To explore the feasibility of maltitol instead of sucrose in frozen steamed bread dough, 0% (S100-M0), 25% (S75-M25), 50% (S50-M50), 75% (S25-M75), and 100% (S0-M100) maltitol were used to make a frozen dough, and the changes of water migration, rheology, melting characteristics, color, texture, and volatile flavor substances of steamed bread were analyzed. Results showed that after adding maltitol, the thawing loss rate of frozen dough decreased significantly. The water fluidity of frozen dough treated with S50-M50 and S25-M75 was higher and the water fluidity was lower. The melting characteristics showed that S25-M75 had the lowest enthalpy ΔH and frozen water content (Fw). Frequency scanning showed that S75-M25, S50-M50, and S25-M75 increased the viscoelasticity of dough. After frozen dough steaming, the free water content of steamed bread treated with sugar and alcohol decreased, the color of the S50-M50 and S25-M75 treatment groups was stable, and the hardness and chewiness of the S75-M25 and S0-M100 treatment groups increased significantly. The GC-MS results showed that a total of 14 aroma components were detected in the five treatment groups. Twenty-seven different aroma components were selected from all the treatment groups by projection variable importance factor (variable importance in projection, VIP), the steamed bread from the five treatment groups was classified into three groups, and S75-M25, S50-M50, and S25-M75 were grouped into one group with high similarity. To sum up, S75-M25 and S50-M50 had better protective effects on frozen dough characteristics and steamed bread quality, which could provide a theoretical reference for the application of maltitol in frozen products.
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