The effect of polyvinyl alcohol content on the heat-seal performance of soy protein isolate paper coating was studied. The coating liquid was prepared to coat the paper and the heat-sealing performance of the blend coating was evaluated through the differential scanning calorimetry test and the heat seal strength test. The results showed that when the mass ratio of soy protein isolate and polyvinyl alcohol is 1∶1, the melting temperature of the coating was significantly reduced. When the heat-sealing temperature was 180 °C, the heat-sealing effect was the best, and the paper substrate was uniformly torn. The effect of stearic acid mass fraction (2%, 4%, 6%, 8%, 10%) on the waterproof performance of soy protein isolate coating was also studied. Through a grafting reaction, stearic acid was grafted onto soy protein isolate. Through attenuated total reflection-Fourier transform infrared spectroscopy, it was proved that stearic acid was successfully grafted onto soy protein isolate. The waterproof performance of the coating was evaluated by Cobb value, water vapor permeability and contact angle. The results showed that when the mass fraction of stearic acid was 6%, the Cobb value decreased by 56.6%, the water vapor permeability decreased by 42.32%, and the contact angle was also significantly increased, from 46° to 87°.
SUN Lingzhi
,
LU Lixin
,
LU Lijing
,
PAN Liao
. Heat-seal and waterproof performance improvement modification of bio-based soy protein isolate paper coating[J]. Food and Fermentation Industries, 2022
, 48(23)
: 143
-148
.
DOI: 10.13995/j.cnki.11-1802/ts.030081
[1] BAZTAN J, CARRASCO A, CHOUINARD O, et al.Protected areas in the Atlantic facing the hazards of micro-plastic pollution:First diagnosis of three Islands in the Canary Current[J].Marine Pollution Bulletin, 2014, 80(1-2):302-311.
[2] KHWALDIA K, ARAB-TEHRANY E, DESOBRY S.Biopolymer coatings on paper packaging materials[J].Comprehensive Reviews in Food Science and Food Safety, 2010, 9(1):82-91.
[3] LIM W S, OCK S Y, PARK G D, et al.Heat-sealing property of cassava starch film plasticized with glycerol and sorbitol[J].Food Packaging and Shelf Life, 2020, 26:100556.
[4] TONGNUANCHAN P, BENJAKUL S, PRODPRAN T, et al.Mechanical, thermal and heat sealing properties of fish skin gelatin film containing palm oil and basil essential oil with different surfactants[J].Food Hydrocolloids, 2016, 56:93-107.
[5] PRATEEPCHANACHAI S, THAKHIEW W, DEVAHASTIN S, et al.Improvement of heat-sealing and mechanical properties of edible chitosan films via addition of gelatin and CO2 treatment of film-forming solutions[J].International Journal of Biological Macromolecules, 2019, 131:589-600.
[6] 赵欣, 管骁.大豆分离蛋白-水溶性大豆多糖可食性复合膜的制备与性质[J].食品与发酵工业, 2013, 39(7):44-49.
ZHAO X, GUAN X.Preparation and characterization of soy protein isolates and soluble soybean polysaccharides composite film[J].Food and Fermentation Industries, 2013, 39(7):44-49.
[7] KIM S J, USTUNOL Z.Thermal properties, heat sealability and seal attributes of whey protein isolate/lipid emulsion edible films[J].Journal of Food Science, 2001, 66(7):985-990.
[8] XU F J, DONG Y M, ZHANG W, et al.Preparation of cross-linked soy protein isolate-based environmentally-friendly films enhanced by PTGE and PAM[J].Industrial Crops and Products, 2015, 67:373-380.
[9] 戴胜东, 刘锐, 张民, 等.复合物质改善大豆分离蛋白膜性能研究[J].食品科技, 2014, 39(9):114-118.
DAI S D, LIU R, ZHANG M, et al.Influence of different materials on the property of soy protein isolate films[J].Food Science and Technology, 2014, 39(9):114-118.
[10] WANG Z, ZHOU J, WANG X X, et al.The effects of ultrasonic/microwave assisted treatment on the water vapor barrier properties of soybean protein isolate-based oleic acid/stearic acid blend edible films[J].Food Hydrocolloids, 2014, 35:51-58.
[11] 孙嘉临, 袁玉娇, 曾涣煌, 等.基于大豆分离蛋白的环境友好型包装材料研究进展[J].食品与发酵工业, 2019, 45(24):269-277.
SUN J L, YUAN Y J, ZENG H H, et al.Research progress of environment-friendly packaging materials based on soy protein isolate[J].Food and Fermentation Industries, 2019, 45(24):269-277.
[12] 张超, 郭晓飞, 李武, 等.脂质在大豆分离蛋白/羧甲基纤维素复合膜中分布形态研究[J].食品科技, 2015, 40(2):91-95.
ZHANG C, GUO X F, LI W, et al.Distribution of lipids in soybean protein-isolate/carboxymethylcellulose composite films[J].Food Science and Technology, 2015, 40(2):91-95.
[13] LI S Z, DONNER E, XIAO H N, et al.Preparation and characterization of soy protein films with a durable water resistance-adjustable and antimicrobial surface[J].Materials Science and Engineering:C, 2016, 69:947-955.
[14] 李路海. 涂布复合技术[M].北京:印刷工业出版社, 2011, 27-28.
LI L H.Coating Compound Technology[M].Beijing:Printing Industry Press, 2011, 27-28.
[15] SU J F, HUANG Z, YANG C M, et al.Properties of soy protein isolate/poly(vinyl alcohol) blend “green” films:Compatibility, mechanical properties, and thermal stability[J].Journal of Applied Polymer Science, 2008, 110(6):3 706-3 716.
[16] ABDORREZA M N, CHENG L H, KARIM A A.Effects of plasticizers on thermal properties and heat sealability of sago starch films[J].Food Hydrocolloids, 2011, 25(1):56-60.
[17] DAS M, CHOWDHURY T.Heat sealing property of starch based self-supporting edible films[J].Food Packaging and Shelf Life, 2016, 9:64-68.
[18] 姜燕, 唐传核, 温其标.大豆分离蛋白膜的DSC分析[J].食品与发酵工业, 2008, 34(1):28-30.
JIANG Y, TANG C H, WEN Q B.DSC analysis of soy protein isolate films[J].Food and Fermentation Industries, 2008, 34(1):28-30.