研究报告

超声改性对壳聚糖/淀粉复合膜特性的影响

  • 裴诺 ,
  • 杜宇凡 ,
  • 孙洁 ,
  • 汪之和
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  • 1(上海海洋大学 食品学院,上海,201306)
    2(国家淡水水产品加工技术研发分中心(上海),上海,201306)
    3(上海水产品加工及贮藏工程技术研究中心,上海,201306)
第一作者:硕士研究生(汪之和教授为通信作者,E-mail:zhwang@shou.edu.cn)

收稿日期: 2021-09-05

  修回日期: 2021-10-09

  网络出版日期: 2022-10-17

基金资助

国家重点研发计划项目(2019YFD0902003)

Effect of ultrasonic modification on properties of chitosan/starch composite membrane

  • PEI Nuo ,
  • DU Yufan ,
  • SUN Jie ,
  • WANG Zhihe
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  • 1(College of Food Science and Technology, Shanghai Ocean University, Shanghai 201306, China)
    2(National Freshwater Aquatic Products Processing Technology Research and Development Center (Shanghai),Shanghai 201306, China)
    3(Shanghai Engineering Research Center of Aquatic Products Processing and Preservation, Shanghai 201306, China)

Received date: 2021-09-05

  Revised date: 2021-10-09

  Online published: 2022-10-17

摘要

壳聚糖/淀粉复合膜作为一种绿色环保的包装材料已被广泛应用于食品包装,但其力学性能较弱的特点限制了其应用范围。该文利用超声对壳聚糖/淀粉复合膜进行改性,比较了不同超声频率改性后的复合膜的力学性能、阻隔性能、表面结构、二级结构、热稳定性以及生物活性,旨在探究不同超声条件对复合膜特性的影响。结果表明,复合膜的抗拉强度及断裂伸长率随着超声强度的增加呈现先增强后减弱的趋势。经过28 kHz超声处理后的复合膜,抗拉强度能提升157%;二级结构、微观结构、热稳定结果也显示其具有更加稳定的内部结构;且其抑菌性及抗氧化性也优于其他组。该研究证明了超声改性能提高复合膜性能,研究结果为壳聚糖/淀粉复合膜的有效应用提供理论基础。

关键词: 超声; 壳聚糖; 淀粉; 复合膜

本文引用格式

裴诺 , 杜宇凡 , 孙洁 , 汪之和 . 超声改性对壳聚糖/淀粉复合膜特性的影响[J]. 食品与发酵工业, 2022 , 48(18) : 88 -94 . DOI: 10.13995/j.cnki.11-1802/ts.029293

Abstract

As a green packaging material, chitosan/starch composite film has been widely used in food packaging, but the weak mechanical properties limit its application. In this paper, chitosan/starch composite membrane was modified by ultrasonic, and then the mechanical properties, barrier properties, surface structure, secondary structure, thermal stability and biological activity of the composite membrane modified by different ultrasonic frequencies were compared. The results showed that the tensile strength and elongation at break of the composite films increased first and then decreased with the increase of ultrasonic intensity. After 28 kHz ultrasonic treatment, the tensile strength of the composite film increased by 157%. Secondary structure, microstructure and thermal stability results also showed that it had a more stable internal structure. The bacteriostasis and antioxidant activity were better than other groups. This study proved that ultrasonic modification could improve the properties of composite membrane, and provided a theoretical basis for the effective application of chitosan/starch composite membrane.

参考文献

[1] AKTER N, KHAN R A, TUHIN M O, et al.Thermomechanical, barrier, and morphological properties of chitosan-reinforced starchbased biodegradable composite films[J].Journal of Thermoplastic Composite Materials, 2014, 27(7):933-948.
[2] GARCÍA-RAMÓN J A, CARMONA-GARCÍA R, VALERA-ZARAGOZA M, et al.Morphological, barrier, and mechanical properties of banana starch films reinforced with cellulose nanoparticles from plantain Rachis[J].International Journal of Biological Macromolecules, 2021, 187:35-42.
[3] SILVA A O, CUNHA R S, HOTZA D, et al.Chitosan as a matrix of nanocomposites:A review on nanostructures, processes, properties, and applications[J].Carbohydrate Polymers, 2021, 272:118472.
[4] 裴诺, 施文正, 汪之和.壳聚糖与生物保鲜剂复合使用在水产品保鲜中的研究进展[J].食品工业科技, 2022,43(5):448-454.
PEI N, SHI W Z, WANG Z H.Research progress in the application of chitosan and biological preservative in aquatic products preservation[J].Science and Technology of Food Industry, 2022,43(5):448-454.
[5] SÁNCHEZ-ORTEGA I, GARCÍA-ALMENDÁREZ B E, SANTOS-LÓPEZ E M, et al.Characterization and antimicrobial effect of starch-based edible coating suspensions[J].Food Hydrocolloids, 2016, 52:906-913.
[6] PINZON M I, GARCIA O R, VILLA C C.The influence of Aloe vera gel incorporation on the physicochemical and mechanical properties of banana starch-chitosan edible films[J].Journal of the Science of Food and Agriculture, 2018, 98(11):4 042-4 049.
[7] CHOO K W, LIN M S, MUSTAPHA A.Chitosan/acetylated starch composite films incorporated with essential oils:Physiochemical and antimicrobial properties[J].Food Bioscience, 2021, 43:101287.
[8] CHENG L, HAO Y L, SONG X S, et al.Effects of chitosan and nano titanium dioxide on the mechanical, physicochemical and antibacterial properties of corn starch films[J].Journal of Macromolecular Science, 2021,60(8):616-630.
[9] ABLOUH E H, JALAL R, RHAZI M, et al.Surface modification of α-chitin using an acidic treatment followed by ultrasonication:Measurements of their sorption properties[J].International Journal of Biological Macromolecules, 2020, 151:492-498.
[10] 张奎亮, 代养勇, 侯汉学, 等.超声处理对马铃薯淀粉结构特性及理化性质的影响[J].食品科学, 2018, 39(5):128-134.
ZHANG K L, DAI Y Y, HOU H X, et al.Effect of ultrasonic treatment on structure and physicochemical properties of potato starch[J].Food Science, 2018, 39(5):128-134.
[11] 肖力源, 余国贤, 雷晏琳, 等.玉米淀粉/壳聚糖/魔芋葡甘露聚糖复合膜的制备及物性研究[J].中国粮油学报, 2018, 33(4):86-92;100.
XIAO L Y, YU G X, LEI Y L, et al.Preparation and properties of corn starch/chitosan/konjac glucomannan composite membrane[J].Journal of the Chinese Cereals and Oils Association, 2018, 33(4):86-92;100.
[12] 张立挺, 蒋子文, 高磊, 等.壳聚糖明胶可食用复合膜的制备与抗菌性能研究[J].食品研究与开发, 2020, 41(6):106-111;180.
ZHANG L T, JIANG Z W, GAO L, et al.Preparation and antimicrobial properties of the edible food packaging film composited by chitosan and gelatin[J].Food Research and Development, 2020, 41(6):106-111;180.
[13] 王圣. 花青素活性智能包装膜研制及其对猪肉的保鲜与新鲜度检测[D].镇江:江苏大学, 2017.
WANG S.Development of active and intelligent film by using anthocyanins for preservation and detection of pork freshness[D].Zhenjiang:Jiangsu University, 2017.
[14] QU W J, ZHANG X X, HAN X, et al.Structure and functional characteristics of rapeseed protein isolate-dextran conjugates[J].Food Hydrocolloids, 2018, 82:329-337.
[15] PELISSARI F M, GROSSMANN M V E, YAMASHITA F, et al.Antimicrobial, mechanical, and barrier properties of cassava starch-chitosan films incorporated with oregano essential oil[J].Journal of Agricultural & Food Chemistry, 2009, 57(16):7 499-7 504.
[16] 李念, 陈露珠, 安鑫, 等.三种虾壳中虾青素提取工艺优化及其抗氧化活性比较[J].上海海洋大学学报, 2022,31(1):298-308.
LI N, CHEN L Z, AN X, et al.Optimization of extraction process of astaxanthin from three kinds of shrimp shells and comparison of antioxidant activity[J].Journal of Shanghai Ocean University, 2022,31(1):298-308.
[17] 麦馨允, 陈庆金, 谭彦妮, 等.魔芋葡甘聚糖/纳米SiO2复合涂膜配方及其对芒果贮藏品质的影响[J].食品与发酵工业, 2018, 44(1):177-184.
MAI X Y, CHEN Q J, TAN Y N, et al.Effect of konjac glucomannan/nano-silica composite coating on the quality of mango fruit[J].Food and Fermentation Industries, 2018, 44(1):177-184.
[18] YUAN D, MENG H C, HUANG Q, et al.Preparation and characterization of chitosan-based edible active films incorporated with Sargassum pallidum polysaccharides by ultrasound treatment[J].International Journal of Biological Macromolecules, 2021, 183:473-480.
[19] 张欣欣. 没食子酸改性超声辅助金枪鱼皮胶原蛋白-壳聚糖膜的制备及应用研究[D].镇江:江苏大学, 2019.
ZHANG X X.The preparation and application of gallic acid modified and ultrasound assisted films from tuna skin collagen-chitosan[D].Zhenjiang:Jiangsu University, 2019.
[20] 赵晓彤, 徐丽娜, 张宏, 等.超声辅助提高大豆蛋白纳米复合膜包装性能及其保鲜应用[J].食品科学, 2020, 41(19):230-237.
ZHAO X T, XU L N, ZHANG H, et al.Ultrasonic treatment for improved properties of soybean protein nanocomposite packaging film and its application in preservation of cherry tomatoes[J].Food Science, 2020, 41(19):230-237.
[21] 陈颖, 陈勉, 王辙, 等.几种淀粉的相对分子质量分布,微晶结构及形貌的研究[J].中国粮油学报, 2014, 29(3):19-23.
CHEN Y, CHEN M, WANG Z, et al.Molecular weight distribution, structures and microscopic morphology of several different starches[J].Journal of the Chinese Cereals and Oils Association, 2014, 29(3):19-23.
[22] CHENG L, HAO Y L, SONG X H, et al.Effects of chitosan and nano titanium dioxide on the mechanical, physicochemical and antibacterial properties of corn starch films[J].Journal of Macromolecular Science, 2021, 60(8):616-630.
[23] YANG J W, LIANG G Q, XIANG T, et al.Effect of crosslinking processing on the chemical structure and biocompatibility of a chitosan-based hydrogel[J].Food Chemistry, 2021, 354:129476.
[24] LIU P F, GAO W Z, ZHANG X L, et al.Effects of ultrasonication on the properties of maize starch/stearic acid/ sodium carboxymethyl cellulose composite film[J].Ultrasonics Sonochemistry, 2021, 72:105447.
[25] 李庆治,顾晓华,张达升, 等.茶多酚改性PBC/PLA/CS可降解复合纤维膜的制备和研究[J].齐齐哈尔大学学报(自然科学版), 2021, 37(3):48-52.
LI Q Z, GU X H, ZHANG D S, et al.Preparation and research of tea polyphenol modified PBC/PLA/CS degradable composite fiber membrane[J].Journal of Qiqihar University (Natural Science Edition),2021, 37(3):48-52.
[26] 宫贵贞, 冯迪, 堵锡华, 等.柑橘皮纤维素/聚磷酸铵/三聚氰胺/聚乙烯醇复合膜的制备及其性能[J].塑料工业, 2020, 48(6):172-177.
GONG G Z, FENG D, DU X H, et al.Preparation and properties of citrus peel cellulose/ammonium polyphosphate/melamine/polyvinyl alcohol composite membrane[J].China Plastics Industry, 2020, 48(6):172-177.
[27] ABD EL-HACK M E, EL-SAADONY M T, SHAFI M E, et al.Antimicrobial and antioxidant properties of chitosan and its derivatives and their applications:A review[J].International Journal of Biological Macromolecules, 2020, 164:2 726-2 744.
[28] 董泽义, 谭丽菊, 王江涛.壳聚糖保鲜膜研究进展[J].食品与发酵工业, 2014, 40(6):147-151.
DONG Z Y, TAN L J, WANG J T.The present situation of chitosan film[J].Food and Fermentation Industries, 2014, 40(6):147-151.
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