Development of multi-nano phase change cold storage material and its application in edible fungi preservation

  • ZHAN Li ,
  • LIN Yang ,
  • LIU Liming ,
  • SHAO Ping ,
  • SUN Peilong ,
  • CHEN Hangjun
Expand
  • 1(College of Food Science and Engineering, Zhejiang University of Technology, Hangzhou 310000, China)
    2(Institute of Food Science, Zhejiang Academy of Agricultural Sciences, Hangzhou 310021, China)

Received date: 2020-11-06

  Revised date: 2020-12-11

  Online published: 2021-10-18

Abstract

In order to explore the influence of inorganic nanoparticles on the thermal properties of organic phase change nanofluids, mannitol aqueous solution was chosen as the main energy storage agent, added titanium dioxide nanoparticle with different mass fractions, and prepared TiO2 phase change cold storage material with super absorbent polymer (SAP) as the carrier. The oneset temperature and phase change enthalpy of the PCMs were measured by differential scanning calorimeter, and its properties were tested by a T-t curve and freeze-thaw cycles. Furthermore, the PCMs were applied to the preservation of Agaricus bisporus.The results showed that the addition of titanium dioxide nanoparticles enhanced the phase change enthalpy of nanofluid and the best additive amount was 0.01% . The developed PCMs (mannitol 0.5%, titanium dioxide nanoparticle 0.01%, SAP 0.3%, the rest was water) had an oneset temperature of -0.45 ℃, phase change enthalpy of 303.01 J/g with no supercooling or phase separation phenomenon. In the Agaricus bisporus preservation application, the addition of the developed PCMs in foam boxes could effectively control the temperature of 0-5 ℃ for up to 35 h. It indicated that the developed PCMs of TiO2 phase change storage material had good cool storage capacity. At 22 ℃, the color, the weight loss rate, the hardness, the soluble solids and the membrane permeability of Agaricus bisporus could be better maintained, and the senescence of Agaricus bisporus could be delayed.

Cite this article

ZHAN Li , LIN Yang , LIU Liming , SHAO Ping , SUN Peilong , CHEN Hangjun . Development of multi-nano phase change cold storage material and its application in edible fungi preservation[J]. Food and Fermentation Industries, 2021 , 47(18) : 215 -223 . DOI: 10.13995/j.cnki.11-1802/ts.026089

References

[1] LIU Y S, YANG Y Z.Investigation of specific heat and latent heat enhancement in hydrate salt based TiO2 nanofluid phase change material[J].Applied Thermal Engineering, 2017, 124:533-538.
[2] LIU C Z, RAO Z H, ZHAO J T, et al.Review on nanoencapsulated phase change materials:Preparation, characterization and heat transfer enhancement[J].Nano Energy, 2015, 13:814-826.
[3] 应铁进, 苏党, 白家玮.用于非冷冻低温区运输的复合有机物相变蓄冷剂[J].农业机械学报, 2017, 48(8):309-314.
YING T J, SU D, BAI J W.Organic phase change compound materials for non-freezing cold chain[J].Transations of the Chinese Society for Agricultural Machinery, 2017, 48(8):309-314.
[4] BARKALINA N, CHARALAMBOUS C, JONES C, et al.Nanotechnology in reproductive medicine:Emerging applications of nanomaterials[J].Nanomedicine Nanotechnology Biology & Medicine, 2014, 10(5):921-938.
[5] LYU S H, TING S, LIU J J, et al.Use of graphene oxide nanosheets to regulate the microstructure of hardened cement paste to increase its strength and toughness[J].CrystEngComm, 2014, 16(36):8 508-8 516.
[6] LIU Y S, YU K Y, YANG Y Z, et al.Size effects of nano-rutile TiO2 on latent heat recovered of binary eutectic hydrate salt phase change material[J].Thermochimica Acta, 2020, 684:178492.
[7] SALYAN S, SURESH S.Study of thermo-physical properties and cycling stability of d-Mannitol-copper oxide nanocomposites as phase change materials[J].Journal of Energy Storage, 2018, 15:245-255.
[8] 张楠, 朱子雄.保鲜处理对双孢蘑菇品质的影响研究综述[J].甘肃农业科技, 2017 (9):63-68.
ZHANG N, ZHU Z X.Research summary of effects of fresh-keeping treatments on quality of Agaricus bisporus[J].Gansu Agricultural Science and Technology, 2017(9):63-68.
[9] 刘灿, 生吉萍, 申琳.不同成熟度双孢菇子实体主要营养元素与矿物质的光谱分析[J].光谱学与光谱分析, 2010,30(10):2 820-2 823.
LIU C, SHENG J P, SHEN L.Spectral analysis of some nutrients and minerals in Agaricus bisporus fruit bodies harvested at four different maturity stages[J].Spectroscopy and Spectral Analysis, 2010,30(10):2 820-2 823.
[10] 周振, 赵立, 郭圣伦, 等.双孢菇涂膜保鲜技术研究[J].中国果菜, 2018, 38(11):1-5;14.
ZHOU Z, ZHAO L, GUO S L, et al.Study on the technology of coating preservation of Agaricus bisporus[J].China Fruit and Vegetable, 2018, 38(11):1-5;14.
[11] 所玉红. 食用菌保鲜技术研究进展[J].乡村科技, 2017(34):74-75.
SUO Y H.Research progress in the preservation technology of edible fungi[J].Rural Science and Technology, 2017(34):74-75.
[12] 史君彦, 高丽朴, 王清, 等.食用菌保鲜技术的研究进展[J].食品工业, 2017, 38(6):278-282.
SHI J Y, GAO L P, WANG Q, et al.The last research advances in the preservation technology of edible fungi[J].The Food Industry, 2017, 38(6):278-282.
[13] 朱冰清.农产品冷链专用相变蓄冷剂的研制与初步应用[D].杭州:浙江大学, 2015.
ZHU B Q.The development of phase change materials and their application on cold chain of agriculture products[D].Hangzhou:Zhejiang University, 2015.
[14] 傅仰泉, 张帆, 李聿乔, 等.环保型蓄冷剂的制备及包装应用[J].包装与食品机械, 2018, 36(3):26-30.
FU Y Q, ZHANG F, LI Y Q, et al.Preparation and packaging application of the environment-friendly cold storage agent[J].Packaging and Food Machinery, 2018, 36(3):26-30.
[15] PECK J H, KIM J J, KANG C, et al.A study of accurate latent heat measurement for a PCM with a low melting temperature using T-history method[J].International Journal of Refrigeration, 2006, 29(7):1 225-1 232.
[16] QU T T, LI B B, HUANG X F, et al.Effect of peppermint oil on the storage quality of white button mushrooms (Agaricus bisporus) [J].Food and Bioprocess Technology, 2020, 13(3):404-418.
[17] 戚晓丽. 复合相变蓄冷剂开发及在果蔬保鲜上的应用研究[D].杭州:浙江大学, 2015.
QI X L.Development of phase-changing coolant and its application on preservation of fruit and vegetables[D].Hangzhou:Zhejiang University, 2015.
[18] 殷刚, 章志超.相变蓄冷材料的选择与相变潜热的测定[J].哈尔滨商业大学学报, 2004, 20(4):499-501.
YIN G, ZHANG Z C.Study on cold energy storage material of phase-change and mensuration of phase-change potential heat[J].Journal of Harbin University of Commerce, 2004, 20(4):499-501.
[19] BRIAN S E.Basic Chemical Thermodynamics[M].5th ed.London:Imperial College Press, 2013.
[20] SANGCHAY W, SIKONG L, KOOPTARNOND K.Comparison of photocatalytic reaction of commercial P25 and synthetic TiO2-AgCl nanoparticles[J].Procedia Engineering, 2012, 32:590-596.
[21] SALYAN S, SURESH S.Multi-walled carbon nanotube laden with D-Mannitol as phase change material:Characterization and experimental investigation[J].Advanced Powder Technology, 2018, 29(12):3 183-3 191.
[22] 方艺达, 李莉, 李栋, 等.基于杏鲍菇冰点的相变蓄冷剂研制与应用[J].现代食品科技, 2019, 35(12):157-165.
FANG Y D, LI L, LI D, et al.Development and application of phase change coolant for Pleurotus eryngii based on its freezing point[J].Modern Food Science and Technology, 2019, 35(12):157-165.
[23] 孔琪, 穆宏磊, 韩延超, 等.复合相变蓄冷材料的制备及对香菇贮藏品质的影响[J].食品科学, 2020, 41(15):238-246.
KONG Q, MU H L, HAN Y C, et al.Preparation of composite phase change cold storage material and its effect on storage quality of Lentinula edodes[J].Food Science, 2020, 41(15):238-246.
[24] JIANG T J, FENG L F, ZHENG X L.Effect of chitosan coating enriched with thyme oil on postharvest quality and shelf life of shiitake mushroom (Lentinus edodes)[J].Journal of Agricultural & Food Chemistry, 2012, 60(1):188-196.
[25] DU J H, FU Y C, WANG N Y.Effects of aqueous chlorine dioxide treatment on browning of fresh-cut Lotus root[J].LWT-Food Science and Technology, 2009, 42(2):654-659.
[26] DING Y, ZHU Z, ZHAO J H, et al.Effects of postharvest brassinolide treatment on the metabolism of white button mushroom (Agaricus bisporus) in relation to development of browning during storage[J].Food and Bioprocess Technology, 2016, 9(8):1 327-1 334.
[27] BICO S L S, RAPOSO M F J, MORAIS R M S C, et al.Combined effects of chemical dip and/or carrageenan coating and/or controlled atmosphere on quality of fresh-cut banana[J].Food Control, 2009, 20(5):508-514.
[28] LIU J, WU Y C, KAN J, et al.Changes in reactive oxygen species production and antioxidant enzyme activity of Agaricus bisporus harvested at different stages of maturity[J].Journal of the Science of Food and Agriculture, 2013, 93(9):2 201-2 206.
[29] 曹建康, 姜微波, 赵玉梅.果蔬采后生理生化实验指导[M].北京:中国轻工业出版社, 2007.
CAO J K, JIANG W B, ZHAO Y M.Postharvest Physiological and Biochemical Laboratory Guidance for Fruits and Vegetables[M].Beijing:China Light Industry Press, 2007.
Outlines

/