Comparison of physicochemical properties of corn starch-modified by different sodium metaphosphate

  • SI Meishuang ,
  • LUAN Mingran ,
  • ZHANG Jianwen ,
  • WU Xiuli
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  • (College of Food Science and Engineering, Changchun University, Changchun 130022, China)

Received date: 2022-03-09

  Revised date: 2022-04-19

  Online published: 2023-08-31

Abstract

To expand the use of corn starch, using corn starch as raw material, corn starch phosphate esters were prepared by adding different contents of sodium trimetaphosphate (STMP) and sodium hexametaphosphate (SHMP). The viscosity characteristics, freeze-thaw stability, transparency, solubility, swelling power, and digestibility of starch samples were analyzed. The molecular structure changes were also observed by Fourier transform infrared spectroscopy. Results showed that the cold paste stability and hot paste stability of STMP starch phosphate were better than those of the native starch and SHMP starch phosphate ester, however, the solubility, swelling power, and transparency of SHMP starch phosphate ester were higher than the STMP starch phosphate ester. The contents of resistant starch and freeze-thaw stability of the two starch phosphate esters were higher than raw starch. The infrared spectrum showed that the modification did not damage the basic structure of the corn starch, and the result of the deconvolution spectrum showed that the internal order degree of modified STMP corn starch phosphate esters was higher than that of SHMP corn starch phosphate esters and raw starch. The reason for the difference in the physicochemical properties of corn-modified starch from STMP and SHMP may be that the former products mainly were starch phosphate diesters, while the latter was starch phosphate monoester.

Cite this article

SI Meishuang , LUAN Mingran , ZHANG Jianwen , WU Xiuli . Comparison of physicochemical properties of corn starch-modified by different sodium metaphosphate[J]. Food and Fermentation Industries, 2023 , 49(15) : 221 -227 . DOI: 10.13995/j.cnki.11-1802/ts.031484

References

[1] XIE Y, ZHANG B, LI M N, et al.Effects of cross-linking with sodium trimetaphosphate on structural and adsorptive properties of porous wheat starches[J].Food Chemistry, 2019, 289:187-194.
[2] 安飞, 刘亚伟, 刘洁.交联程度对木薯淀粉特性的影响[J].食品科学, 2017, 38(15):101-107.
AN F, LIU Y W, LIU J.Effect of cross-linking degree on characteristics of tapioca starch[J].Food Science, 2017, 38(15):101-107.
[3] 张佳艳, 张英, 熊建文, 等.马铃薯交联淀粉的研究进展[J].粮食与油脂, 2017, 30(3):8-12.
ZHANG J Y, ZHANG Y, XIONG J W, et al.Review on cross-linked potato starch[J].Cereals & Oils, 2017, 30(3):8-12.
[4] 季佳佳. 三偏磷酸钠交联玉米淀粉的理化性质研究[D].天津:天津科技大学, 2010.
JI J J.A study on physiochemical properties of cross-linked maize starch with sodium trimetaphosphat[D].Tianjin:Tianjin University of Science & Technology, 2010.
[5] 李光磊, 李一卓, 马汉军, 等.玉米淀粉磷酸双酯的理化特性研究[J].现代食品科技, 2014, 30(3):18-22;27.
LI G L, LI Y Z, MA H J, et al.Characteristic study of phosphodiester in corn starch[J].Modern Food Science and Technology, 2014, 30(3):18-22;27.
[6] 邵华为. 芭蕉芋交联淀粉的制备及性质研究[J].中国粮油学报, 2019, 34(4):50-56.
SHAO H W.Preparation and characteristics of crosslinked Canna edulis Ker starch[J].Journal of the Chinese Cereals and Oils Association, 2019, 34(4):50-56.
[7] 郭耀东, 游新勇, 王国泽.马铃薯交联淀粉的性能分析[J].商洛学院学报, 2014, 28(2):49-52.
GUO Y D, YOU X Y, WANG G Z.The property analysis of potato cross-linking starch[J].Journal of Shangluo University, 2014, 28(2):49-52.
[8] 李明宇. 乙酰化二淀粉磷酸酯的制备及性质研究[D].哈尔滨:哈尔滨商业大学, 2013.
LI M Y.Study on preparation and characterization of acetylated distarch phosphate[D].Harbin:Harbin University of Commerce, 2013.
[9] 李玉娥, 闫舟, 王晓闻, 等.红芸豆淀粉及其变性淀粉性质比较[J].食品工业, 2019, 40(2):117-121.
LI Y E, YAN Z, WANG X W, et al.Comparative the properties of red kidney bean starch and its modified starch[J].The Food Industry, 2019, 40(2):117-121.
[10] 秦维. 不同制备方法对慈姑抗性淀粉结构及相关功能的影响[D].镇江:江苏大学, 2020.
QIN W.Influence on the structure and related functional characteristics of arrowhead(Sagittaria sagittifolia L.) resistant starch prepared by different methods[D].Zhenjiang:Jiangsu University, 2020.
[11] 薛慧, 张国治, 吕飞杰, 等.抗性淀粉测定方法的研究[J].河南工业大学学报(自然科学版), 2012, 33(4):57-60.
XUE H, ZHANG G Z, LYU F J, et al.Study on resistant starch determination methods[J].Journal of Henan University of Technology (Natural Science Edition), 2012, 33(4):57-60.
[12] KOO S H, LEE K Y, LEE H G.Effect of cross-linking on the physicochemical and physiological properties of corn starch[J].Food Hydrocolloids, 2010, 24(6-7):619-625.
[13] 方志林. 马铃薯交联淀粉的制备及理化性质的研究[D].南京:南京林业大学, 2009.
FANG Z L.Study on preparation and physicochemical properties of cross-linked potato starch[D].Nanjing:Nanjing Forestry University, 2009.
[14] 杨文英, 张盛贵, 何绍凯, 等.马铃薯磷酸酯双淀粉的制备及在无矾粉丝中的应用[J].粮食加工, 2017, 42(1):44-47.
YANG W Y, ZHANG S G, HE S K, et al.Preparation of the potato distarch phosphate and its application in alum-free vermicelli[J].Grain Processing, 2017, 42(1):44-47.
[15] 田龙, 刘亚伟.三偏磷酸钠制备小麦淀粉磷酸酯研究[J].粮食与饲料工业, 2005(1):20-21.
TIAN L, LIU Y W.Study on preparing wheat starch phosphate with sodium tripolyphosphate[J].Cereal & Feed Industry, 2005(1):20-21.
[16] 何传波. 甘薯淀粉磷酸单酯制备机理及最优参数研究[D].合肥:合肥工业大学, 2002.
HE C B.Study on mechanism and optimum parameters for the preparation of phosphate monoester of sweet potato starch[D].Hefei:Hefei University of Technology, 2002.
[17] 吴卫国, 杨泌泉, 罗泽民, 等.食用甘薯淀粉磷酸单酯的研究[J].湖南农业大学学报, 1997, 23(6):559-564.
WU W G, YANG B Q, LUO Z M, et al.Studies on edible sweet potato starch phosphate monoester[J].Journal of Hunan Agricultural University, 1997, 23(6):559-564.
[18] 寇婷婷. 直链淀粉对交联反应的影响及其在检测中的应用[D].广州:华南理工大学, 2019.
KOU T T.Influence of amylose to cross-linking reaction and its application in characterization of starch[D].Guangzhou:South China University of Technology, 2019.
[19] 袁立军. 交联酯化预糊化木薯复合变性淀粉制备及其应用研究[D].广州:华南理工大学, 2010.
YUAN L J.Preparation of tri-modified cassava starch by cross-linking and esterification pregelatinization methods and its application[D].Guangzhou:South China University of Technology, 2010.
[20] 李潮鹏. 小麦淀粉粒特性对面片流变学特性及面条品质的影响[D].郑州:河南工业大学, 2020.
LI C P.Effects of wheat starch granules properties on sheeted dough rheology and noodle quality[D].Zhengzhou:Henan University of Technology, 2020.
[21] 刘静. 板栗淀粉老化特性及抗性淀粉的制备[D].秦皇岛:河北科技师范学院, 2020.
LIU J.Aging characteristics of chestnut starch and preparation of resistant starch[D].Qinhuangdao:Hebei Normal University of Science & Technology, 2020.
[22] 高慧. 淀粉磷酸单酯的制备及毒理学安全性评价[D].合肥:合肥工业大学, 2007.
GAO H.Preparation and toxicological assessment of starch phosphate monoester[D].Hefei:Hefei University of Technology, 2007.
[23] WONGSAGONSUP R, PUJCHAKARN T, JITRAKBUMRUNG S, et al.Effect of cross-linking on physicochemical properties of tapioca starch and its application in soup product[J].Carbohydrate Polymers, 2014, 101:656-665.
[24] 李岩. 三偏磷酸钠对葛根淀粉微结构及其应用性能影响的研究[D].天津:天津大学, 2015.
LI Y.Study on the effect of sodium trimetaphosphate on the micro-structure and application properties of kudzu starch[D].Tianjin:Tianjin University, 2015.
[25] 蔡花真, 李书华, 王振丽, 等.玉米磷酸酯淀粉取代度对其特性影响研究[J].食品研究与开发, 2012, 33(4):36-41.
CAI H Z, LI S H, WANG Z L, et al.The studies for characteristics influence of substituted phosphates corn starch ester[J].Food Research and Development, 2012, 33(4):36-41.
[26] 畅新薷. 不同条件下抗性淀粉的制备及性质研究[D].天津:天津科技大学, 2019.
CHANG X R.Preparation and properties of resistant starch under different conditions[D].Tianjin:Tianjin University of Science & Technology, 2019.
[27] 牛博文, 徐薇, 张彧.不同化学方法制备的抗性淀粉理化性质及表征研究[J].食品工业科技, 2020, 41(17):19-23;31.
NIU B W, XU W, ZHANG Y.Physical and chemical properties and characterization of resistant starch prepared by different chemical methods[J].Science and Technology of Food Industry, 2020, 41(17):19-23;31.
[28] 范迎宾, 陈梦雪, 曾洁, 等.甘薯淀粉磷酸双酯消化特性研究[J].食品工业, 2017, 38(4):141-144.
FAN Y B, CHEN M X, ZENG J, et al.The digestibility in vitro of sweet potato starch phosphodiester[J].The Food Industry, 2017, 38(4):141-144.
[29] 刘燕, 王璐颖, 郑晓卫, 等.山药交联淀粉的制备与表征[J].食品研究与开发, 2020, 41(16):22-30.
LIU Y, WANG L Y, ZHENG X W, et al.Preparation and characterization of yam cross-linked starch[J].Food Research and Development, 2020, 41(16):22-30.
[30] XIE Y, LI M N, CHEN H Q, et al.Effects of the combination of repeated heat-moisture treatment and compound enzymes hydrolysis on the structural and physicochemical properties of porous wheat starch[J].Food Chemistry, 2019, 274:351-359.
[31] 黄弼晨, 张娟, 唐亚芳, 等.响应面法优化芭蕉芋淀粉磷酸单酯制备[J].食品科学, 2013, 34(4):17-22.
HUANG B C, ZHANG J, TANG Y F, et al.Optimization of preparation of phosphate monoester of Canna edulis Ker.starch by response surface methodology[J].Food Science, 2013, 34(4):17-22.
[32] 徐志海, 孙立斌, 孙丽雪, 等.交联复合变性淀粉在食品中的应用[J].黑龙江粮食, 2014(9):45-47.
XU Z H, SUN L B, SUN L X, et al.Application of cross-linked compound modified starch in food[J].Heilongjiang Grain, 2014(9):45-47.
[33] 孙平, 张骅骞, 安娜, 等.交联淀粉的检测[J].食品科学, 2007, 28(12):88-91.
SUN P, ZHANG H Q, AN N, et al.Determination methods for self-made high degree cross-linking starch[J].Food Science, 2007, 28(12):88-91.
[34] 于浩. 磷酸酯淀粉的生产及应用[J].适用技术市场, 1997, 10(7):6-9.
YU H.Production and application of phosphate starch[J].Applicable Technology Market, 1997, 10(7):6-9.
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