对复合型和单一型水果酿造的果酒的挥发性香气成分和感官特征进行了研究。采用顶空气相固相微萃取(headspace solid-phase micro extraction, HS-SPME)提取香气成分,并用GC-MS进行鉴定。在3种复合型果酒和1种单一型果酒中共鉴定出15种挥发性化合物。结果显示,果酒中的挥发性化合物主要是高级醇,其次是醛类和酯类。通过偏最小二乘法(partial least squares regression, PLSR)对特征呈味物质与感官属性之间的相关性进行了研究,与单一果酒W4相比,复合果酒W1、W2、W3的香气均更浓郁、更丰富。W3果酒被描述为乳酸味、乙酸味、苦味和麦芽香,与乙醛、正丁醇、正丙醇和异戊醇相关。W2果酒呈现出花香、水果香和甜味,与糠醛和异丁醇相关。W1果酒的感官描述与挥发性成分之间的相关性较弱,可能的原因之一是原料成分比较复杂,有待进一步研究。该研究可为复合果酒风味特征的研究及果酒产品的开发和推广提供有价值的参考信息。
The volatile aroma compounds and sensory characteristics in wines produced from compound and single type of fruit were investigated. The aroma compounds were extracted by headspace solid-phase micro extraction (HS-SPME) and identified by GC-MS. A total of 15 volatile compounds were identified in three compound fruit wine samples and a single-fruit wine. The main volatile compounds found in the fruit wines were higher alcohols, followed by aldehydes and esters. Partial least square regression (PLSR) was used to study the correlation between characteristic taste substances and sensory attributes. The results showed that compared with single fruit wine W4, the aroma properties of compound fruit wines W1, W2, and W3 were richer and more intense. W3 wine was described as lactic, acetate, bitter, and malt notes, which was found to be associated with acetaldehyde, 1-butanol, 1-propanol, and 3-methyl-1-butanol. W2 wine was associated with floral, fruity, and sweet, and these descriptors were related to furfural and 2-methyl-1-propanol. However, the correlation between sensory description and volatile components of W1 was weak, one possible reason was the influence of complex ingredients. This study was expected to provid valuable information for the research of compound fruit wine flavor characteristics and the development and promotion of fruit wine products.
[1] QIN Z H, PETERSEN M A, BREDIE W L P.Flavor profiling of apple ciders from the UK and Scandinavian region[J].Food Research International, 2018, 105:713-723.
[2] LEE J E, YUN J H, LEE A R, et al.Volatile components and sensory properties of jujube wine as affected by material preprocessing[J].International Journal of Food Properties, 2018, 21(1):2 052-2 061.
[3] XIAO Z B, WU Q Y, NIU Y W, et al.Characterization of the key aroma compounds in five varieties of mandarins by gas chromatography-olfactometry, odor activity values, aroma recombination, and omission analysis[J].Journal of Agricultural and Food Chemistry, 2017, 65(38):8 392-8 401.
[4] OGODO A C, UGBOGU O C, UGBOGU A E, et al.Production of mixed fruit (pawpaw, banana and watermelon) wine using Saccharomyces cerevisiae isolated from palm wine[J].SpringerPlus, 2015, 4(1):683.
[5] TSEGAY Z T, LEMMA S M.Response surface optimization of Cactus pear (Opuntia ficus-indica) with Lantana camara (L.camara) fruit fermentation process for quality wine production[J].International Journal of Food Science, 2020.DOI:10.1155/2020/8647262.
[6] KING E S, OSIDACZ P, CURTIN C, et al.Assessing desirable levels of sensory properties in Sauvignon Blanc wines- consumer preferences and contribution of key aroma compounds[J].Australian Journal of Grape and Wine Research, 2011, 17(2):169-180.
[7] STYGER G, PRIOR B, BAUER F F.Wine flavor and aroma[J].Journal of Industrial Microbiology and Biotechnology, 2011, 38(9):1 145-1 159.
[8] SUN S Y, JIANG, W G, ZHAO Y P.Comparison of aromatic and phenolic compounds in cherry wines with different cherry cultivars by HS-SPME-GC-MS and HPLC[J].International Journal of Food Science & Technology, 2012, 47(1):100-106.
[9] DE JAGER L S, PERFETTI G A, DIACHENKO G W.Comparison of membrane assisted solvent extraction, stir bar sorptive extraction, and solid phase microextraction in analysis of tetramine in food[J].Journal of Separation Science, 2009, 32(7):1 081-1 086.
[10] ANDREU-SEVILLA A J, MENA P, MARTÍ N, et al.Volatile composition and descriptive sensory analysis of pomegranate juice and wine[J].Food Research International, 2013, 54(1):246-254.
[11] WOLD S, SJÖSTRÖM M, ERIKSSON L.PLS-regression:A basic tool of chemometrics[J].Chemometrics and Intelligent Laboratory Systems.2001, 58(2):109-130.
[12] 陈义, 郭桂义, 房志杰.基于主成分分析法的信阳毛尖香气质量评价模型构建[J].河南农业科学, 2014, 43(8):142-145.
CHEN Y,GUO G Y, FANG Z J.Modeling for aroma quality evaluation of Xinyangmaojian tea based on principal component analysis[J].Journal of Henan Agricultural Sciences, 2014, 43(8):142-145.
[13] 牛云蔚, 孔佳丽, 肖作兵.基于PLSR分析樱桃酒呈味物质与感官属性之间的相关性[J].食品科学, 2018, 39(4):144-148.
NIU Y W, KONG J L, XIAO Z B.Correlation analysis between taste compounds and sensory attributes of cherry wine based on partial least squares regression[J].Food Science, 2018, 39(4):144-148.
[14] BRAGA C M, ZIELINSKI A A F, SILVA K M D, et al.Classification of juices and fermented beverages made from unripe, ripe and senescent apples based on the aromatic profile using chemometrics[J].Food Chemistry, 2013, 141(2):967-974.
[15] PAN W, JUSSIER D, TERRADE N, et al.Kinetics of sugars, organic acids and acetaldehyde during simultaneous yeast-bacterial fermentations of white wine at different pH values[J].Food Research International, 2011, 44(3):660-666.
[16] POLÁSKOVÁ P, HERSZAGE J, EBELER S E.Wine flavor:Chemistry in a glass[J].Chemical Society Reviews, 2008, 37:2 478-2 489.
[17] LI H, TAO Y S, WANG H, ZHANG L, et al.Impact odorants of Chardonnay dry white wine from Changli County[J].European Food Research and Technology, 2008, 227(1):287-292.
[18] YANG C X, WANG Y J, LIANG Z C, et al.Volatiles of grape berries evaluated at the germplasm level by headspace-SPME with GC-MS[J].Food Chemistry, 2009, 114(3):1 106-1 114.
[19] GAMERO A, HERNÁNDEZ-ORTE P, QUEROL A, et al.Effect of aromatic precursor addition to wine fermentations carried out with different ‘Saccharomyces’ species and their hybrids[J].International Journal of Food Microbiology, 2011, 147:33-44.
[20] EBELER S E. Aanlytical chemistry: Unlocking the secrets of wine flavor[J].Food Reviews International, 2001, 17:45-64.
[21] FRANCIS I L, NEWTON J L.Determining wine aroma from compositional data[J].Australian Journal of Grape and Wine Research, 2005, 11(2):114-126.
[22] PINO J A, MESA J.Contribution of volatile compounds to mango (Mangifera indica L.) aroma[J].Flavour and Fragrance Journa, 2006, 21(2):207-213.
[23] FERREIRA V, LÓPEZ R, CACHO J F, et al.Quantitative determination of the odorants of young red wines from different grape varieties[J].Journal of the Science of Food and Agriculture, 2000, 80:1 659-1 667.
[24] GIL M, CABELLOS J M, ARROYO T, et al.Characterization of the volatile fraction of young wines from the denomination of origin ‘Vinos de Madrid’[J].Analytica Chimica Acta, 2006, 563(1-2):145-153.
[25] LOSCOS N, HERNÁNDEZ-ORTE P, CACHO J, et al.Evolution of the aroma composition of wines supplemented with grape flavour precursors from different varietals during accelerated wine ageing[J].Food Chemistry, 2010, 120(1):205-216.
[26] GONZÁLEZ ALVAREZ M, GONZAÁLEZ-BARREIRO C, CANCHO-GRANDE B, et al.Relationships between Godello white wine sensory properties and its aromatic fingerprinting obtained by GC-MS[J].Food Chemistry, 2011, 129(3):890-898.
[27] XIAO Z B, YU D, NIU Y W, et al.Characterization of different aroma-types of Chinese liquors based on their aroma profile by gas chromatography-mass spectrometry and sensory evaluation[J].Flavour and Fragrance Journa, 2016, 31(3):217-227.
[28] FAULHABER S, HENER U, MOSANDL A.GC/IRMS analysis of mandarin essential Oils.2.δ13CPDB values of characteristic flavor components[J].Journal of Agricultural and Food Chemistry, 1997, 45(12):4 719-4 725.
[29] ANDREU-SEVILLA A J, MENA P, MARTÍ N, et al.Volatile composition and descriptive sensory analysis of pomegranate juice and wine[J].Food Research International, 2013, 54(1):246-254.