Please wait a minute...
 
 
食品与发酵工业  2019, Vol. 45 Issue (1): 210-218    DOI: 10.13995/j.cnki.11-1802/ts.017126
  分析与检测 本期目录 | 过刊浏览 | 高级检索 |
玉米冻藏过程中挥发性成分变化及主成分分析
徐瑞1,李洪军1,2,贺稚非1,2*
1(西南大学 食品科学学院,重庆,400716)
2(重庆市特色食品工程技术研究中心,重庆,400716)
Changes and principal component analysis of volatile compounds in corn ears during frozen storage
XU Rui1, LI Hongjun1,2,HE Zhifei1,2*
1(College of Food Science, Southwest University, Chongqing 400715, China)
2(Chongqing Engineering Research Center of Regional Food, Chongqing 400715, China)
下载:  HTML   PDF (1402KB) 
输出:  BibTeX | EndNote (RIS)      
摘要 为研究冻藏温度和时间对玉米挥发性风味的影响,采用顶空-固相微萃取(HS-SPME)结合气相色谱-质谱联用技术(GC-MS),分别对在-4、-18、-40 ℃条件下冻藏1、2、3个月的玉米样品进行分析,为玉米贮藏保鲜提供理论指导。研究表明:随着贮藏时间的增加,当贮藏温度为-4 ℃和-18 ℃时,烃类物质相对含量先增加后减少,醇类物质种类数量及相对含量均不断增加,酮类物质种类数量不断减少;当贮藏温度为-18 ℃与-40 ℃时,醛、酸、酯类物质相对含量先减少后增加。此外,当贮藏时间为1个月时,贮藏温度越低,烃类、酮类物质种类数量越多,相对含量越小;当贮藏时间为3个月时,贮藏温度越低,烃、酮、酯类物质相对含量越大,醛类物质种类数量和相对含量越小。随后,选取63种主要挥发性成分进行主成分分析,挥发性成分主要指向醛、酮、酯类物质,棕榈酸乙酯、癸醛、2,3-辛二酮、4-甲基二苯甲酮、辛醛、植烷、癸二酸二壬酯、棕榈酸异丙酯、邻苯二甲酸二异丁酯、十四酸异丙酯是玉米挥发性成分的主要特征化合物。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
徐瑞
李洪军
贺稚非
关键词:  玉米  冻藏  挥发性风味  顶空固相萃取  气质联用  主成分分析    
Abstract: In order to study the effects of storage temperature and duration on the volatility of corn, HS-SPME and GC-MS were used to detect the volatile flavor in corns stored at -4 ℃, -18 ℃, and -40 ℃ for 1, 2, 3 months. This provides a theoretical guidance for storing and preserving corn ears. This research showed that with prolonged storage time, the relative contents of hydrocarbons increased first and then decreased at -4 ℃ and -18 ℃. The quantities and relative contents of alcohols increased continuously, while the amounts of ketones decreased continuously. When the storage temperature was -18 ℃ and -40 ℃, the relative contents of aldehydes, acids, and esters decreased first and then increased. In addition, when the storage pericd was 1 month, the lower the storage temperature, the greater the quantities of hydrocarbons and ketones, but their relative contents were smaller. When the storage period was 3 months, the lower the storage temperature, the greater the relative contents of hydrocarbons, ketones, and esters, and the amounts and relative contents of aldehydes were smaller. Then, 63 major volatile compounds were selected for principal component analysis. The volatile compounds were mainly aldehydes, ketones, esters. Ethyl palmitate, decanal, 2,3-octanedione, 4-methylbenzophenone, octanal, phytan, dinonyl sebacate, isopropyl palmitate, diisobutyl phthalate, isopropyl myristate were the main volatile compounds of corn ears.
Key words:  corn    frozen storage    volatile components    head space solid phase micro-extraction (HS-SPME)    gas chromatography-mass spectrometry (GC-MS)    principle components analysis(PCA)
收稿日期:  2018-02-28                出版日期:  2019-01-15      发布日期:  2019-02-01      期的出版日期:  2019-01-15
基金资助: 国家重点研发计划资助(2016YFD0401503);重庆市特色食品工程技术研究中心能力提升项目(cstc2014pt-gc8001)
作者简介:  硕士研究生(贺稚非教授为通讯作者,E-mail:2628576386@qq.com)。
引用本文:    
徐瑞,李洪军,贺稚非. 玉米冻藏过程中挥发性成分变化及主成分分析[J]. 食品与发酵工业, 2019, 45(1): 210-218.
XU Rui,LI Hongjun,HE Zhifei. Changes and principal component analysis of volatile compounds in corn ears during frozen storage[J]. Food and Fermentation Industries, 2019, 45(1): 210-218.
链接本文:  
http://sf1970.cnif.cn/CN/10.13995/j.cnki.11-1802/ts.017126  或          http://sf1970.cnif.cn/CN/Y2019/V45/I1/210
[1] 谢玉花,宋洪波,刘升,等. 贮藏温度和薄膜包装对甜玉米呼吸强度及品质的影响[J]. 食品科学, 2014,35(2):282-286.
[2] 谢跃杰,贺稚非,李洪军. 超临界CO2流体萃取兔肉腥味物质[J]. 中国农业科学, 2016,49(16):3 208-3 218.
[3] 谢正敏,练顺才,叶华夏,等. 玉米蒸煮香气成分的研究[J]. 酿酒科技, 2012(9):68-71.
[4] FRATINI G, LOIS S, PAZOS M, et al. Volatile profile of atlantic shellfish species by HS-SPME GC/MS[J]. Food Research International, 2012,48(2):856-865.
[5] LV H, ZHONG Q, LIN Z, et al. Aroma characterisation of pu-erh tea using headspace-solid phase microextraction combined with GC/MS and GC-olfactometry[J]. Food Chemistry, 2012,130(4):1 074-1 081.
[6] DU L, LI J, LI W, et al. Characterization of volatile compounds of pu-erh tea using solid-phase microextraction and simultaneous distillation-extraction coupled with gas chromatography-mass spectrometry[J]. Food Research International, 2014,57:61-70.
[7] 褚能明,柯剑鸿,袁亮. 不同鲜食甜糯玉米挥发性风味物质主成分分析[J]. 核农学报, 2017,31(11):2 175-2 185.
[8] SHA S, CHEN S, QIAN M, et al. Characterization of the typical potent odorants in chinese roasted sesame-like flavor type liquor by headspace solid phase microextraction-aroma extract dilution analysis, with special emphasis on sulfur-containing odorants[J]. Journal of Agricultural and Food Chemistry, 2017,65(1):123-131.
[9] JULIAN Cuevas F, MORENO R M, JOSE R M. Assessing a traceability technique in fresh oranges (Citrus sinensis L. Osbeck) with an HS-SPME-GC-MS method. Towards a volatile characterisation of organic oranges[J]. Food Chemistry, 2017,221:1 930-1 938.
[10] DU L, LI J, LI W, et al. Characterization of volatile compounds of pu-erh tea using solid-phase microextraction and simultaneous distillation-extraction coupled with gas chromatography-mass spectrometry[J]. Food Research International, 2014,57:61-70.
[11] BRO R, SMILEDE A K. Principal component analysis[J]. Analytical Methods, 2014,6(9):2 812-2 831.
[12] TIAN X, CAI Q, ZHANG Y. Rapid classification of hairtail fish and pork freshness using an electronic nose based on the PCA method[J]. Sensors, 2012,12(1):260-277.
[13] ZHOU Q, YANG M, HUANG F, et al. Effect of pretreatment with dehulling and microwaving on the flavor characteristics of cold-pressed rapeseed oil by GC-MS-PCA and electronic nose discrimination[J]. Journal of Food Science, 2013,78(7):C961-C970.
[14] LEGENDRE M G, DUPUY H P, ORY R L, et al. Instrumental analysis of volatiles from rice and corn products[J]. Journal of Agricultural and Food Chemistry, 1978,26(5):1 035-1 038.
[15] 刘春泉,宋江峰,刘玉花,等. 京甜紫花糯2号玉米软罐头加工过程中风味成分变化[J]. 核农学报, 2010,24(3):555-561.
[16] 宋江峰,李大婧,刘春泉. 贮藏过程中京甜紫花糯2号玉米软罐头的主要挥发性风味成分的变化[J]. 核农学报, 2011,25(5):980-987.
[17] 马良,王若兰. 玉米储藏过程中挥发性成分变化研究[J]. 现代食品科技, 2015,31(7):316-325.
[18] LAOPONGSIT W, SRZEDNICKI G, CRASKE J. Preliminary study of solid phase micro-extraction (SPME) as a method for detecting insect infestation in wheat grain[J]. Journal of Stored Products Research, 2014,59:88-95.
[19] 段中华,全小龙,乔有明,等. 高寒草甸植物正构烷烃特征分析[J]. 草业学报, 2016,25(6):136-147.
[20] FELLMAN J K, MILLER T W, MATTINSON D S, et al. Factors that influence biosynthesis of volatile flavor compounds in apple fruits[J]. Hort Science, 2000,35(6):1 026-1 033.
[21] 潘冰燕,鲁晓翔,张鹏,等. GC-MS结合电子鼻分析1-MCP处理对线椒低温贮藏期挥发性物质的影响[J]. 食品科学, 2016,37(2):238-243.
[22] 李天元,张鹏,李江阔,等. 贮藏微环境气体调控对蓝莓冷藏期果实品质及挥发性物质的影响[J]. 食品与发酵工业, 2016,42(8):226-234.
[23] 程焕.杨梅风味特征组分鉴定及变化规律的研究[D]. 杭州:浙江大学, 2017.
[24] RANI P R, CHELLADURAI V, JAYAS D S, et al. Storage studies on pinto beans under different moisture contents and temperature regimes[J]. Journal of Stored Products Research, 2013,52(52):78-85.
[25] 唐柯,马玥,徐岩,等. 冰葡萄酒重要风味化合物嗅觉阈值的研究[J]. 食品与发酵工业, 2016,42(1):148-151.
[26] TEOH L S, LASEKAN O, AZEEZ S. Quality characteristics and volatile compounds of foam mat dried corn flour[J]. Journal of Food Quality, 2016,39(5):456-464.
[1] 占敏宣, 魏清江, 林雄, 李宏祥, 陈金印, 马巧利. PCA再分析采收成熟度对桃溪蜜柚贮藏品质变化模式的影响[J]. 食品与发酵工业, 2021, 47(9): 183-190.
[2] 杨玉宁, 陈松树, 高尔刚, 李园园, 潘秀珍, 刘红昌, 辛雪辉. 基于主成分分析的木通属植物果实品质评价[J]. 食品与发酵工业, 2021, 47(9): 191-200.
[3] 郑涛, 苏柯星, 丛桂芝, 陈明杰, 孙丙寅, 刘淑明. 树上干杏和梅杏果实品质分析与综合评价[J]. 食品与发酵工业, 2021, 47(9): 201-207.
[4] 姚文生, 蔡莹暄, 刘登勇, 张明成, 马双玉, 杨晶, 苟紫慧, 张浩. 基于HS-GC-IMS和HS-SPME-GC-MS的熏鸡腿肉挥发性风味成分分析[J]. 食品与发酵工业, 2021, 47(9): 253-261.
[5] 程琨雅, 杜冰, 付月, 宝宇翔, 肖琳, 王缤晨, 耿宇凤, 董亮. 玉米油加热过程中挥发性物质形成机制[J]. 食品与发酵工业, 2021, 47(8): 27-33.
[6] 张敏, 余佶, 王琪琰, 张锦程, 游湘淘, 姚茂君, 麻成金. 藤茶感官特征定量描述分析与风味轮构建[J]. 食品与发酵工业, 2021, 47(8): 134-139.
[7] 刘丹丹, 李昕沂, 罗晶晶, 王启会, 罗静, 王海燕. 超高压微射流均质技术对猕猴桃果酒品质的影响[J]. 食品与发酵工业, 2021, 47(8): 165-169.
[8] 胡雪, 李锦松, 唐永清, 张良, 钱宇, 赵金松. 基于GC-MS结合化学计量学的浓香型白酒分类方法[J]. 食品与发酵工业, 2021, 47(8): 212-217.
[9] 郭金喜, 马燕, 范田丽, 杨光勇, 马君刚. 微波消解-电感耦合等离子体串联质谱法测定新疆黑枸杞红酒中微量元素的主成分分析[J]. 食品与发酵工业, 2021, 47(8): 243-249.
[10] 张迪, 吉宏武, 陈浩, 刘书成, 毛伟杰. 脂质对凡纳滨对虾热风干制品香气特性的影响[J]. 食品与发酵工业, 2021, 47(7): 189-196.
[11] 岳翠男, 秦丹丹, 蔡海兰, 李琛, 王治会, 李文金, 杨普香, 吴华玲. QDA和GC-MS结合PLSR分析宁红茶中的风味物质[J]. 食品与发酵工业, 2021, 47(7): 225-231.
[12] 李晓朋, 曾欢, 林柳, 陶宁萍, 徐逍, 丛建华. 不同煎炸用油制备河豚鱼汤挥发性风味成分的差异性[J]. 食品与发酵工业, 2021, 47(7): 251-259.
[13] 张振霞, 徐炜, 吴昊, 张文立, 光翠娥, 沐万孟. 玉米赤霉烯酮内酯水解酶的鉴定、改造及应用[J]. 食品与发酵工业, 2021, 47(7): 285-291.
[14] 徐霞, 倪逸凡, 周绪霞, 丁玉庭. 猪皮毛霉固态发酵过程中营养及挥发性风味的动态变化[J]. 食品与发酵工业, 2021, 47(6): 49-55.
[15] 刘含龙, 万金庆, 杨帆, 张毅, 高欣月, 童年. 不同干燥方式对草菇切片品质的影响[J]. 食品与发酵工业, 2021, 47(6): 160-168.
No Suggested Reading articles found!
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
版权所有 © 《食品与发酵工业》编辑部
地址:北京朝阳区酒仙桥中路24号院6号楼111室
本系统由北京玛格泰克科技发展有限公司设计开发  技术支持:support@magtech.com.cn