Preparation of high oxygen barrier protein-polysaccharide-kraft paper-based edible film composite material and its process optimization

  • WU Hao ,
  • LEI Qiao ,
  • CAO Qinglong ,
  • GAO Wenjing ,
  • WANG Zi
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  • 1(College of Food Science and Technology, Shanghai Ocean University, Shanghai 201306, China)
    2(Shanghai Engineering Research Center of Aquatic-Product Processing & Preservation, Shanghai 201306, China)
    3(Laboratory of Quality and Safety Risk Assessment for Aquatic Products on Storage and Preservation (Shanghai), Ministry of Agriculture, Shanghai 201306, China

Received date: 2021-07-23

  Revised date: 2021-08-23

  Online published: 2022-09-16

Abstract

In this study, whey protein isolate-sodium caseinate-pullulan composite colloid was compounded with kraft paper to prepare high-barrier biodegradable food packaging materials to develop alternatives to plastic-coated paper. Taking the oxygen transmission rate of the product as the objective function, the influence of factors such as the volume ratio of the film-forming composite solution, the pH value, and the amount of glycerin added was analyzed, and the process was optimized by orthogonal experiments with three factors and three levels. The results showed that when the volume ratio of whey protein isolate-sodium caseinate to pullulan was 1∶2 at pH 9 and the glycerin content was 60%, the oxygen barrier performance of the composite coated paper was the best. The transmittance was as low as 3.824 cm3/(m2·24h·0.1MPa). In addition, its water vapor transmission coefficient was 9.241×10-12 g·cm/(cm2·s·Pa), and the water contact angle and oil contact angle were 69.9°, 48.4° respectively. Meanwhile, the transverse/longitudinal tensile strength was 13.894 MPa/24.731 MPa, the transverse/longitudinal elongation at break was 8.2%/6.6%, so its performance can meet the actual packaging application requirements.

Cite this article

WU Hao , LEI Qiao , CAO Qinglong , GAO Wenjing , WANG Zi . Preparation of high oxygen barrier protein-polysaccharide-kraft paper-based edible film composite material and its process optimization[J]. Food and Fermentation Industries, 2022 , 48(16) : 175 -181 . DOI: 10.13995/j.cnki.11-1802/ts.028760

References

[1] 赵清清. 以纸代塑:走循环经济之路[J].中国包装工业, 2012(9):16.
ZHAO Q Q.Replacing plastic with paper-taking the road of circular economy[J].China Packaging Industry, 2012(9):16.
[2] RHIM J W, LEE J H, HONG S I.Increase in water resistance of paperboard by coating with poly(lactide)[J].Packaging Technology and Science, 2007, 20(6):393-402.
[3] ZHANG W W, XIAO H N, QIAN L Y.Beeswax-chitosan emulsion coated paper with enhanced water vapor barrier efficiency[J].Applied Surface Science, 2014, 300:80-85.
[4] HONG S I, RHIM J W.Preparation and properties of melt-intercalated linear low density polyethylene/clay nanocomposite films prepared by blow extrusion[J].LWT-Food and Technology, 2012, 48(1):43-51.
[5] MOHAMED S A A, EL-SAKHAWY M, EL-SAKHAWY M A M.Polysaccharides, protein and lipid -based natural edible films in food packaging:A review[J].Carbohydrate Polymers, 2020, 238:116178.
[6] JANJARASSKUL T, TANANUWONG K, PHUPOKSAKUL T, et al.Fast dissolving, hermetically sealable, edible whey protein isolate-based films for instant food and/or dry ingredient pouches[J].LWT, 2020, 134:110102.
[7] PREZ-GAGO M B, NADAUD P, KROCHTA J M.Water vapor permeability, solubility, and tensile properties of heat-denatured versus native whey protein films[J].Journal of Food Science, 1999, 64(6):1 034-1 037.
[8] SCHOU M, LONGARES A, MONTESINOS-HERRERO C, et al.Properties of edible sodium caseinate films and their application as food wrapping[J].LWT-Food and Technology, 2005, 38(6):605-610.
[9] WANG L, XUE J, ZHANG Y.Preparation and characterization of curcumin loaded caseinate/zein nanocomposite film using pH-driven method[J].Industrial Crops and Products, 2019, 130:71-80.
[10] LIN H C, WANG B J, WENG Y M.Development and characterization of sodium caseinate edible films cross-linked with genipin[J].LWT, 2020, 118:108813.
[11] OMAR-AZIZ M, KHODAIYAN F, YARMAND M S, et al.Combined effects of octenylsuccination and beeswax on pullulan films:Water-resistant and mechanical properties[J].Carbohydrate Polymers, 2021, 255:117471.
[12] KRISTO E, BILIADERIS C G, ZAMPRAKA A.Water vapour barrier and tensile properties of composite caseinate-pullulan films:Biopolymer composition effects and impact of beeswax lamination[J].Food Chemistry, 2007, 101(2):753-764.
[13] 高文婧, 雷桥, 曹庆龙, 等.普鲁兰多糖的添加对可食性复合蛋白膜的改性研究[J].包装学报, 2020, 12(3):10-15.
GAO W J, LEI Q, CAO Q L, et al.Modification of edible composite protein films by pullulan addition[J].Packaging Journal, 2020, 12(3):10-15.
[14] 孙翠焕, 王艳华, 朱万芹, 等.肉制品腐败变质原因分析[J].微生物学杂志, 2011, 31(3):106-109.
SUN C H, WANG Y H, ZHU W Q, et al.Causes analysis of deterioration of meat products[J].Journal of Microbiology, 2011, 31(3):106-109.
[15] 宋景新. 浓缩乳清蛋白/小麦交联淀粉可食膜与牛皮纸复合材料的制备及性能研究[D].长春:吉林大学, 2018.
SONG J X.Preparation and properties of composites based on whey protein concentrate/wheat crosslinked starch edible films and kraft paper[D].Changchun:Jilin University, 2018.
[16] HAN J H, KROCHTA J M.Physical properties and oil absorption of whey-protein-coated paper[J].Journal of Food Science, 2001, 66(2):294-299.
[17] 林宝凤, 杜予民, 陈亮, 等.壳聚糖涂布纸的保鲜包装特性研究[J].包装工程, 2008, 29(1):1-3.
LIN B F, DU Y M, CHEN L, et al.Study of the characteristic of fresh-keeping wrapper coated with chitosan[J].Packaging Engineering, 2008, 29(1):1-3.
[18] 郄梓含, 雷桥, 高文婧, 等.美拉德交联对乳清分离蛋白-酪蛋白酸钠-普鲁兰多糖薄膜阻隔性及抗氧化性的改性研究[J].食品与发酵工业, 2020, 46(14):70-76.
QIE Z H, LEI Q, GAO W J, et al.Modification of Maillard crosslinking on barrier and antioxidant properties of WPI-NaCas-pullulan based edible films[J].Food and Fermentation Industries, 2020, 46(14):70-76.
[19] PONCIN-EPAILLARD F, BROSSE J C, FALHER T.Cold plasma treatment:Surface or bulk modification of polymer films?[J].Macromolecules, 1997, 30(15):4 415-4 420.
[20] GOUNGA M E, XU S Y, WANG Z.Whey protein isolate-based edible films as affected by protein concentration, glycerol ratio and pullulan addition in film formation[J].Journal of Food Engineering, 2007, 83(4):521-530.
[21] BAE H J, PARK H J, HONG S I, et al.Effect of clay content, homogenization RPM, pH, and ultrasonication on mechanical and barrier properties of fish gelatin/montmorillonite nanocomposite films[J].LWT-Food and Technology, 2009, 42(6):1 179-1 186.
[22] 尹兴, 朱俊南, 陈林, 等.可食性大豆分离蛋白膜的制备及其性能研究[J].包装工程, 2020, 41(23):83-89.
YIN X, ZHU J N, CHEN L, et al.Preparation and properties of edible soy protein isolate film[J].Packaging Engineering, 2020, 41(23):83-89.
[23] 冉锐敏, 王璐瑶, 何淑蹇, 等.大豆分离蛋白膜结构与配方优化研究[J].四川农业大学学报, 2021, 39(2):166-172.
RAN R M, WANG L Y, HE S J, et al.Study on characterizes and formula a soybean protein isolate film[J].Journal of Sichuan Agricultural University, 2021, 39(2):166-172.
[24] 丁晓峰, 陈沛智, 管蓉.接触角测量技术的应用[J].分析试验室, 2008, 27(S1):72-75.
DING X F, CHEN P Z, GUAN R.Application of contact angle measurement technology[J].Chinese Journal of Analysis Laboratory, 2008, 27(S1):72-75.
[25] 章国华. 生物基涂覆牛皮纸的制备及性能研究[J].数字印刷, 2020(1):53-58.
ZHANG G H.Preparation and properties of bio-based coated kraft paper[J].Digital Printing, 2020(1):53-58.
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