A high performance liquid chromatography (HPLC) method for simultaneous determination of formaldehyde and acetaldehyde migration in aluminum bottle packaging was established, and the migration law of formaldehyde and acetaldehyde in aluminum bottle packaging to food simulants (volume fraction was 4% acetic acid, 10% ethanol, 20% ethanol, 50% ethanol) was studied at different time and temperature. The results showed that the method had a good linear relationship in the determination range of formaldehyde and acetaldehyde with all of the correlation coefficient R2 > 0.999. Moreover, the detection limit was 0.000 8-0.007 8 mg/L. And the standard recovery and precision was 80.22%-107.41% and 0.17%-6.57% respectively. The migration of formaldehyde in aluminum bottles was much larger than that of acetaldehyde. The migration of formaldehyde in aluminum bottles to different simulants was as follows: 4% acetic acid > 50% ethanol > 20% ethanol > 10% ethanol. The aluminum bottles migrated acetaldehyde from the 4% acetic acid solution, but did not move acetaldehyde from the other three food simulants. Besides, with the increase of temperature and the extension of time, the migration of formaldehyde and acetaldehyde gradually increased until reaching their equilibrium.
ZHAO Qianqian
,
GAO Hongbo
,
QIU Kai
,
LIU Bing
,
WU Gang
,
ZHANG Yuling
,
XU Tongtong
,
TU Zhenhua
. Simultaneous determination of formaldehyde acetaldehyde in aluminum bottles and their migration laws[J]. Food and Fermentation Industries, 2021
, 47(17)
: 265
-271
.
DOI: 10.13995/j.cnki.11-1802/ts.026693
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