分析与检测

基于便携式近红外光谱仪的樱桃番茄糖分快速分析模型

  • 孙阳 ,
  • 刘翠玲 ,
  • 孙晓荣 ,
  • 闻世震
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  • (北京工商大学 人工智能学院,食品安全大数据技术北京市重点实验室,北京,100048)
硕士研究生(刘翠玲教授为通讯作者,E-mail: lclbtbu@163.com)

收稿日期: 2021-01-31

  修回日期: 2021-03-12

  网络出版日期: 2021-12-31

基金资助

国家自然科学基金(61807001);北京市自然科学基金项目(4182017)

Rapid analysis model of sugar content in cherry tomatoes based on portable near infrared spectrometer

  • SUN Yang ,
  • LIU Cuiling ,
  • SUN Xiaorong ,
  • WEN Shizhen
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  • (College of Artificial Intelligence Academy,Beijing Technology and Business University, Beijing Key Laboratory of Food Safety Big Data Technology,Beijing 100048,China)

Received date: 2021-01-31

  Revised date: 2021-03-12

  Online published: 2021-12-31

摘要

为实现对樱桃番茄糖分的现场快速无损检测,应用便携式近红外光谱仪器AMBER Ⅱ对所采集樱桃番茄的近红外光谱数据进行建模分析。实验样本共172个,利用Kennard-Stone(K-S)算法以3∶1比例划分样本集。光谱预处理选用Savitzky-Golay卷积平滑和标准归一化(standard normal variate,SNV),分别使用无信息变量消除法(uniformative variable elimination,UVE)、连续投影算法(successive projections algorithm,SPA)和无信息变量消除结合连续投影算法(UVE-SPA)3种算法进行特征波长提取,用偏最小二乘(partial least squares,PLS)方法建模,最终使用UVE-SPA算法提取得到12个特征波长点进行PLS建模的结果最佳,建模集和预测集的决定系数R2分别为0.938 5和0.934 7,建模集和预测集的均方根误差分别为0.130 5和0.174 4,相对分析误差(relative percent deviation,RPD)为2.81。研究表明,利用以上方法提取的特征波长点所建立的模型预测效果较好,说明便携式近红外光谱仪器可以应用于对樱桃番茄糖分的现场快速无损检测。

本文引用格式

孙阳 , 刘翠玲 , 孙晓荣 , 闻世震 . 基于便携式近红外光谱仪的樱桃番茄糖分快速分析模型[J]. 食品与发酵工业, 2021 , 47(23) : 214 -220 . DOI: 10.13995/j.cnki.11-1802/ts.026939

Abstract

To realize the rapid and non-destructive detection of sugar content in cherry tomato, a portable near infrared spectroscopy instrument amber II was used to build model and analyze the near infrared spectroscopy data of cherry tomato. A total of 172 experimental samples were divided into 3∶1 scale by Kennard stone (K-S) algorithm. Savitzky-Golay convolution smoothing and standard normal variable (SNV) were used for spectral preprocessing. Three algorithms, namely, uniform variable elimination (UVE), successive projections algorithm (SPA) and UVE-SPA, were used to extract characteristic wavelengths, and partial least squares (PLS) method was used to set model. Finally, 12 characteristic wavelength points extracted by UVE-SPA algorithm were used for PLS modeling, the determination coefficients of modeling set and prediction set were 0.938 5 and 0.934 7 respectively. The root mean square error of modeling set and prediction set were 0.130 5 and 0.174 4, the relative percent deviation was 2.81. The results showed that the model based on the extracted characteristic wavelength points had a good prediction effect, and the portable NIR spectrometer can be used for the rapid and nondestructive detection of sugar content in cherry tomato.

参考文献

[1] 甘霖,申琳,生吉萍.秸秆源品质改良因子采前处理对番茄果实品质的影响[J].食品科学,2013,34(4):221-225.
GAN L,SHEN L,SHENG J P.Effect of pre-harvest treatment with stalk-derived quality modification factor on tomato quality[J].Food Science,2013,34(4):221-225.
[2] 常培培,梁燕,张静,等.5种不同果色樱桃番茄品种果实挥发性物质及品质特性分析[J].食品科学,2014,35(22):215-221.
CHANG P P,LIANG Y,ZHANG J,et al.Volatile components and quality characteristics of cherry tomato from five color varieties[J].Food Science,2014,35(22):215-221.
[3] ALSHATWI A A,ALOBAAID M A,ALSEDAIRY S A,et al.Tomato powder is more protective than lycopene supplement against lipid peroxidation in rats[J].Nutrition Research,2010,30(1):66-73.
[4] RAO A V,RAO L G.Carotenoids and human health[J].Pharmacological Research,2007,55(3):207-216.
[5] FORD E S,BERGMANN M M,KRÖGER J,et al.Healthy living is the best revenge:Findings from the European prospective investigation into cancer and nutrition-potsdam study[J].Archives of Internal Medicine,2009,169(15):1 355-1 362.
[6] BLOCK G,PATTERSON B,SUBAR A.Fruit,vegetables,and cancer prevention:A review of the epidemiological evidence[J].Nutrition and Cancer,1992,18(1):1-29.
[7] BUTELLI E,TITTA L,GIORGIO M,et al.Enrichment of tomato fruit with health-promoting anthocyanins by expression of select transcription factors[J].Nature Biotechnology,2008,26(11):1 301-1 308.
[8] LIANG P S,HAFF R P,HUA S S T,et al.Nondestructive detection of zebra chip disease in potatoes using near-infrared spectroscopy[J].Biosystems Engineering,2018,166(2):161-169.
[9] MISHRA P,CORDELLA C B Y,RUTLEDGE D N,et al.Application of independent components analysis with the JADE algorithm and NIR hyperspectral imaging for revealing food adulteration[J].Journal of Food Engineering,2016,168:7-15.
[10] ORRILLO I,CRUZ-TIRADO J P,CARDENAS A,et al.Hyperspectral imaging as a powerful tool for identification of papaya seeds in black pepper[J].Food Control,2019,101(2):45-52.
[11] ABREU G F,BORÉM F M,OLIVEIRA L F C,et al.Raman spectroscopy:A new strategy for monitoring the quality of green coffee beans during storage[J].Food Chemistry,2019,287(2):241-248.
[12] LARABELL C A,NUGENT K A.Imaging cellular architecture with X-rays[J].Current Opinion in Structural Biology,2010, 20(5):623-631.
[13] MUROI Y,KURAWAKI J,HAYAKAWA K,et al.Fluorescence spectroscopy of fulvic acids’ interaction with surfactants[J].Colloid and Polymer Science,2009,287(1):57-62.
[14] 王凡,彭彦昆,汤修映,等.樱桃番茄可溶性固形物含量的可见/近红外透射光谱无损检测[J].中国食品学报,2018,18(10):235-240.
WANG F,PENG Y K,TANG X Y,et al.Near infrared nondestructive testing of soluble solids content of cherry tomato[J].Journal of Chinese Institute of Food Science and Technology,2018,18(10):235-240.
[15] 雷鹰,刘翠玲,周子彦.应用便携式近红外光谱仪研究苹果糖度的快速分析模型[J].食品科学技术学报,2018,36(6):95-100.
LEI Y,LIU C L,ZHOU Z Y.Rapid analysis model of apple sugar degree using portable near-infrared spectrometer[J].Journal of Food Science and Technology,2018,36(6):95-100.
[16] 刘伟.水果糖度便携式光谱无损检测方法研究[D].南昌:华东交通大学,2011.
LIU W.Portable near infrared test device fruit nondestructive testing research[D].Nanchang:East China Jiaotong University,2011.
[17] 赵建涛,张静,张雅婷,等.红色和粉色樱桃番茄与大果番茄果实品质特性分析[J].食品科学,2016,37(16):135-141.
ZHAO J T,ZHANG J,ZHANG Y T,et al.Analysis of fruit quality traits and volatiles in red and pink cherry and large-fruited tomato accessions[J].Food Science,2016,37(16):135-141.
[18] CENTNER V,MASSART D L,DE NOORD O E,et al.Elimination of uninformative variables for multivariate calibration[J].Analytical Chemistry,1996,68(21):3 851-3 858.
[19] 成忠,张立庆,刘赫扬,等.连续投影算法及其在小麦近红外光谱波长选择中的应用[J].光谱学与光谱分析,2010,30(4):949-952.
CHENG Z,ZHANG L Q,LIU H Y,et al.Successive projections algorithm and its application to selecting the wheat near-infrared spectral variables[J].Spectroscopy and Spectral Analysis,2010,30(4):949-952.
[20] 刘思伽,田有文,张芳,等.采用二次连续投影法和BP人工神经网络的寒富苹果病害高光谱图像无损检测[J].食品科学,2017,38(8):277-282.
LIU S J,TIAN Y W,ZHANG F,et al.Hyperspectral imaging for nondestructive detection of Hanfu apple diseases using successive projections algorithm and BP neural network[J].Food Science,2017,38(8):277-282.
[21] 宁井铭,颜玲,张正竹,等.祁门红茶加工中氨基酸和儿茶素快速检测模型建立[J].光谱学与光谱分析,2015,35(12):3 422-3 426.
NING J M,YANG L,ZHANG Z Z,et al.Rapid and dynamic determination models of amino acids and catechins concentrations during the processing rocedures of Keemun black tea[J].Spectroscopy and Spectral Analysis,2015,35(12):3 422-3 426.
[22] 张亚坤,罗斌,宋鹏,等.基于近红外光谱的大豆叶片可溶性蛋白含量快速检测[J].农业工程学报,2018,34(18):187-193.
ZHANG Y K,LUO B,SONG P,et al.Rapid determination of soluble protein content for soybean leaves based on near infrared spectroscopy[J].Transactions of the Chinese Society of Agricultural Engineering,2018,34(18):187-193.
[23] 段宇飞,王巧华,马美湖,等.基于LLE-SVR的鸡蛋新鲜度可见/近红外光谱无损检测方法[J].光谱学与光谱分析,2016,36(4):981-985.
DUAN F Y,WANG Q H,MA M H,et al.Study on non-destructive detection method for egg freshness based on LLE-SVR and visible/near-infrared spectrum[J].Spectroscopy and Spectral Analysis,2016,36(4):981-985.
[24] 于雷,洪永胜,周勇,等.高光谱估算土壤有机质含量的波长变量筛选方法[J].农业工程学报,2016,32(13):95-102.
YU L,HONG Y S,ZHOU Y,et al.Wavelength variable selection methods for estimation of soil organic matter content using hyperspectral technique[J].Transactions of the Chinese Society of Agricultural Engineering,2016,32(13):95-102.
[25] LI Y,GUO Y,LIU C,et al.SPA combined with swarm intelligence optimization algorithms for wavelength variable selection to rapidly discriminate the adulteration of apple juice[J].Food Analytical Methods,2017,10(6):1 965-1 971.
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