Variation of 17 mineral elements in the aging process of bamboo liquor was studied using ICP-MS. Results showed that the aging process significantly affected the content of mineral elements in bamboo liquor. At the beginning of aging, potassium content increased exponentially, reaching a peak of 330.83 mg/L at 14th day, then gradually decreased, and stabilized at about 190 mg/L after 28th day. The content changes of calcium, sodium, chromium and arsenic followed to the first-order kinetic equation, and the half-lives were 26.05 days, 9.40 days, 9.59 days and 11.92 days, respectively. Exogenous flavonoids affected the variation of mineral elements in bamboo liquor to different degrees. Treatment with 2.5 mg/mL exogenous flavonoids significantly increased the peak value of potassium content, reaching 1 044.90 mg/L at 14th day, which was 3.16 times higher than that without addition. Under the treatment of 10 mg/mL, the potassium content increased fastest and reached the peak at 10th day. Arsenic content raised with the increase of exogenous flavonoids addition, while chromium content showed an opposite trend. Except for cobalt and molybdenum, 15 mineral elements were detected in bamboo liquor, and all the contents met the requirements of relevant food limit standards.
[1] 刘宗鹤. 遂昌县志[M].杭州:浙江人民出版社, 1996:467-468.
LIU Z H.Suichang County Chronicles[M].Hangzhou:Zhejiang People's Publishing House, 1996:467-468.
[2] 陈晨, 樊玮, 张保, 等.竹酒矿质元素评价及表征品质元素筛选[J].食品与发酵工业, 2020,46 (21):195-200.
CHEN C, FAN W, ZHANG B, et al.Mineral elements and characteristic as quality markers on bamboo liquor[J].Food and Fermentation Industries, 2020, 46 (21):195-200.
[3] 刘沛龙, 唐万裕, 练顺才, 等.白酒中金属元素的测定及其与酒质的关系(上)[J].酿酒科技, 1997 (6):23-28.
LIU P L, TANG W Y, LIAN S C, et al.Determination of metal elements in liquor and its relationship with liquor quality (I)[J].Liquor-Making Science & Technology,1997 (6):23-28.
[4] 刘沛龙, 唐万裕, 练顺才, 等.白酒中金属元素的测定及其与酒质的关系(下)[J].酿酒科技, 1998 (1):12-20.
LIU P L, TANG W Y, LIAN S C, et al.Determination of metal elements in liquor and its relationship with liquor quality (Ⅱ)[J].Liquor-Making Science & Technology,1998 (1):12-20.
[5] 曹智华, 余有贵, 何红梅.中国传统白酒中微量成分的来源与作用[J].食品与机械,2018, 34 (9):191-195;219.
CAO Z H,YU Y G,HE H M.Sources and effects of trace components in traditional Chinese liquor[J].Food & Machinery, 2018, 34 (9):191-195;219.
[6] ZHU J C, CHEN F, WANG L Y, et al.Comparison of aroma-active compounds and sensory characteristics of durian (Durio zibethinus L.) wines using strains of Saccharomyces cerevisiae with odor activity values and partial least-squares regression[J].Journal of Agricultural and Food Chemistry,2015, 63 (7):1 939-1 947.
[7] QIN H, HUO D Q, ZHANG L, et al.Colorimetric artificial nose for identification of Chinese liquor with different geographic origins[J].Food Research International,2012, 45 (1):45-51.
[8] 叶萌祺, 岳田利, 高振鹏, 等.基于ICP-MS法的苹果酒发酵过程矿质元素的动态分析[J].光谱学与光谱分析, 2015,35 (1):229-233.
YE M Q, YUE T L, GAO Z P, et al.Analysis of changes in minerals contents during cider fermentation process by inductively coupled plasma mass spectrometry[J].Spectroscopy and Spectral Analysis, 2015, 35 (1):229-233.
[9] 陶勇, 徐占成, 刘孟华, 等.剑南春窖泥理化特性及矿质元素变化趋势研究[J].酿酒科技, 2011 (7):51-54.
TAO Y, XU Z C, LIU M H, et al.Study on the physiochemical properties of pit mud from Jiannanchuan pit & the change trend of its mineral elements[J].Liquor-Making Science & Technology,2011 (7):51-54.
[10] 姜忠军. 白兰地酿造工艺及质量评价指标研究[D].无锡:江南大学,2006.
JIANG Z J.The study on the technology of brandy brewing and the parameters of quality evaluation[D].Wuxi:Jiangnan University, 2006.
[11] World Health Organization.Evaluation of Certain Food Additives and Contaminants:Forty-first Report of the Joint FAO/WHO Expert Committee on Food Additives[R].Geneva,1993.
[12] 封焕英, 范少辉, 苏文会, 等.毛竹竹节矿质营养特征的研究[J].热带作物学报, 2014,35 (2):317-322.
FENG H Y, FAN S H, SU W H, et al.Nutrition characteristics of moso bamboo node[J].Chinese Journal of Tropical Crops, 2014,35 (2):317-322.
[13] MAJID M, KHAN M R, SHAH N A, et al.Studies on phytochemical, antioxidant, anti-inflammatory and analgesic activities of Euphorbia dracunculoides[J].BMC Complementary and Alternative Medicine,2015, 15(1):349.
[14] OMOLOLU P A, ROCHA J B T, KADE I J.Attachment of rhamnosyl glucoside on quercetin confers potent iron-chelating ability on its antioxidant properties[J].Experimental and Toxicologic Pathology,2011, 63 (3):249-255.
[15] BINBUGA N, HENRY W P, SCHULTZ T P.Binding of hydroxychromones with Al3+ in methanol[J].Polyhedron,2007, 26 (1):6-10.
[16] ZHANG J, YUE L, HAYAT K, et al.Purification of flavonoid from Gingko biloba extract by zinc complexation method and its effect on antioxidant activity[J].Separation and Purification Technology,2010, 71 (3):273-278.
[17] 陈翔, 童育鹏, 仇佩虹.两种黄酮与硒配合物的合成及其结构分析[J].温州医学院学报, 2009,39 (1):63-65.
CHEN X, TONG Y P, QIU P H.Synthesis and structure analysis of two complexes of flavonoids with selenium[J].Journal of Wenzhou Medical University, 2009, 39 (1):63-65.
[18] 雷毅,蒋丽娟,陈宝宝,等.不同浓度乙醇溶液杀菌效果观察[J].中国消毒学杂志,2020,37(9):656-658.
LEI Y, JIANG L J, CHEN B B, et al.Observation on the disinfection effect of different concentrations of ethanol solutions[J].Chinese Journal of Disinfection,2020,37(9):656-658.
[19] 杨跃生,简玉瑜.植物的乙醇代谢及其在农业生产上的意义[J].华南理工大学学报(自然科学版),1996,24(S1):107-111.
YANG Y S, JIAN Y Y.The role of ethanol metabolism in plants[J].Journal of South China University of Technology(Natural Science Edition),1996,24(S1):107-111.
[20] 蔡永萍. 植物生理学[M].北京:中国农业大学出版社, 2008.
CAI Y P.Plant Physiology[M].Beijing:China Agricultural University Press, 2008.
[21] 苏文会. 基于生长和养分积累规律的毛竹林施肥理论与实践研究[D].北京:中国林业科学研究院,2012.
SU W H.Fertilization theory and practice for Phyllostachys edulis stand based on growth and nutrient accumulation rules[D].Beijing:Chinese Academy of Forestry, 2012.
[22] 张大鹏,蔡春菊,范少辉,等.重金属Pb2+和Cd2+对毛竹种子萌发及幼苗早期生长的影响[J].林业科学研究,2012,25(4):500-504.
ZHANG D P, CAI C J, FAN S H, et al.Effects of Pb2+, Cd2+ on germination and seedling early growth of moso bamboo(Phyllostachys edulis) seed [J].Forest Research, 2012, 25(4): 500-504.