Food and Fermentation Industries >

2022 , Vol. 48 >Issue 18: 198 - 204

DOI: https://doi.org/10.13995/j.cnki.11-1802/ts.029387

Application of butyric anhydride modified porous starch as Pickering emulsion stabilizer

  • LI Min ,
  • WANG Yue ,
  • GOU Lina ,
  • WANG Yuxia ,
  • ZHANG Shenggui
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  • 1(College of Science, Gansu Agricultural University, Lanzhou 730070, China)
    2(College of Food Science and Engineering, Gansu Agricultural University, Lanzhou 730070, China)

Received date: 2021-09-16

  Revised date: 2021-09-29

  Online published: 2022-10-17

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Abstract

In order to synthesize butyric anhydride modified starch with higher degree of substitution (DS) and explore its emulsification performance and emulsification stability, butyric anhydride modified porous starch (PS) with DS of 0.023-0.148 was prepared in alkaline aqueous system with enzyme modified PS as the main body and butyric acid (BA) as the guest (butyric anhydride porous starch ester, BA-PS). Then, itwas used as stabilizer to prepare Pickering emulsion. Scanning electron microscope (SEM) and N2-adsorption/desorption results showed that the PS surface was distributed with a relatively uniform hole structure. The average pore diameter was 11.13 nm and the BET was 3.914 4 m2/g. The esterified BA-PS still retains the original particle shape of PS. Moreover, Fourier transform infrared spectroscopy (FT-IR) and 1HNMR spectrum mutually confirmed the success of BA's esterification modification of PS. X-ray diffraction (XRD) showed that both PS and BA-PS retained the original crystalline form of natural starch; The Pickering emulsion results showed that after 20 days storage native starch (NS) had no emulsifying properties, and the PS obtained by enzyme modification had certain emulsifying properties. However, the emulsifying ability was limited. Meanwhile, BA-PS obtained by butyric anhydride modification the emulsification performance was much better than that of NS and PS, and with the degree of substitution increased, the emulsification ability gradually increased. The better the uniformity of the droplets of the prepared emulsion, the smaller the droplet size. This study showed that butyric acid-modified starch had better emulsification and emulsification stability. Pickering emulsion prepared with it as an emulsifier can be used for further drug or active substance delivery research.

Key words： butyric anhydride; porous starch; esterification reaction; Pickering emulsion; emulsification; emulsification stability

Cite this article

LI Min , WANG Yue , GOU Lina , WANG Yuxia , ZHANG Shenggui . Application of butyric anhydride modified porous starch as Pickering emulsion stabilizer[J]. Food and Fermentation Industries, 2022 , 48(18) : 198 -204 . DOI: 10.13995/j.cnki.11-1802/ts.029387

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