研究报告

再制马苏里拉干酪的玻璃化转变测定及状态图研究

  • 李红娟 ,
  • 秦爱荣 ,
  • 刘婷婷 ,
  • 李丹 ,
  • 李媛 ,
  • 李洪波 ,
  • 于景华
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  • 1(天津科技大学 食品科学与工程学院,天津,300457);
    2(妙可蓝多(天津)食品科技有限公司,天津,300462)
博士,讲师(于景华教授为通讯作者,E-mail:yujinghua@tust.edu.cn)

收稿日期: 2020-06-05

  修回日期: 2020-07-06

  网络出版日期: 2020-12-11

基金资助

国家重点研发计划(2017YFE0131800);天津市教委科研计划项目(2017 KJ005);天津市教育科学“十三五”规划课题青年专项(HEYP5015)

Determination of glass transition and state diagram of processed Mozzarella cheese

  • LI Hongjuan ,
  • QIN Airong ,
  • LIU Tingting ,
  • LI Dan ,
  • LI Yuan ,
  • LI Hongbo ,
  • YU Jinghua
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  • 1(School of Food Science and Engineering,Tianjin University of Science and Technology,Tianjin 300457,China);
    2(Miao Ke Landuo (Tianjin) Food Technology Co., Ltd.,Tianjin 300462,China)

Received date: 2020-06-05

  Revised date: 2020-07-06

  Online published: 2020-12-11

摘要

食品状态图能够对食品的贮藏稳定性进行预测,并为产品的适宜加工原料和加工工艺提供参考。再制奶酪是中国目前乳品行业热点,为深入了解再制干酪加工贮藏性质,该文研究了再制干酪的吸附等温线,构建再制干酪的状态图。结果表明,再制干酪吸附等温线为典型“J”型曲线,含有非冻结水干酪样品随着湿基含水率从0.008 g/g增大到0.068 g/g,玻璃转化温度(glass transition temperature,Tg)从71.2 ℃降低至20.6 ℃;含有冻结水干酪样品随着湿基含水率从0.22 g/g增大到0.77 g/g,Tg从-19.7 ℃降低至-29.7 ℃,再制干酪最大冻结浓缩状态的Tg为-35.5 ℃,在此状态下的固形物湿基质量分数为79%。通过状态图可以直观了解再制干酪不同状态与物料的含水率和Tg之间的关系,协助预测再制干酪在储藏过程中的稳定性,为再制干酪加工及贮藏提供理论基础。

本文引用格式

李红娟 , 秦爱荣 , 刘婷婷 , 李丹 , 李媛 , 李洪波 , 于景华 . 再制马苏里拉干酪的玻璃化转变测定及状态图研究[J]. 食品与发酵工业, 2020 , 46(21) : 75 -80 . DOI: 10.13995/j.cnki.11-1802/ts.024647

Abstract

The state chart of food can be used to predict the storage stability and provide reference for the suitable formulation and process of raw materials. Processed cheese is a popular dairy product in China. In order to understand the processing and storage properties of processed cheese, the adsorption isotherm of processed cheese was studied and a state diagram of processed cheese was built. The results showed that the adsorption isotherm of the processed cheese was a typical“J-shaped” curve. The glass transition temperature (Tg) of the cheese containing non-frozen water reduced from 71.2 ℃ to 20.6 ℃, with the wet base moisture content increased from 0.008 g/g to 0.068 g/g. Tg of the cheese containing frozen water decreased from -19.7℃ to-29.7 ℃, with the wet base moisture content increased from 0.22 g/g to 0.77 g/g. Tg of the processed cheese under maximum freezing concentration state was -35.5 ℃, with a solid wet base mass fraction of 79%. The relationship between moisture content and Tg could be visually understood through state diagram, which could help to predict the stability of processed cheese during storage and provide theoretical basis for its processing and storage.

参考文献

[1] SABLANI S S.Non-equilibrium states and glass transitions in foods:Processing effects and product-specific implications[J].Drying Technology,2017,36(9):1 143-1 144.
[2] 周顺华,刘宝林.玻璃化转变理论及其在冷冻食品中的应用[J].食品研究与开发,2001,22:69-72.
[3] PELEG M,CHINACHOTI P.On modeling changes in food and biosolids at and around their glass transition temperature range[J].Crit Rev Food Sci Nutr,1996,36(1-2):49-67.
[4] MESTE M L,CHAMPION D,ROUDAUT G,et al.Glass transition and food technology:A critical appraisal[J].Journal of Food Science,2002,67(7):2 444-2 458.
[5] 武晗, 李晓东.再制干酪贮藏期间的物理及化学变化[J].中国乳品工业,2006,34(3):35-38.
[6] 赵金红. 渗透脱水—冻结与玻璃化贮藏对芒果品质的影响及动力学模拟[D].北京:中国农业大学,2014.
[7] KING A P,NAIDUS H.The relationship between emulsion freeze-thaw stability and polymer glass transition temperature.I.A study of the polymers and copolymers of methyl methacrylate and ethyl acrylate[J].Journal of Polymer Science Polymer Symposia,2010,27(1):311-319.
[8] HOGAN S A,FAMELART M H,O'CALLAGHAN D J,et al.A novel technique for determining glass-rubber transition in dairy powders[J].Journal of Food Engineering,2010,99(1):76-82.
[9] KAWAI K,TOH M,HAGURA Y.Effect of sugar composition on the water sorption and softening properties of cookie[J].Food Chemistry,2014,145(7):772-776.
[10] 赵金红 朱温馨,姜云栋,等.芒果玻璃化转变与状态图研究[J].农业机械学报,2015,46(4):226-232.
[11] SCHUCK P,BLANCHARD E,DOLIVET A,et al.Water activity and glass transition in dairy ingredients[J].Lait,2005,85:295-304.
[12] SCHUCK P.Chapter 13-Implications of non-equilibrium states and glass transition in dairy powders[M].Non-Equilibrium States and Glass Transitions in Foods,Woodhead Publishing,2016:303-324.
[13] BENGOECHEA C,ARRACHID A,GUERRERO A,et al.Relationship between the glass transition temperature and the melt flow behavior for gluten,casein and soya[J].Journal of Cereal Science,2007,45(3):275-284.
[14] YE A Q,HEWITT S,TAYLOR S.Characteristics of rennet-casein-based model processed cheese containing maize starch:rheological properties,meltabilities and microstructures[J].Food Hydrocolloids,2009,23(4):1 220-1 227.
[15] LI R,LIN D,ROOS Y H,et al.Glass transition,structural relaxation and stability of spray-dried amorphous food solids:A review[J].Drying Technology,2019,37(3):287-300.
[16] 于华宁, 李云飞.调制初乳清粉的状态图研究[J].上海交通大学学报,2012,46(3):487-492.
[17] SAWHNEY I K,SARKAR B C,PATIL G R.Moisture sorption characteristics of dried acid casein from buffalo skim milk[J].LWT-Food Science and Technology,2011,44(2):502-510.
[18] MAUER L J,LABUZA D E S,P.T.Effect of water content,temperature and storage on the glass transition,moisture sorption characteristics and stickiness of β-asein 1 RIDFN0001 Published as paper number 99[J].International Journal of Food Properties,2009.DOI:10.1080/109429/0009524630.
[19] FAN F,ROOS Y H.Glass transition-associated structural relaxations and applications of relaxation times in amorphous food solids:a review[J].Food Engineering Reviews,2017(3):1-14.
[20] ALPIZARREYES E,CASTA O J,CARRILLONAVAS H,et al.Thermodynamic sorption analysis and glass transition temperature of faba bean (Vicia faba L.) protein[J].Journal of Food Science & Technology,2018,55(3):935-943.
[21] ROOS Y H.Glass transition temperature and its relevance in food processing[J].Annu Rev Food Sci Technol,2010,1(1):469-496.
[22] TELIS V R N,TONON R V.Chapter 16-the effects of non-equilibrium states and storage conditions on glass transitions in food[M].Non-Equilibrium States and Glass Transitions in Foods,Woodhead Publishing,2017.
[23] KALICHEVSKY M T,BLANSHARD J M V,TOKARGZUK P F.Effect of water content and sugars on the glass transition of casein and sodium caseinate[J].International Journal of Food Science & Technology,2010,28(2):139-151.
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