Properties and mechanisms of Cr(VI) adsorption on acetic acidlignin from bamboo shoot shells

  • HU Zicong ,
  • FANG Cuilan ,
  • LI Sheng ,
  • YE Fayin ,
  • ZHAO Guohua
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  • 1(College of Food Science, Southwest University, Chongqing 400715, China)
    2(Centre for Disease Control and Prevention of Jiulongpo, Chongqing 400039, China)
    3(Chongqing Engineering Research Center for Regional Foods, Chongqing 400715, China)

Received date: 2020-02-06

  Online published: 2020-06-24

Abstract

This study aimed to evaluate the adsorption capacity and potential adsorption mechanisms of Cr (VI) by bamboo shoot shell acetic acid lignin (BSS-AL). The effects of pH, addition amount of BSS-AL, contact time and initial Cr(VI) concentration were studied through batch adsorption experiments. And the adsorption models were also been established. Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) were used to detect the functional groups and element composition of BSS-AL before and after adsorption in order to explore the adsorption mechanisms. The results showed that BSS-AL exhibited high-efficiency adsorption capacity of Cr (VI) and the removal rate of Cr (VI) could reach 97% in four hours. Furthermore, the pseudo-second-order kinetic model could be matched with the adsorption behavior over the whole range of adsorption process. Moreover, the adsorption of Cr (VI) by BSS-AL could be described well by Langmuir model and the maximum adsorption capacity reached 14.908 mg/g. The adsorption mechanisms could be explained by FTIR and XPS spectra: electrostatic interaction, ion exchange and re-adsorption after reduction. And BSS-AL has great potential to remove toxic pollutant Cr(VI) from food.

Cite this article

HU Zicong , FANG Cuilan , LI Sheng , YE Fayin , ZHAO Guohua . Properties and mechanisms of Cr(VI) adsorption on acetic acidlignin from bamboo shoot shells[J]. Food and Fermentation Industries, 2020 , 46(11) : 52 -60 . DOI: 10.13995/j.cnki.11-1802/ts.023531

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