emulsion. Further study indicated that the citral Pickering emulsion showed relative excellent heat stability but poor tolerance of freezing; that adding xanthan gum (5 g/L) could significantly increase the freeze resistance of the emulsion. This research has provided a novel green approach for citral emulsion preparation.

Cite this article

WANG Xiangfan , LI Xuehong , YU Guoqiang , DING Hongying , YANG Feng , XU Hongtao . Preparation of citral emulsion stabilized by β-cyclodextrin and its stability[J]. Food and Fermentation Industries, 2019 , 45(24) : 124 -129 . DOI: 10.13995/j.cnki.11-1802/ts.020903

References

[1] XIAO J, LI Q, HUANG Q R. Recent advances on food-grade particles stabilized Pickering emulsions: Fabrication, characterization and research trends[J]. Trends in Food Science and Technology, 2016, 55:48-60.
[2] 李海明,杨盛,韦何雯,等.食品级Pickering乳液的研究进展[J]. 食品科学, 2015, 36(19): 265-270.
[3] CHRISTINA L,STEPHAN D. Pickering emulsions in foods - opportunities and limitations[J]. Critical Reviews in Food Science Nutrition, 2018, 58(12):1 971-1 985.
[4] 李丹凤,徐婷,胡静,等.香料化合物柠檬醛稳定性研究进展[J].食品工业, 2016, 37(9): 215-219.
[5] MASWAL M, DAR A A. Formulation challenges in encapsulation and delivery of citral for improved food quality[J]. Food Hydrocolloids, 2014, 37:182-195.
[6] ZAHI MR, LIANG H, YUAN Q. Improving the antimicrobial activity of D-limonene using a novel organogel-based nanoemulsion[J]. Food Control, 2015, 50:554-559.
[7] WAGONER T B, FOEGEDING E A. Whey protein-pectin soluble complexes for beverage applications[J]. Food Hydrocolloids, 2017, 63: 130-138.
[8] PIORKOWSKI D T, MCCLEMENTS D J. Beverage emulsions: Recent developments in formulation, production, and applications[J]. Food Hydrocolloids, 2014, 42:5-41.
[9] TIAN H X, LI D F, XU T, et al. Citral stabilization and characterization of nanoemulsions stabilized by a mixture of gelatin and Tween 20 in an acidic system[J]. Joutnal of the Science of Food and Agriculture, 2017, 97(9): 2 991-2 998
[10] YANG X Q, TIANH X, HO C T, et al. Inhibition of citral degradation by oil-in-water nanoemulsions combined with antioxidants[J].Journal of Agricultural and Food Chemistry, 2011, 59(11): 6 113-6 119.
[11] YANG Y, CUI S, GONG J, et al. Stability of citral in oil-in-water emulsions protected by a soy protein-polysaccharide Maillard reaction product[J]. Food Research International, 2015, 69: 357-363.
[12] MOTOKI I, KANAME H, HIROYUKI T, et al. Emulsifying ability of β-cyclodextrins for common oils[J]. Journal of Dispersion Science and Technology, 2010, 31:1 648-1 651.
[13] XI Y K, LUO Z G, LU X X, et al. Modulation of cyclodextrins particles amphiphilic properties to stabilize Pickering emulsion[J]. Journal of Agriculture and Food Chemistry, 2018, 66(1): 228-237.
[14] MATHAPA B G, PAUNOV V N. Self-assembly of cyclodextrin-oil inclusion complexes at the oil-water interface: A route to surfactant-free emulsions[J]. Journal of Materials Chemistry A, 2013, 1(36):10 836-10 846.
[15] 袁继凤,徐化能,王周平. 基于β-环糊精稳定的Pickering乳液微观结构与流变性质研究[J]. 食品与生物技术学报, 2014, 33(4): 374-380.
[16] CHAUDHARI A, PAN Y, NITI N. Beverage emulsions: Comparison among nanoparticle stabilized emulsion with starch and surfactant stabilized emulsions[J]. Food Research International, 2015, 69:156-163.
[17] LI P H, LU W C. Effect of storage condition on the physical stability of D-limonene nanoemulsion[J]. Food Hydrocoll, 2016, 53:218-224.
[18] YANG Y, ZHAO C Y, TIAN G F, et al. Effects of preheating and storage temperatures on aroma profile and physical properties of citrus-oil emulsions[J]. Journal of Agricultural and Food Chemistry, 2017, 65(35): 7 781-7 789.
[19] HU J W, YEN M W, WANG A J, et al. Effect of oil structure on cyclodextrin-based Pickering emulsions for bupivacaine topical application[J]. Colloids and Surfaces B: Biointerfaces, 2018, 161:51-58.
[20] ARAB D, KANTZAS A, BRYANT S L. Nanoparticle stabilized oil in water emulsions: A critical review[J]. Journal of Petroleum Science and Engineering, 2018, 163:217-242.
[21] RAO J J, MCCLEMENTS D J. Formation of flavor oil microemulsions, nanoemulsions and emulsions: Influence of composition and preparation method[J]. Journal of Agricultural and Food Chemistry, 2011, 59(9): 5 026-5 035.
[22] KATEPALLI H, VIJAY T J, TRIPATHI A, et al. Microstructure and rheology of particle stabilized emulsions: Effects of particle shape and inter-particle interactions[J]. Journal of Colloid and Interface Science, 2017, 485:11-17.
[23] HONARY S, ZAHIR F. Effect of zeta potential on the properties of nano-drug delivery systems–A review (part 2)[J]. Tropical Journal of Pharmaceutical Research, 2013, 12(2): 265-273.
[24] RAVINDRAN S, WILLIAMS M A K, WARD R L, et al. Understanding how the properties of whey protein stabilized emulsions depend on pH, ionic strength and calcium concentration, by mapping environmental conditions to zeta potentia[J]. Food Hydrocolloids, 2018, 79: 572-578.
[25] SAV A R, MEER T A, FULE R A, et al. Investigational studies on highly purified fenugreek gum as emulsifying agent[J]. Journal of Dispersion Science and Technology, 2013, 34(5): 657-662.
[26] SONG X Y, PEI Y Q, QIAO M W. Preparation and characterizations of Pickering emulsions stabilized by hydrophobic starch particles[J]. Food Hydrocolloids, 2015, 45: 256-263.
[27] DERAKHSHANDEH M, PILAPIL B K, WORKMAN B. Analysis of network formation and long-term stability in silica nanoparticle stabilized emulsions[J]. Soft Matter, 2018, 14(21): 4 268-4 277.
[28] CATHERINE P W, LOTTE L, LANG C. Structure of concentrated oil-in-water Pickering emulsions[J]. Soft Matter, 2012, 8(30): 7 784-7 789.
[29] 朱雨晴,刘伟,陈兴,等. 食品级皮克林乳液的稳定机制及稳定性研究进展[J]. 食品工业科技, 2018, 39(7): 315-322.
Outlines

/