The nanocellulose from the Rosa sterilis residues (RSC-NCC) was prepared by the sulfuric acid hydrolysis method. The properties of RSC-NCC were studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and differential scanning calorimetry (DSC). Meanwhile, the effect of RSC-NCC on the properties of soybean protein isolate (SPI) film was studied, and the microstructure of RSC-NCC/SPI film was analyzed by SEM, DSC, FTIR, and XRD. Results indicated that RSC-NSS had a diameter of about 10 nm and a length of about 500 nm, high crystallinity, and 100 ℃ of melting temperature, and retained the basic chemical structure of cellulose. The addition of RSC-NCC reduced the permeability and enhanced the mechanical properties of SPI film. SEM, DSC, FTIR, and XRD analysis showed that RSC-NCC and SPI had good compatibility, and the structure compactness and stability of the film were improved.
[1] 丁新泉, 刘敏超, 闫翠香.我国第三代水果产业现状与发展战略[J].广东农业科学, 2013, 40(19):206-209.
DING X Q, LIU M C, YAN C X.Study on the status of the third generation fruit industry and developing strategy[J].Guangdong Agricultural Sciences, 2013, 40(19):206-209.
[2] 王瑀, 王丹, 商士斌, 等.纳米纤维素基复合吸附材料去除水体系重金属离子的研究进展[J].化工新型材料, 2022, 50(1):51-55.
WANG Y, WANG D, SHANG S B, et al.Research progress on nanocellulose-based composite adsorbent for the removal of heavy metal ions in water[J].New Chemical Materials, 2022, 50(1):51-55.
[3] 卢天鸿. 纳米纤维素/胶原蛋白复合材料的制备与性能[D].哈尔滨:东北林业大学, 2014.
LU T H.Preparation and properties of cellulose nanofibers/collagen composite[D].Harbin:Northeast Forestry University, 2014.
[4] 薛刚. 银杏果壳纳米纤维素制备和表征及其在可食膜中的应用[D].杭州:浙江农林大学, 2021.
XUE G.Preparation and characterization of nanocellulose from Ginkgo husk and its application in edible film[D].Hangzhou:Zhejiang A & F University, 2021.
[5] 关曼, 谢晶, 薛斌, 等.柠檬酸钠对壳聚糖/大豆分离蛋白复合膜性能的影响[J].食品工业科技, 2016, 37(9):277-281.
GUAN M, XIE J, XUE B, et al.Effect of sodium citrate on properties of chitosan/soybean protein isolate composite films[J].Science and Technology of Food Industry, 2016, 37(9):277-281.
[6] YANG Z L, LUO L, FAN F Y, et al.Preparation and characterization of soy protein isolate/SiO2 nanocomposite films and their walnut oil microcapsules[J].Journal of Applied Polymer Science, 2021, 138(29):50695.
[7] 黄志成. 菠萝叶纳米纤维素/壳聚糖复合膜的制备及其性能研究[D].湛江:广东海洋大学, 2014.
HUANG Z C.Study on preparation and characterization of nano-cellulose of pineapple leaf fiber/chitosan composite film[D].Zhanjiang:Guangdong Ocean University, 2014.
[8] 罗苏芹, 戴宏杰, 黄惠华.不同制备方法对菠萝皮渣纳米纤维素的结构影响[J].包装与食品机械, 2018, 36(5):1-6.
LUO S Q, DAI H J, HUANG H H.Effect of different preparation methods on the structure of nanocellulose in pineapple peels[J].Packaging and Food Machinery, 2018, 36(5):1-6.
[9] 陈珊珊, 陶宏江, 王亚静, 等.葵花籽壳纳米纤维素/壳聚糖/大豆分离蛋白可食膜制备工艺优化[J].农业工程学报, 2016, 32(8):306-314.
CHEN S S, TAO H J, WANG Y J, et al.Process optimization of soy protein isolate-based edible films containing nanocrystalline cellulose from sunflower seed hull and chitosan[J].Transactions of the Chinese Society of Agricultural Engineering, 2016, 32(8):306-314.
[10] 孟冬玲, 刘彬, 邹琳, 等.烟草秸秆纤维素纳米晶的制备及表征分析[J].云南大学学报(自然科学版), 2021, 43(2):343-351.
MENG D L, LIU B, ZOU L, et al.Preparation and characterization of cellulose nanocrystal from tobacco straw[J].Journal of Yunnan University (Natural Sciences Edition), 2021, 43(2):343-351.
[11] 李彤, 张宏, 赵晓彤, 等.大豆分离蛋白/纳米纤维素/阿魏酸复合膜的制备及其包装性能[J].食品科学, 2020, 41(17):253-260.
LI T, ZHANG H, ZHAO X T, et al.Preparation and packaging properties of soybean protein isolate/cellulose nanofiber/ferulic acid composite film[J].Food Science, 2020, 41(17):253-260.
[12] 王明力, 赵德刚, 陈汝材, 等.纳米SiOx/单甘脂对壳聚糖保鲜涂膜改性的研究[J].食品科学, 2007, 28(3):96-99.
WANG M L, ZHAO D G, CHEN R C, et al.Study on the modification of chitosan keeping films with nano-SiOx, glycerel monostearte[J].Food Science, 2007, 28(3):96-99.
[13] 范方宇,张蕊,杨宗玲,等.纳米SiO2/阿拉伯胶复合膜的制备与性质研究[J].食品与发酵工业,2020, 46(12):147-152.
FAN F Y, ZHANG R, YANG Z L, et al.Preparation and characterization of nano-SiO2/gum Arabic film[J].Food and Fermentation Industries, 2020, 46(12):147-152.
[14] 孙海涛, 邵信儒, 姜瑞平,等.玉米磷酸酯淀粉/秸秆纤维素可食膜的制备及物理性能[J].食品科学, 2016, 37(24):21-28.
SUN H T, SHAO X R, JIANG R P, et al.Preparation and physical properties of corn distarch phosphate/corn straw cellulose edible film[J].Food Science, 2016, 37(24):21-28.
[15] LIU H Y, LIU D G, YAO F, et al.Fabrication and properties of transparent polymethylmethacrylate/cellulose nanocrystals composites[J].Bioresource Technology, 2010, 101(14):5 685-5 692.
[16] 张菲然, 黄金田.沙柳纳米纤维素的制备及表征[J].应用化工, 2018, 47(12):2 599-2 601.
ZHANG F R, HUANG J T.Preparation and characterization of salix nanocellulose[J].Applied Chemical Industry, 2018, 47(12):2 599-2 601.
[17] SUN X F, XU F, SUN R C, et al.Characteristics of degraded cellulose obtained from steam-exploded wheat straw[J].Carbohydrate Research, 2005, 340(1):97-106.
[18] 郭洪运. 棕榈纳米纤维素的制备表征及膜应用研究[D].苏州:苏州大学, 2019.
GUO H Y.Preparation and characterization of palm nanocellulose and research on its application[D].Suzhou:Soochow University, 2019.
[19] HAN Y Y, YU M, WANG L J.Soy protein isolate nanocomposites reinforced with nanocellulose isolated from licorice residue:Water sensitivity and mechanical strength[J].Industrial Crops and Products, 2018, 117:252-259.
[20] 高惠, 李瑜涛, 戴晓娟, 等.不同添加剂对可食性大豆蛋白-海藻酸钠复合膜性能的影响[J].食品安全导刊, 2020,(15):124-126.
GAO H, LI Y T, DAI X J, et al.Effects of different additives on properties of edible soybean protein-sodium alginate composite film[J].China Food Safety Magazine, 2020,(15):124-126.
[21] MARTELLI-TOSI M, MASSON M M, SILVA N C, et al.Soybean straw nanocellulose produced by enzymatic or acid treatment as a reinforcing filler in soy protein isolate films[J].Carbohydrate Polymers, 2018, 198:61-68.
[22] HAN Y, YU M, WANG L. Soy protein isolate nanocomposites reinforced with nano-cellulose isolate from licorice residue: Water sensitivity and mechanical strength[J]. In-dustrial Crops and Products, 2018, 117: 252-259.
[23] MATHEW S, ABRAHAM T E.Characterization of ferulic acid incorporated starch-chitosan blend films[J].Food Hydrocolloids, 2008, 22(5):826-835.