Food and Fermentation Industries >

2024 , Vol. 50 >Issue 20: 153 - 160

DOI: https://doi.org/10.13995/j.cnki.11-1802/ts.037852

Preparation and haracterization of oxidized κ-carrageenan/polyacrylamide hydrogel

  • LI Zhaoyu ,
  • LI Xiangping ,
  • YANG Shaoling ,
  • PAN Chuang ,
  • LI Chunsheng ,
  • HU Xiao ,
  • ZHAO Yongqiang ,
  • DENG Jianchao ,
  • QI Bo
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  • 1(College of Food Science and Technology, Shanghai Ocean University, Shanghai 201306, China)
    2(South China Sea Fisheries Research Institute, Chinese Academy of Fishery Sciences, Key Laboratory of Aquatic Product Processing, Guangzhou 510300, China)
    3(Affiliated TCM Hospital of Guangzhou Medical University, Guangzhou 510130, China)

Received date: 2023-11-04

  Revised date: 2023-11-28

  Online published: 2024-11-01

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Abstract

κ-Carrageenan is a macromolecular polysaccharide substance with galactose and dehydrated galactose as the main chain.It is also one of the most important edible gums.It can be used to prepare composite hydrogel with other hydrophilic polymers and has important application potential in the field of medical materials.To improve the application performance of κ-carrageenan hydrogel, in this paper, oxidized κ-carrageenan (OKC) was prepared by TEMPO/NaClO/NaBr reaction system using κ-carrageenan (KC) as the material, and then the oxidized κ-carrageenan/polyacrylamide hydrogel was prepared by chemical crosslinking method using OKC and polyacrylamide (PAM) in different mass ratio.The effect of oxidized κ-carrageenan on the application properties of hydrogel was investigated by measuring moisture content, water solubility, swelling rate, mechanical properties, infrared spectroscopy, and microstructure of hydrogel.Results showed that OKC could significantly increase the swelling rate, tensile strength, and elongation at break, and decrease the water solubility of the composite hydrogel (P<0.05), and when the ratio of OKC/PAM was 3∶4, the performance index of the composite hydrogel reached the optimal value, the moisture content of OKC3/PAM4 was 82.7%, the water solubility was 12.2%, the swelling rate was 887%, the tensile strength reached 0.223 MPa, and the elongation at break reached 448%.Infrared spectroscopy analysis showed that the C-6 alcohol hydroxyl group in κ-carrageenan was oxidized to the C-6 carboxyl group, and hydrogen bonding existed between the components of the oxidized κ-carrageenan/polyacrylamide hydrogel.Scanning electron microscope showed that the OKC/PAM hydrogel had a dense porous three-dimensional network structure with uniform and regular pore size.Therefore, OKC and PAM can be compounded to prepare hydrogel with good performance, which will provide a theoretical basis for the development of carrageenan hydrogel medical dressing.

Key words： κ-carrageenan; oxidized κ-carrageenan; polyacrylamide; hydrogel

Cite this article

LI Zhaoyu , LI Xiangping , YANG Shaoling , PAN Chuang , LI Chunsheng , HU Xiao , ZHAO Yongqiang , DENG Jianchao , QI Bo . Preparation and haracterization of oxidized κ-carrageenan/polyacrylamide hydrogel[J]. Food and Fermentation Industries, 2024 , 50(20) : 153 -160 . DOI: 10.13995/j.cnki.11-1802/ts.037852

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