食品与发酵工业 >

2022 , Vol. 48 >Issue 7: 258 - 263

DOI: https://doi.org/10.13995/j.cnki.11-1802/ts.029077

分析与检测

高灵敏测定市售饮料酒中的矿物油污染物

  • 刘玲玲 ,
  • 李冰宁 ,
  • 杨梦奇 ,
  • 杨明 ,
  • 武彦文
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  • 1(北京市科学技术研究院 分析测试研究所(北京市理化分析测试中心),北京,100094)
    2(北京市食品安全测试工程技术研究中心,北京,100094)
硕士,高级工程师(武彦文研究员为通信作者,E-mail:wuyanwen@bcpca.ac.cn)

收稿日期: 2021-08-20

  修回日期: 2021-10-17

  网络出版日期: 2022-04-27

基金资助

北京市科学技术研究院北科萌芽计划项目(BGS202104);北京市改革与发展专项项目(2021ZL0111)

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Highly sensitivity determination of mineral oil hydrocarbons in commercial alcoholic beverages

  • LIU Lingling ,
  • LI Bingning ,
  • YANG Mengqi ,
  • YANG Ming ,
  • WU Yanwen
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  • 1(Institute of Analysis and Testing,Beijing Academy of Science and Technology(Beijing Center for Physical and Chemical Analysis),Beijing100094,China)
    2(Beijing Food Safety Analysis and Testing Engineering Research Center,Beijing100094,China)

Received date: 2021-08-20

  Revised date: 2021-10-17

  Online published: 2022-04-27

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摘要

采用液液萃取和高效液相色谱-气相色谱联用建立了白酒、啤酒和葡萄酒中微量饱和烃矿物油(mineral oil saturated hydrocarbons,MOSH)和芳香烃矿物油(mineral oil aromatic hydrocarbons,MOAH)的高灵敏度测定方法,方法的定量限为0.05 mg/L,加标回收率为87%～107%,相对标准偏差为1.9%～4.9%。应用该方法调查了市售17个饮料酒(其中白酒9个,啤酒和葡萄酒各4个)中的矿物油污染情况。结果表明:所有啤酒和葡萄酒样品均未检出矿物油,但有5个白酒被检出MOSH,质量浓度为0.06～2.74 mg/L;其中2个检出MOAH,分别为0.11和1.24 mg/L;这些阳性样品的矿物油含量与酒精度呈正相关,其部分污染可能来自包装金属罐。

关键词： 白酒; 矿物油; 高效液相色谱-气相色谱联用; 酒精度; 金属罐

本文引用格式

刘玲玲 , 李冰宁 , 杨梦奇 , 杨明 , 武彦文 . 高灵敏测定市售饮料酒中的矿物油污染物[J]. 食品与发酵工业, 2022 , 48(7) : 258 -263 . DOI: 10.13995/j.cnki.11-1802/ts.029077

Abstract

Liquid-liquid extraction combined with on-line coupled high performance liquid chromatography-gas chromatography was proposed for highly sensitive determination of trace mineral oil saturated hydrocarbons (MOSH) and aromatic hydrocarbons (MOAH) in Baijiu, beer and wine. The limit of quantification (LOQ) was 0.05 mg/L, the recovery was 87%-107% and the relative standard deviation (RSD) was 1.9%-4.9%. The results showed that no contaminants were detected in all beer and wine samples. MOSH were detected in five Baijiu samples with contents ranging from 0.06 to 2.74 mg/L. MOAH of 0.11 and 1.24 mg/L were detected in two Baijiu samples, respectively. The contamination of these positive samples was positively correlated with the alcohol contents which might come from the packaging metal cans.

Key words： Baijiu; mineral oil hydrocarbons; on-line coupled high performance liquid chromatography-gas chromatography (HPLC-GC); alcohol content; metal can

参考文献

[1] BIEDERMANN M,GROB K.How “white” was the mineral oil in the contaminated Ukrainian sunflower oils?[J].European Journal of Lipid Science and Technology,2009,111(4):313-319.
[2] EFSA PANEL ON CONTAMINANTS IN THE FOOD CHAIN (CONTAM).Scientific opinion on mineral oil hydrocarbons in food[J].EFSA Journal,2012,10(6):2704.
[3] BRATINOVA S,HOEKSTRA E.Guidance on sampling,analysis and data reporting for the monitoring of mineral oil hydrocarbons in food and food contact materials[J].Luxembourg:Publications Office of the European Union,2019,DOI:10.2760/208879.
[4] GRUNDBÖCK F,FISELIER K,SCHMID F,et al.Mineral oil in sunflower seeds:The sources[J].European Food Research and Technology,2010,231(2):209-213.
[5] BIEDERMANN M,INGENHOFF J E,BARBANERA M,et al.Migration of mineral oil into noodles from recycled fibres in the paperboard box and the corrugated board transport box as well as from printing inks:A case study[J].Packaging Technology and Science,2011,24(5):281-290.
[6] COMMISSION OF THE EUROPEAN Union.Commission Recommendation(EU) 2017/84 of 16 January 2017 on the monitoring of mineral oil hydrocarbons in food and in materials and articles intended to come into contact with food[J].Official Journal of the European Union,2017,L12:95-96.
[7] VAN HEYST A,VANLANCKER M,VERCAMMEN J,et al.Analysis of mineral oil in food:Results of a Belgian market survey[J].Food Additives & Contaminants:Part A,2018,35(10):2 062-2 075.
[8] HOCHEGGER A,MORET S,GEURTS L,et al.Mineral oil risk assessment:Knowledge gaps and roadmap.Outcome of a multi-stakeholders workshop[J].Trends in Food Science & Technology,2021,113:151-166.
[9] BRÜHL L.Occurrence,determination,and assessment of mineral oils in oilseeds and vegetable oils[J].European Journal of Lipid Science and Technology,2016,118(3):361-372.
[10] LIU L L,HUANG H,WU Y W,et al.Offline solid-phase extraction large-volume injection-gas chromatography for the analysis of mineral oil-saturated hydrocarbons in commercial vegetable oils[J].Journal of Oleo Science,2017,66(9):981-990.
[11] 刘玲玲,李冰宁,欧阳杰,等.高效液相色谱-气相色谱联用法测定稻谷和大米中的饱和烃矿物油[J].食品科学,2019,40(16):302-307.
LIU L L,LI B N,OUYANG J,et al.Determination of mineral oil-saturated hydrocarbons in paddy and rice by on-line high performance liquid chromatography-gas chromatography[J].Food Science,2019,40(16):302-307.
[12] LIU L L,LI B N,OUYANG J,et al.Mild mixed-solvent extraction for determination of total mineral oil hydrocarbon contaminants in milk powder products[J].Food Chemistry,2020,333:127488.
[13] 谢尧卿,刘玲玲,李冰宁,等.基于液相色谱-气相色谱联用测定巧克力中的饱和烃与芳香烃矿物油[J].食品科学,2021,42(12):288-294.
XIE Y Q,LIU L L,LI B N,et al.Determination of mineral oil saturated hydrocarbons and aromatic hydrocarbons in chocolate by on-line liquid chromatography-gas chromatography[J].Food Science,2021,42(12):288-294.
[14] WAN J J,ZHANG S C,LIU L L,et al.Contribution of packaging materials to MOSH and POSH contamination of milk powder products during storage[J].Food Additives& Contaminants:Part A,2021,38(6):1 034-1 043.
[15] LIU L L,LI B N,YANG D Y,et al.Survey of mineral oil hydrocarbons in Chinese commercial complementary foods for infants and young children[J].Food Additives & Contaminants:Part A,2021,38(9):1 441-1 455.
[16] CASTLE L,KELLY M,GILBERT J.Migration of mineral hydrocarbons into foods.1.Polystyrene containers for hot and cold beverages[J].Food Additives & Contaminants,1991,8(6):693-699.
[17] JICKELLS S M,NICHOL J,CASTLE L.Migration of mineral hydrocarbons into foods.5.Miscellaneous applications of mineral hydrocarbons in food contact materials[J].Food Additives & Contaminants,1994,11(3):333-341.
[18] VOSS H G J,MENDES J J A,FARINELLI M E,et al.A prototype to detect the alcohol content of beers based on an electronic nose[J].Sensors,2019,19(11):2646.
[19] 李国辉,高红波,吕志远,等.酒精度快速测定仪测定饮料酒酒精度[J].食品与发酵工业,2019,45(1):197-201.
LI G H,GAO H B,LV Z Y,et al.A rapid alcohol tester for determination alcohol strengths of alcoholic beverages[J].Food and Fermentation Industries,2019,45(1):197-201.
[20] BIEDERMANN M,GROB K.On-line coupled high performance liquid chromatography-gas chromatography for the analysis of contamination by mineral oil.Part 1:Method of analysis[J].Journal of Chromatography A,2012,1 255:56-75.
[21] 武彦文,李冰宁,刘玲玲,等.基于高效液相色谱-气相色谱联用技术的矿物油分析研究进展[J].分析化学,2021,49(3):341-349.
WU Y W,LI B N,LIU L L,et al.Research progress of analysis of mineral oil hydrocarbons using on-line high performance liquid chromatography coupled with gas chromatography[J].Chinese Journal of Analytical Chemistry,2021,49(3):341-349.
[22] ARCELLA D,BAERT K,BINAGLIA M.Rapid risk assessment on the possible risk for public health due to the contamination of infant formula and follow-on formula by mineral oil aromatic hydrocarbons(MOAH)[J].EFSA Supporting Publications,2019,16(11):1741E.
[23] BIEDERMANN-BREM S,KASPRICK N,SIMAT T,et al.Migration of polyolefin oligomeric saturated hydrocarbons(POSH) into food[J].Food Additives & Contaminants:Part A,2012,29(3):449-460.
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