综述与专题评论

低温相变蓄冷材料及其应用于冷链的研究进展

  • 游辉 ,
  • 谢晶
展开
  • 1(上海海洋大学 食品学院,上海,201306)
    2(食品科学与工程国家级实验教学示范中心(上海海洋大学),上海,201306)
    3(上海冷链装备性能与节能评价专业技术服务平台,上海,201306)
    4(教育部海洋食品精深加工关键技术省部共建协同创新中心(上海),上海,201306)
硕士研究生(谢晶教授为通讯作者,E-mail:jxie@shou.edu.cn)

收稿日期: 2021-02-01

  修回日期: 2021-03-11

  网络出版日期: 2021-10-18

基金资助

国家“十三五”重点研发项目课题(2019YFD0901604);上海市科委公共服务平台建设项目(20DZ2292200)

Research progress of low temperature phase change storage materials and their applications in cold chain

  • YOU Hui ,
  • XIE Jing
Expand
  • 1(College of Food Science and Technology, Shanghai Ocean University, Shanghai 201306, China)
    2(National Experimental Teaching Demonstration Center of Food Science and Engineering (Shanghai Ocean University), Shanghai 201306, China)
    3(Shanghai Cold Chain Equipment Performance and Energy Conservation Evaluation Professional Technical Service Platform, Shanghai 201306, China)
    4(Ministry of Education Collaborative Innovation Center of Key Technologies for Deep Processing of Marine Food (Shanghai), Shanghai 201306, China)

Received date: 2021-02-01

  Revised date: 2021-03-11

  Online published: 2021-10-18

摘要

随着生鲜食品电商行业的兴起,冷链物流成为越发重要的存在,但机械制冷技术的应用场景要求高,而相变蓄冷技术可以实现跨时间和空间的能量转移,成为了冷链物流行业目前减少机械制冷能耗的重要方式之一。该文就低温有机相变蓄冷材料、低温无机相变蓄冷材料和复合低温相变蓄冷材料3个方面对-18 ℃左右相变蓄冷材料的研究进行概述,并回顾了低温相变蓄冷材料在蓄冷板冷藏车、蓄冷集装箱、冷库等冷链装备中的应用, 指出目前改善低温相变蓄冷材料的性能是该领域的研究重点,提出了在冷链应用方面还需要在蓄冷材料释冷时进行温度控制、降低运输成本等方面进一步改进。

本文引用格式

游辉 , 谢晶 . 低温相变蓄冷材料及其应用于冷链的研究进展[J]. 食品与发酵工业, 2021 , 47(18) : 287 -293 . DOI: 10.13995/j.cnki.11-1802/ts.026944

Abstract

With the spring up of the e-commerce industry of fresh foods, cold chain logistics has become more and more important. And phase change cold storage technology can realize energy transfer across time and space, which has become one of the important ways to reduce the energy consumption of mechanical refrigeration in the cold chain logistics industry. In this paper, the research of low-temperature organic phase change storage materials, low-temperature inorganic phase change storage materials and composite low-temperature phase change storage materials about -18 ℃ were summarized, and the application of low-temperature phase change storage materials in cold chain equipment such as cold storage plate refrigerated truck, cold storage container and cold storage were reviewed. It was pointed out that improving the performance of low temperature phase change cold storage materials has attracted researchers attention, and further improvement should be made in the aspects of temperature control and transportation cost reduction of cold storage materials in cold chain application.

参考文献

[1] PACE R D, PLAHAR W A, LU J Y.Status of traditional food preservation methods for selected ghanaian foods[J].Food Reviews International, 1989,5(1):1-12.
[2] ZHAO Y, ZHANG X L, XU X F, et al.Research progress of phase change cold storage materials used in cold chain transportation and their different cold storage packaging structures[J].Journal of Molecular Liquids, 2020, 319:114360.
[3] 鄢冬茂. 相变储能材料在食品冷链物流中的应用研究进展[J].制冷与空调, 2017,17(11):1-5.
YAN D M.Advances in the application of phase change energy storage materials in food cold chain logistics[J].Refrigeration&Air-Conditioning,2017,17(11):1-5.
[4] 赵晓晓, 夏铭, 管维良, 等.蓄冷技术在生鲜果蔬贮藏和运输中的研究与应用[J].保鲜与加工,2020, 20(1):217-225.
ZHAO X X, XIA M, GUAN W L,et al.Research and application of cool storage technology in storage and transportation of fresh fruits and vegetables [J].Storage and Process,2020, 20(1):217-225.
[5] ORÓ E, BARRENECHE C, FARID M M, et al.Experimental study on the selection of phase change materials for low temperature applications[J].Renewable Energy, 2013, 57:130-136.
[6] WANG C J, HE Z J, LI H L, et al.Evaluation on performance of a phase change material based cold storage house[J].Energy Procedia, 2017, 105:3 947-3 952.
[7] PEREIRA DA CUNHA J, EAMES P.Thermal energy storage for low and medium temperature applications using phase change materials—A review[J].Applied Energy, 2016, 177:227-238.
[8] ZHANG N, YUAN Y P.Synthesis and thermal properties of nanoencapsulation of paraffin as phase change material for latent heat thermal energy storage[J].Energy and Built Environment, 2020, 1(4):410-416.
[9] 姜龙, 王鹏, 张宝云, 等.有机相变储能材料的研究进展[J].化学工程与装备, 2011(3):142-143.
JIANG L, WANG P, ZHANG B Y, et al.Research progress of organic phase change energy storage materials[J].Chemical Engineering and Equipment, 2011(3):142-143.
[10] 唐娟. 新型低温相变蓄冷材料的热物性及应用研究[D].重庆:重庆大学, 2007.
TANG J.Thermal properties and applications of a new type of cold storage material with phase change at low temperature[D].Chongqing:Chongqing University, 2007.
[11] XU X F, ZHANG X L, MUNYALO J M.Key technologies and research progress on enhanced characteristics of cold thermal energy storage[J].Journal of Molecular Liquids, 2019, 278:428-437.
[12] DONG B B, LI S L, ZHANG X W, et al.Synthesis and characterization of nanoalumina and cnts-reinforced microcapsules with n-dodecane as a phase change material for cold energy storage[J].Energy&Fuels, 2020, 34(6):7 700-7 708.
[13] LI S L, DONG B B, WANG J H, et al.Synthesis and characterization of mixed alkanes microcapsules with phase change temperature below ice point for cryogenic thermal energy storage[J].Energy, 2019, 187:115898.
[14] 杨天润.基于相变材料的冷库储能系统设计及优化[D].济南:山东大学, 2018.
YANG T R.Design and optimization of the cold storage energy storage system based on phase change materials[D].Jinan:Shandong University, 2018.
[15] 黄艳, 章学来, 杨阳, 等.冷冻运输用蓄冷材料的研制及性能研究[C].第九届全国食品冷藏链大会暨第六届全国冷冻冷藏产业创新发展年会论文集.广州, 2014:183-186.
HUANG Y, ZHANG X L, YANG Y, et al.Research and development of cold storage materials for refrigerating transportation[C].Proceedings of the 9th National Food Cold Chain Conference and the 6th National Annual Conference on Innovation and Development of Frozen cold Storage Industry. Guangzhou, 2014:183-186.
[16] ORÓ E, MIRÓ L, BARRENECHE C, et al.Corrosion of metal and polymer containers for use in PCM cold storage[J].Applied Energy, 2013, 109:449-453.
[17] 刘家庆. 蓄冷式冷藏车用蓄冷材料的研制及其热性能的研究[D].哈尔滨:哈尔滨商业大学, 2014.
LIU J Q.Study on the development and thermal properties of storage material for cold storage vehicle[D].Harbin:Harbin University of Commerce, 2014.
[18] SINGH P, SHARMA R K, ANSU A K, et al.Study on thermal properties of organic phase change materials for energy storage[J].Materials Today:Proceeding, 2020,28:2 353-2 357.
[19] YANG Y, YAN H Y, SHEN H Y.Development of a low temperature phase transforming composed material for cool storage[J].Journal of Superconductivity and Novel Magnetism, 2010, 23(6):1 115-1 117.
[20] 李靖, 谢如鹤, 刘广海, 等.冷藏运输用新型低温相变材料及装备的研制[J].制冷学报, 2018, 39(4):32-37.
LI J, XIE R H, LIU G H, et al.Development of new low-temperature phase change materials and equipment used in refrigerated transportation[J].Journal of Refrigeration, 2018, 39(4):32-37.
[21] HAN B, CHOI J H, DANTZIG J A, et al.A quantitative analysis on latent heat of an aqueous binary mixture[J].Cryobiology, 2006, 52 (1):146-151.
[22] 班超方, 卢立新, 潘嘹.冷冻型复合相变蓄冷材料的制备与性能评价[J].化工新型材料, 2019, 47(5):218-221;226.
BAN C F, LU L X, PAN L.Preparation and performance evaluation of freeze type composite phase change storage material[J].New Chemical Materials, 2019, 47(5):218-221;226.
[23] LU W, LIU G Z, XING X H, et al.Investigation on ternary salt-water solutions as phase change materials for cold storage[J].Energy Procedia, 2019, 158:5 020-5 025.
[24] 张小英. 低温高分子基复合蓄冷材料的制备与性能研究[D].无锡:江南大学, 2018.
ZHANG X Y.Preparation and properties of low temperature cool storage materials with polymer matrix[D].Wuxi:Jiangnan University, 2018.
[25] 宁初明, 李燕军, 沈灿铎, 等.相变蓄冷技术在食品冷藏保鲜运输中的应用[J].科学技术与工程, 2020, 20(6):2 115-2 120.
NING C M, LI Y J, SHEN C D, et al.Application of phase change cool storage technology in food cold storage transport[J].Science Technology and Engineering, 2020, 20(6):2 115-2 120.
[26] 王会, 刘忠宝, 赵洋.用于冰箱冷冻室的相变蓄冷材料的速冻特性[J].制冷与空调(四川), 2015, 29(1):6-10.
WANG H, LIU Z B, ZHAO Y.Frozen properties of phase change cool storage material in the refrigerator freezer[J].Refrigeration and Air Conditioning (Sichuan), 2015, 29(1):6-10.
[27] 贾一鸣. 纳米复合相变蓄冷剂热物性及蓄冷特性研究[D].天津:天津商业大学, 2020.
JIA Y M.Research on thermal properties and cold storage characteristics of nano-composite phase change coolant[D].Tianjin:Tianjin University of Commerce, 2020.
[28] HE Q B, WANG S F, TONG M W, et al.Experimental study on thermophysical properties of nanofluids as phase-change material(PCM) in low temperature cool storage[J]. Energy Conversion and Management, 2012, 64(5):199-205.
[29] ZHANG S H, ZHANG X L, XU X F, et al.Experimental study on the storage and release characteristics of phase change materials with different nanomaterials as addictives[J].Heat and Mass Transfer,2020, 56(9):2 769-2 777.
[30] 章学来, 周孙希, 刘升, 等.正辛酸-月桂酸纳米复合相变材料的蓄冷特性[J].天津大学学报(自然科学与工程技术版), 2019, 52(1):71-77.
ZHANG X L, ZHOU S X, LIU S, et al.Cold storage characteristics of n-octanoic lauric acid nanocomposite phase change materials[J].Journal of Tianjin University (Science and Technology), 2019, 52(1):71-77.
[31] 贾蒲悦, 武卫东, 王益聪, 等.新型复合低温相变蓄冷材料的研制及热物性优化[J].化工学报, 2019, 70(7):2 758-2 765.
JIA P Y, WU W D, WANG Y C, et al.Preparation and thermophysical property optimization of a new composite phase change material for cold storage[J].CIEESC Journal, 2019, 70(7):2 758-2 765.
[32] 李新芳, 王先菊, 朱冬生.纳米颗粒强化相变蓄冷特性的数值模拟(英文)[J].低温工程, 2016(6):54-61.
LI X F, WANG X J, ZHU D S.Numerical simulation of cold storage characteristics of phase change enhanced by nanoparticles[J].Cryogenics, 2016(6):54-61.
[33] 戴瑨, 梁荣蓉, 罗欣,等.不同包装方式对冷鲜猪肉的保鲜效果[J].食品与发酵工业, 2014, 40(6):171-178.
DAI J, LIANG R R, LUO X, et al.Effect of different packaging methods on the quality traies of chilled pork[J].Food and Fermentation Industries, 2014, 40(6):171-178.
[34] XU X F, ZHANG X L, MUNYALO J.Simulation study on temperature field and cold plate melting of cold storage refrigerator car[J].Energy Procedia, 2017, 142:3 394-3 400.
[35] AHAMED M, MEADE O, MEDINA M A.Reducing heat transfer across the insulated walls of refrigerated truck trailers by the application of phase change materials[J].Energy Conversion and Management, 2010, 51(3):383-392.
[36] LIU M, SAMAN W, BRUNO F.Computer simulation with TRNSYS for a mobile refrigeration system incorporating a phase change thermal storage unit[J].Applied Energy, 2014,132:226-235.
[37] LIU M, SAMAN W, BRUNO F.Development of a novel refrigeration system for refrigerated trucks incorporating phase change material[J].Applied Energy, 2012, 92:336-342.
[38] LIU M,SAMAN W, BRUNO F.Validation of a mathematical model for encapsulated phase change material flat slabs for cooling applications[J]. Applied Thermal Engineering, 2011, 31(14-15):2 340-2 347.
[39] 吴学红, 王春煦, 高茂条, 等.相变蓄冷技术在食品冷链中的应用进展[J].冷藏技术, 2016, 39(3):5-11.
WU X H, WANG C X, GAO M T, et al.A review of application of phase change storage technology in the food cold chain[J].Cold Storage Technic, 2016, 9(3):5-11.
[40] 刘广海, 吴俊章, ALAN Foster, 等.GU-PCM2型控温式相变蓄冷冷藏车设计与空载性能试验[J].农业工程学报, 2019, 35(6):288-295.
LIU G H, WU J Z, ALAN F, et al.Design and No-load performance test of GU-PCM2 temperatire controlled phase change storage cold storage refrigertor[J].Transactions of the Chinese Society of Agricultural Engineering, 2019, 35(6):288-295.
[41] 刘伟, 杨洲, 段洁利, 等.蓄冷式冷藏箱降温过程的数值模拟及试验验证[J].华南农业大学学报, 2019, 40(4):119-125.
LIU W, YANG Z, DUAN J L, et al.Numerical simulation and experimental verification of cooling process in cool storage refrigerator[J].Journal of South China Agricultural University, 2019, 40(4):119-125.
[42] MOUSAZADE A, RAFEE R, VALIPOUR M S.Thermal performance of cold panels with phase change materials in a refrigerated truck[J].International Journal of Refrigeration, 2020, 120:119-126.
[43] 陈海洋, 张建一.蓄冷型运输保温箱在冷链中的应用[J].冷藏技术, 2010,33(3):12-16.
CHEG H Y, ZHANG J Y.Applications of cold type transport box in cold chain[J].Journal of Refrigeration Technology, 2010,33(3):12-16.
[44] 折弯弯, 程曦, 张洪翠, 等.蓄冷剂控温泡沫箱对常温物流莴笋尖的保鲜机理[J].食品与发酵工业, 2018, 44(3):170-178.
SHE W W, CHENG X, ZHANG H C, et al.Mechanism of coolant controlled temperature foam box in lettuce fresh keeping under normal temperature logistics and transportation[J].Food and Fermentation Industries, 2018, 44(3):170-178.
[45] 汤元睿, 谢晶, 徐慧文, 等.相变蓄冷工艺在金枪鱼冷链物流中的应用研究[J].现代食品科技, 2015, 31(1):173-178;253.
TANG Y R, XIE J, XU H W, et al.Application of cold storage phase-change technology in cold chain logistics of tuna(Thunns obesus)[J].Modern Food Science and Technology, 2015, 31(1):173-178;253.
[46] BAI B, ZHAO K, LI X F.Application research of nano-storage materials in cold chain logistics of e-commerce fresh agricultural products[J]. Results in Physics, 2019, 13:102049.
[47] DU J P, NIE B J, ZHANG Y P, et al.Cooling performance of a thermal energy storage-based portable box for cold chain applications[J].Journal of Energy Storage, 2020, 28:101238.
[48] MITKARI M S S.A survey paper on cold storage monitoring system using IoT [J].International Journal for Research in Applied Science and Engineering Technology, 2020, 8(12):642-645.
[49] YANG T R, WANG C J, SUN Q, et al.Study on the application of latent heat cold storage in a refrigerated warehouse[J]. Energy Procedia, 2017, 142:3 546-3 552.
[50] 吴丽媛, 宋文吉, 高日新, 等.基于板式冰蓄冷的冷藏库恒温特性的实验研究[J].制冷学报, 2012, 33(5):66-69.
WU L Y, SONG W J, GAO R X, et al.Experimental study on insulation characteristics of cold storage with the phase change storage system[J].Journal of Refrigeration, 2012, 33(5):66-69.
[51] 杨凤, 刘清江, 宋瑞亭, 等.顶置蓄冷板对冷库融霜时库温波动的影响[J].食品与机械, 2020,36(12):85-89.
YANG F, LIU Q J, SONG R T, et al.Effect of overhead cool storage plate on the storage temperature fluctuation in the cold storage during defrosting[J].Food & Machinery, 2020,36(12):85-89.
文章导航

/