Application of deep eutectic solvents-dispersive liquid-liquid microextraction for the determination of contaminants in food and environment

  • LIN Zhihao ,
  • ZHANG Yaohai ,
  • JIAO Bining ,
  • HAN Ke ,
  • QIN Yan
Expand
  • 1(Citrus Research Institute,Southwest University & Chinese Academy of Agricultural Sciences,Chongqing 400712,China)
    2(Laboratory of Quality and Safety Risk Assessment for Citrus Products,Ministry of Agriculture and Rural Affairs,Chongqing 400712,China)
    3(Quality Supervision and Testing Center for Citrus and Seedling,Ministry of Agriculture and Rural Affairs,Chongqing 400712,China)

Received date: 2020-10-20

  Revised date: 2020-11-09

  Online published: 2021-05-20

Abstract

Deep eutectic solvents(DESs) have been favored by scientific researchers due to their unique properties, such as low vapor pressure, low toxicity, good designable structures, good recyclability, environment friendly and cheap, and gradually applied in the fields of extraction and separation.In the paper, the characteristics of DESs and the modes of deep eutectic solvents-dispersive liquid-liquid microextraction were introduced.The recent applications of this technique in the determination of contaminants in foods and the environment were emphatically reviewed.Based on the above discussion, future exploration and development of this technique are also proposed.

Cite this article

LIN Zhihao , ZHANG Yaohai , JIAO Bining , HAN Ke , QIN Yan . Application of deep eutectic solvents-dispersive liquid-liquid microextraction for the determination of contaminants in food and environment[J]. Food and Fermentation Industries, 2021 , 47(7) : 260 -268 . DOI: 10.13995/j.cnki.11-1802/ts.025921

References

[1] 张琰,张耀海,焦必宁.离子液体-分散液液微萃取在食品及环境污染物检测中的应用[J].食品科学,2015,36(5):250-259.
ZHANG Y,ZHANG Y H,JIAO B N.Application of ionic liquid-dispersive liquid-liquid microextraction for the determination of contaminants in foods and environment:A review[J].Food Science,2015,36(5):250-259.
[2] PAIVA A,CRAVEIRO R,AROSO I,et al.natural deep eutectic solvents-solvents for the 21 st century[J].ACS Sustainable Chemistry & Engineering,2014,2(5):1 063-1 071.
[3] KHEZELI T,DANESHFAR A,SAHRAEI R.Emulsification liquid-liquid microextraction based on deep eutectic solvent:An extraction method for the determination of benzene,toluene,ethylbenzene and seven polycyclic aromatic hydrocarbons from water samples[J].Journal of Chromatography A,2015,1 425:25-33.
[4] KARIMI M,DADFARNIA S,SHABANI A M H,et al.Deep eutectic liquid organic salt as a new solvent for liquid-phase microextraction and its application in ligandless extraction and preconcentraion of lead and cadmium in edible oils[J].Talanta,2015,144:648-654.
[5] LI G Z,ROW K H.Utilization of deep eutectic solvents in dispersive liquid-liquid micro-extraction[J].TrAC Trends in Analytical Chemistry,2019,120.DOI:10.1016/j.trac.2019.115651.
[6] LOMBA L,ZURIAGA E,GINER B.Solvents derived from biomass and their potential as green solvents[J].Current Opinion in Green and Sustainable Chemistry,2019,18:51-56.
[7] LOOW Y L,NEW E K,YANG G H,et al.Potential use of deep eutectic solvents to facilitate lignocellulosic biomass utilization and conversion[J].Cellulose,2017,24(9):3 591-3 618.
[8] TORRES-VALENZUELA L S,BALLESTEROS-GÓMEZ A,RUBIO S.Green solvents for the extraction of high added-value compounds from agri-food waste[J].Food Engineering Reviews,2020,12(1):83-100.
[9] SMITH E L,ABBOTT A P,RYDER K S.Deep eutectic solvents (DESs) and their applications[J].Chemical Reviews,2014,114(21):11 060-11 082.
[10] TORBATI M,MOHEBBI A,FARAJZADEH M A,et al.Simultaneous derivatization and air-assisted liquid-liquid microextraction based on solidification of lighter than water deep eutectic solvent followed by gas chromatography-mass spectrometry:An efficient and rapid method for trace analysis of aromatic amines in aqueous samples[J].Analytica Chimica Acta,2018,1 032:48-55.
[11] OZAK S S,YILMAZ Y.Ultrasound-assisted hydrophobic deep eutectic solvent based solid-liquid microextraction of Sudan dyes in spice samples[J].Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy,2020,236:118 353-118 360.
[12] JOUYBAN A,FARAJZADEH M A,KHOUBNASABJAFARI M,et al.Derivatization and deep eutectic solvent-based air-assisted liquid-liquid microextraction of salbutamol in exhaled breath condensate samples followed by gas chromatography-mass spectrometry[J].Journal of Pharmaceutical and Biomedical Analysis,2020,191:113 572-113 578.
[13] NOROUZI F,KHOUBNASABJAFARI M,JOUYBAN-GHARAMALEKI V,et al.Determination of morphine and oxymorphone in exhaled breath condensate samples:Application of microwave enhanced three-component deep eutectic solvent-based air-assisted liquid-liquid microextraction and derivatization prior to gas chromatography-mass spectrometry[J].Journal of Chromatography B,2020,1152:122 256-122 262.
[14] ABDI K,EZODDIN M,PIROOZNIA N.Temperature-controlled liquid-liquid microextraction using a biocompatible hydrophobic deep eutectic solvent for microextraction of palladium from catalytic converter and road dust samples prior to ETAAS determination[J].Microchemical Journal,2020,157:104 999-105 005.
[15] JIA L Y,HUANG X,ZHAO W F,et al.An effervescence tablet-assisted microextraction based on the solidification of deep eutectic solvents for the determination of strobilurin fungicides in water,juice,wine,and vinegar samples by HPLC[J].Food Chemistry,2020,317:126 424-126 430.
[16] FARAJZADEH M A,DABBAGH M S,YADEGHARI A.Deep eutectic solvent based gas-assisted dispersive liquid-phase microextraction combined with gas chromatography and flame ionization detection for the determination of some pesticide residues in fruit and vegetable samples[J].Journal of Separation Science,2017,40(10):2 253-2 260.
[17] SHIRANI M,HABIBOLLAHI S,AKBARI A.Centrifuge-less deep eutectic solvent based magnetic nanofluid-linked air-agitated liquid-liquid microextraction coupled with electrothermal atomic absorption spectrometry for simultaneous determination of cadmium,lead,copper,and arsenic in food samples and non-alcoholic beverages[J].Food Chemistry,2019,281:304-311.
[18] SHISHOV A,GERASIMOV A,NECHAEVA D,et al.An effervescence-assisted dispersive liquid-liquid microextraction based on deep eutectic solvent decomposition:Determination of ketoprofen and diclofenac in liver[J].Microchemical Journal,2020,156:104 837-104 843.
[19] FARAJZADEH M A,HOJGHAN A S,MOGADDAM M R A.Development of a new temperature-controlled liquid phase microextraction using deep eutectic solvent for extraction and preconcentration of diazinon,metalaxyl,bromopropylate,oxadiazon,and fenazaquin pesticides from fruit juice and vegetable samples followed by gas chromatography-flame ionization detection[J].Journal of Food Composition and Analysis,2018,66:90-97.
[20] BÜNYAMIN D,ADIL E,NAIL A.Determination of paracetamol in synthetic urea and pharmaceutical samples by shaker-assisted deep eutectic solvent microextraction and spectrophotometry[J].Microchemical Journal,2020,154.DOI:10.1016/j.microc.2020.104645.
[21] TEKIN Z,UNUTKAN T,ERULAS F,et al.A green,accurate and sensitive analytical method based on vortex assisted deep eutectic solvent-liquid phase microextraction for the determination of cobalt by slotted quartz tube flame atomic absorption spectrometry[J].Food Chemistry,2020,310:125 825-125 831.
[22] TORBATI M,FARAJZADEH M A,MOGADDAM M R A,et al.Development of microwave-assisted liquid-liquid extraction combined with lighter than water in syringe dispersive liquid-liquid microextraction using deep eutectic solvents:Application in extraction of some herbicides from wheat[J].Microchemical Journal,2019,147:1 103-1 108.
[23] DI X,ZHAO X J,GUO X L.Hydrophobic deep eutectic solvent as a green extractant for high-performance liquid chromatographic determination of tetracyclines in water samples[J].Journal of Separation Science,2020,43(15):3 129-3 135.
[24] HABIBOLLAHI M H,KARIMYAN K,ARFAEINIA H,et al.Extraction and determination of heavy metals in soil and vegetables irrigated with treated municipal wastewater using new mode of dispersive liquid-liquid microextraction based on the solidified deep eutectic solvent followed by GFAAS[J].Journal of the Science of Food and Agriculture,2019,99(2):656-665.
[25] HEIDARI H,GHANBARI-RAD S,HABIBI E.Optimization deep eutectic solvent-based ultrasound-assisted liquid-liquid microextraction by using the desirability function approach for extraction and preconcentration of organophosphorus pesticides from fruit juice samples[J].Journal of Food Composition and Analysis,2020,87:103 389-103 395.
[26] ALTUNAY N,ELIK A,GÜRKAN R.A novel,green and safe ultrasound-assisted emulsification liquid phase microextraction based on alcohol-based deep eutectic solvent for determination of patulin in fruit juices by spectrophotometry[J].Journal of Food Composition and Analysis,2019,82:103 256-103 264.
[27] TORBATI M,FARAJZADEH M A,MOGADDAM M R A,et al.Deep eutectic solvent based homogeneous liquid-liquid extraction coupled with in-syringe dispersive liquid-liquid microextraction performed in narrow tube;Application in extraction and preconcentration of some herbicides from tea[J].Journal of Separation Science,2019,42(9):1 768-1 776.
[28] NASSER M,MOHAMMADALI T,ALI F M,et al.Synthesis and characterization of phosphocholine chloride-based three-component deep eutectic solvent:Application in dispersive liquid-liquid microextraction for determination of organothiophosphate pesticides[J].Journal of the Science of Food and Agriculture,2020,100(6):2 364-2 371.
[29] PIAO H L,JIANG Y X,QIN Z C,et al.Application of an in-situ formulated magnetic deep eutectic solvent for the determination of triazine herbicides in rice[J].Talanta,2021,222:121 527-121 533.
[30] JOUYBAN A,FARAJZADEH M A,AFSHAR MOGADDAM M R.Dispersive liquid-liquid microextraction based on solidification of deep eutectic solvent droplets for analysis of pesticides in farmer urine and plasma by gas chromatography-mass spectrometry[J].Journal of Chromatography B,2019,1 124:114-121.
[31] JI Y H,MENG Z R,ZHAO J,et al.Eco-friendly ultrasonic assisted liquid-liquid microextraction method based on hydrophobic deep eutectic solvent for the determination of sulfonamides in fruit juices[J].Journal of Chromatography A,2020,1 609:460 520-460 529.
[32] YU K L,YUE M E,XU J,et al.Determination of fluoroquinolones in milk,honey and water samples by salting out-assisted dispersive liquid-liquid microextraction based on deep eutectic solvent combined with MECC[J].Food Chemistry,2020,332:127 371-127 377.
[33] HE T T,ZHOU T,WAN Y Q,et al.A simple strategy based on deep eutectic solvent for determination of aflatoxins in rice samples[J].Food Analytical Methods,2020,13(2):542-550.
[34] HE T T,ZHOU T,WAN H,et al.One-step deep eutectic solvent strategy for efficient analysis of aflatoxins in edible oils[J].Journal of the Science of Food and Agriculture,2020,100(13):4 840-4 848.
[35] LIU W,ZHANG K D,YU J J,et al.A green ultrasonic-assisted liquid-liquid microextraction based on deep eutectic solvent for the HPLC-UV determination of TBHQ in edible oils[J].Food Analytical Methods,2017,10(9):3 209-3 215.
[36] GE D D,WANG Y,JIANG Q,et al.A deep eutectic solvent as an extraction solvent to separate and preconcentrate parabens in water samples using in situ liquid-liquid microextraction[J].Journal of the Brazilian Chemical Society,2019,30(6):1 203-1 210.
[37] FARAJI M.Determination of some red dyes in food samples using a hydrophobic deep eutectic solvent-based Vortex assisted dispersive liquid-liquid microextraction coupled with high performance liquid chromatography[J].Journal of Chromatography A,2019,1 591:15-23.
[38] SHI Y Y,LI X,SHANG Y,et al.Effective extraction of fluorescent brightener 52 from foods by in situ formation of hydrophobic deep eutectic solvent[J].Food Chemistry,2020,311:125 870-125 876.
[39] OZAK S S,YILMAZ Y.Ultrasound-assisted hydrophobic deep eutectic solvent based solid-liquid microextraction of Sudan dyes in spice samples[J].Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy,2020,236:118 353-118 360.
[40] YILMAZ E,SOYLAK M.Ultrasound assisted-deep eutectic solvent based on emulsification liquid phase microextraction combined with microsample injection flame atomic absorption spectrometry for valence speciation of chromium(III/VI) in environmental samples[J].Talanta,2016,160:680-685.
[41] SOROURADDIN S M,FARAJZADEH M A,DASTOORI H.Development of a dispersive liquid-liquid microextraction method based on a ternary deep eutectic solvent as chelating agent and extraction solvent for preconcentration of heavy metals from milk samples[J].Talanta,2020,208:120 485-120 492.
[42] NAEBI M,JAMSHIDI M A,FARAJZADEH M A,et al.In-process prepared deep eutectic solvent based homogeneous liquid-liquid microextraction for the determination of irgaphos 168 and irganox 1010 in polypropylene packed drinks[J].Journal of Separation Science,2020,43(14):2 850-2 857.
[43] ZHANG K,LIU C,LI S Y,et al.A hydrophobic deep eutectic solvent based vortex-assisted liquid-liquid microextraction for the determination of formaldehyde from biological and indoor air samples by high performance liquid chromatography[J].Journal of Chromatography A,2019,1589:39-46.
[44] SOROURADDIN S M,FARAJZADEH M A,OKHRAVI T.Development of dispersive liquid-liquid microextraction based on deep eutectic solvent using as complexing agent and extraction solvent:Application for extraction of heavy metals[J].Separation Science and Technology,2020,55(16):2 955-2 966.
[45] ALOTHMAN Z A,HABILA M A,YILMAZ E,et al.A novel deep eutectic solvent microextraction procedure for enrichment,separation and atomic absorption spectrometric determination of palladium at ultra-trace levels in environmental samples[J].Measurement,2020,153:107 394-107 398.
[46] FLORINDO C,BRANCO L C,MARRUCHO I M.Quest for green-solvent design:From hydrophilic to hydrophobic (deep) eutectic solvents[J].Chemsuschem,2019,12(8):1 549-1 559.
[47] SHISHOV A,GORBUNOV A,MOSKVIN L,et al.Decomposition of deep eutectic solvents based on choline chloride and phenol in aqueous phase[J].Journal of Molecular Liquids,2020,301:112 380-112 384.
[48] CELEBI A T,VLUGT T J H,MOULTOS O A.Structural,thermodynamic,and transport properties of aqueous reline and ethaline solutions from molecular dynamics simulations[J].Journal of Physical Chemistry B,2019,123(51):11 014-11 025.
[49] MARYAM S,HAKIM F,HAMIDREZA S,et al.Sustainable and green microextraction of organophosphorus flame retardants by a novel phosphonium-based deep eutectic solvent[J].Journal of Separation Science,2020,43(2):452-461.
[50] FARAJZADEH M A,SOHRABI H,MOHEBBI A,et al.Combination of a modified quick,easy,cheap,efficient,rugged,and safe extraction method with a deep eutectic solvent based microwave-assisted dispersive liquid-liquid microextraction:Application in extraction and preconcentration of multiclass pesticide residues in tomato samples[J].Journal of Separation Science,2019,42(6):1 273-1 280.
[51] ASGHAR M,AFSHAR M M R,ALI F M,et al.A three-phase solvent extraction system combined with deep eutectic solvent-based dispersive liquid-liquid microextraction for extraction of some organochlorine pesticides in cocoa samples prior to gas chromatography-electron capture detector[J].Journal of Separation Science,2020,43(18):3 674-3 682.
[52] 王素利, 郭振幅,庚丽丽.基于低共熔溶剂的液-液微萃取技术测定食用油中的新烟碱类杀虫剂[J/OL].食品科学,2020.
WANG S L,GUO Z F,GENG L L.The liquid phase microextraction technology based on deep eutectic solvent for determination of new neonicotinoid insecticide in edible oil[J/OL].Food Science,2020.
[53] YUVALI D,SEYHANEYILDIZI M,SOYLAK M,et al.An environment-friendly and rapid liquid-liquid microextraction based on new synthesized hydrophobic deep eutectic solvent for separation and preconcentration of erythrosine (E127) in biological and pharmaceutical samples[J].Spectrochimica Acta Part A:Molecular and Biomolecular Spectroscopy,2021,244:118 842-118 847.
Outlines

/