分析与检测

橙汁与宽皮橘汁关键香气的比较及其在各自主体风味呈现中的作用

  • 周琦 ,
  • 谈安群 ,
  • 欧阳祝 ,
  • 廖洪波 ,
  • 李贵节 ,
  • 程玉娇 ,
  • 黄林华 ,
  • 王华
展开
  • 1(西南大学 柑桔研究所,重庆,400712)
    2(重庆市水产技术推广总站,重庆,401121)
    3(重庆市质量和标准化研究院,重庆,400023)
周琦硕士研究生和谈安群农艺师为共同第一作者(李贵节副教授和王华研究员为共同通讯作者,E-mail:liguijie@cric.cn;wanghua@cric.cn)

收稿日期: 2021-02-08

  修回日期: 2021-04-14

  网络出版日期: 2021-11-30

基金资助

柑桔加工综合利用集成科研基地建设项目(2 018-000403-13-01-003433);西南大学实验技术研究项目(SYJ2021018);中央高校基本科研业务费专项资金项目(XDJK2020B018,XDJK2020C026);西南大学校地合作项目(2020001040)

Comparison of key aromas between sweet orange and mandarin juices and their roles in the presentation of main flavors of the two juices

  • ZHOU Qi ,
  • TAN Anqun ,
  • OUYANG Zhu ,
  • LIAO Hongbo ,
  • LI Guijie ,
  • CHENG Yujiao ,
  • HUANG Linhua ,
  • WANG Hua
Expand
  • 1(Citrus Research Institute, Southwest University, Chongqing, 400712, China)
    2(Chongqing Fisheries Technology Extension Station, Chongqing 401121, China)
    3(Chongqing Institute of Quality and Standardization, Chongqing, 400023, China)

Received date: 2021-02-08

  Revised date: 2021-04-14

  Online published: 2021-11-30

摘要

宽皮橘汁风味不及橙汁丰富诱人,与二者香气物质的组成与含量不同有直接关系。为明确甜橙汁和宽皮橘汁各自关键香气对其主体风味的影响,筛选出两类柑橘汁各自的共性关键香气成分,并探究其对果汁产品主体风味的作用。通过顶空固相微萃取-气相色谱-质谱法对16种甜橙和20种宽皮橘汁样品的挥发性成分做定性和定量分析,采用香气活度值筛选出各自的共性关键香气并做比较分析,进一步对其进行香气重组和遗漏研究。结果表明,甜橙和宽皮橘汁分别检出共性关键香气20和14种,利用共性关键香气能够较好地还原两类柑橘汁的风味。其中对伞花烃、巴伦西亚橘烯和γ-松油烯对甜橙汁主体风味呈现起显著作用(P<0.05);α-蒎烯、癸醛和β-蒎烯对宽皮橘汁主体风味呈现起显著作用(P<0.05)。研究为改善宽皮橘汁风味品质拓宽思路并提供实验数据支撑。

本文引用格式

周琦 , 谈安群 , 欧阳祝 , 廖洪波 , 李贵节 , 程玉娇 , 黄林华 , 王华 . 橙汁与宽皮橘汁关键香气的比较及其在各自主体风味呈现中的作用[J]. 食品与发酵工业, 2021 , 47(21) : 259 -267 . DOI: 10.13995/j.cnki.11-1802/ts.027023

Abstract

The flavor of mandarin juice is not as rich and attractive as that of sweet orange juice, which is directly related to the different composition and content of aroma substances of the two citrus juices. In order to clarify the influence of the key aromas of juices on their respective main flavor, the common key aroma components of two kinds of orange juice were analyzed and screened, and their effects on the main flavor of juice products were explored in this study. Juices were extracted from 16 cultivars of sweet orange fruits and 20 cultivars of mandarin fruits. Juice volatiles was qualitatively and quantitatively analyzed by using headspace-solid-phase-microextraction-gas-chromatography-mass-spectrometry. Odor active value was used to screen out the common key aromas which were used to perform aroma recombination and omission studies. The results showed that 20 and 14 key aromas were detected in sweet orange juices and mandarin juices, respectively. A combination of these key aromas could restore the typical main flavor of each type of juice. Among them, p-cymenene, valencene and γ-terpinene had significant effects on the main flavor of sweet orange juice (P<0.05). α-pinene, decanal and β-pinene had significant effects on the main flavor of mandarin juice (P<0.05). This study broadened the idea and route of improving the flavor quality of mandarin juices and provided the corresponding experimental data support.

参考文献

[1] SELLAMI I,MALL V,SCHIEBERLE P.Changes in the key odorants and aroma profiles of Hamlin and Valencia orange juices not from concentrate (NFC) during chilled storage[J].Journal of Agricultural and Food Chemistry,2018,66(28):7 428-7 440.
[2] REN J N,TAI Y N,DONG M,et al.Characterisation of free and bound volatile compounds from six different varieties of Citrus fruits[J].Food Chemistry,2015,185:25-32.
[3] 周琦, 易鑫,欧阳祝,等.气质联用结合多元分析法比较甜橙汁与宽皮柑橘汁的香气成分差异[J].食品与发酵工业,2021,47(1):250-258.
ZHOU Q,YI X,OUYANG Z,et al.Comparing the difference of aroma components in sweet orange juice and mandarin juice using GC-MS coupled with multivariate analysis[J].Food and Fermentation Industries,2021,47(1):250-258.
[4] YU Y,BAI J H,CHEN C X,et al.Comparative analysis of juice volatiles in selected mandarins,mandarin relatives and other Citrus genotypes[J].Journal of the Science of Food and Agriculture,2018,98(3):1 124-1 131.
[5] DHARMAWAN J,KASAPIS S,CURRAN P,et al.Characterization of volatile compounds in selected Citrus fruits from Asia.Part I:Freshly-squeezed juice[J].Flavour and Fragrance Journal,2007,22(3):228-232.
[6] GONZÁLEZ-MAS M C X,RAMBLA J L,ALAMAR M C,et al.Comparative analysis of the volatile fraction of fruit juice from different Citrus species[J].PLoS One,2011,6(7):e220167.
[7] 张涵, 鲁周民,王锦涛,等.4种主要柑橘类香气成分比较[J].食品科学,2017,38(4):192-196.
ZHANG H,LU Z M,WANG J T,et al.Comparative aroma components of fruits of four main citrus varieties[J].Food Science,2017,38(4):192-196.
[8] FENG S,SUH J H,GMITTER F G,et al.Differentiation between flavors of sweet orange (Citrus sinensis) and mandarin (Citrus reticulata)[J].Journal of Agricultural and Food Chemistry,2018,66(1):203-211.
[9] CHOI Y,KIM S S,PARK K J.Changes in volatile components of satsuma mandarin (Citrus unshiu marc.) fruit during ripening stages in Korea[J].Hortscience,2019,54S(9):S214.
[10] MALL V,SELLAMI I,SCHIEBERLE P.New degradation pathways of the key aroma compound 1-penten-3-one during storage of not-from-concentrate orange juice[J].Journal of Agricultural and Food Chemistry,2018,66(42):11 083-11 091.
[11] LIU J,WAN P,XIE C F,et al.Key aroma-active compounds in brown sugar and their influence on sweetness[J].Food Chemistry,2021,345:128826.
[12] 金润楠, 李子函,赵开丽,等.基于气质联用的不同产地温州蜜柑香气成分比较分析[J].食品与发酵工业,2020,46(2):252-260.
JIN R N,LI Z H,ZHAO K L,et al.A comparative analysis of aroma components of Satsuma mandarin from different producing areas based on HS-SPME-GC-MS[J].Food and Fermentation Industries,2020,46(2):252-260.
[13] 张铭铭, 尹洪旭,邓余良,等.基于HS-SPME/GC×GC-TOFMS/OAV不同栗香特征绿茶关键香气组分分析[J].食品科学,2020,41(2):244-252.
ZHANG M M,YIN H X,DENG Y L,et al.Analysis of key odorants responsible for different chestnut-like aromas of green teas based on headspace solid-phase microextraction coupled with comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry and odor activity value[J].Food Science,2020,41(2):244-252.
[14] SHUI M Z,FENG T,TONG Y Y,et al.Characterization of key aroma compounds and construction of flavor base module of Chinese sweet oranges[J].Molecules Basel,switzertand,2019,24(13):E2384.
[15] FERREIRA V.Revisiting psychophysical work on the quantitative and qualitative odour properties of simple odour mixtures:A flavour chemistry view.Part 1:Intensity and detectability.A review[J].Flavour and Fragrance Journal,2012,27(2):124-140.
[16] COMETTO-MUNIZ J E,ABRAHAM M H.Dose-response functions for the olfactory,nasal trigeminal,and ocular trigeminal detectability of airborne chemicals by humans[J].Chemical Senses,2016,41(1):3-14.
[17] ZHOU Q,LI G J,OU-YANG Z,et al.Volatile organic compounds profiles to determine authenticity of sweet orange juice using head space gas chromatography coupled with multivariate analysis[J].Foods,2020,9(4):505.
[18] CHENG Y J,ROUSEFF R,LI G J,et al.Methanethiol,an off-flavor produced from the thermal treatment of mandarin juices:A study of Citrus sulfur volatiles[J].Journal of Agricultural and Food Chemistry,2020,68(4):1 030-1 037.
[19] GENEVA N U C U.Flavor net and human odor space[EB/OL].[2.20].http://www.flavornet.org/flavornet.html.
[20] 周琦,易鑫,欧阳祝,等.顶空固相微萃取-气相色谱-质谱联用结合多元统计法分析不同品种温州蜜柑汁的香气成分[J].食品与发酵工业,2020,46(10):248-254.
ZHOU Q,YI X,OU-YANG Z,et al.Analysis of aroma components in different satsuma juices by HS-SPME-GC-MS combined with multivariate statistical methods[J].Food and Fermentation Industries,2020,46(10):248-254.
[21] 李贵节, 张群琳,何雅静,等.三种晚熟甜橙冷磨精油挥发性及主体香气成分的比较分析[J].食品与发酵工业,2020,46(5):284-291.
LI G J,ZHANG Q L,HE Y J,et al.Comparative analysis of volatile and principal aroma components of cold-pressed oil from three varieties of late-maturing sweet oranges[J].Food and Fermentation Industries,2020,46(5):284-291.
[22] XIAO Z B,WU Q Y,NIU Y W,et al.Characterization of the key aroma compounds in five varieties of mandarins by gas chromatography-olfactometry,odor activity values,aroma recombination,and omission analysis[J].Journal of Agricultural and Food Chemistry,2017,65(38):8 392-8 401.
[23] VAN G L J.Complications of odor threshold values in air,water and other media[M].Van Setten Kwadraat:Houten,The Netherlands,2003.
[24] GAO J,WU B P,GAO L X,et al.Glycosidically bound volatiles as affected by ripening stages of Satsuma mandarin fruit[J].Food Chemistry,2018,240:1 097-1 105.
[25] WEI X,SONG M,CHEN C,et al.Juice volatile composition differences between Valencia orange and its mutant Rohde Red Valencia are associated with carotenoid profile differences[J].Food Chemistry,2018,245:223-232.
[26] 吴曲阳. 不同品种宽皮柑橘果汁特征香气成分研究[D].上海:上海应用技术大学,2017.
WU Q Y.The study of characteristic aroma compounds in mandarin (Citrus reticulata Blanco) juices[D].Shanghai:Shanghai Institute of Technology,2017.
文章导航

/