不同结构纳米铜 /PP 复合膜中铜向食品模拟物的迁移

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  • 1(暨南大学 食品科学与工程系,广东 广州,510632)2(广东省普通高校产品包装与物流重点实验室,广东 珠海,519070)3(暨南大学 包装工程研究所,广东 珠海,519070)4(广东出入境检验检疫局检验检疫技术中心,广东 广州,510623)
石玉杰,硕士在读,研究方向为食品包装安全。E-mail: YujieSHIJNU@163.com

网络出版日期: 2018-02-02

基金资助

国家自然科学基金(31571762)

Migration of copper from different structures of nanocopper/polypropylene composite fi lm to the food simulants

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  • 1 (Department of Food Science and Engineering, Jinan University, Guangzhou, 510632, China) 2 (Key Laboratory of Product Packaging and Logistics of Guangdong Higher Education Institutes, Zhuhai, 519070, China) 3(Packaging Engineering Institute of Jinan University, Zhuhai, 519070, China) 4(Guangdong Inspection and Quarantine Technology Center, Guangzhou, 510623, China)

Online published: 2018-02-02

摘要

探究了温度、时间、食品模拟物、氧气,以及聚丙烯(Polypropylene, PP)的三种结构( PP-B、PP-R和PP-H)对纳米铜/PP复合膜中铜向食品模拟物迁移的影响。将含有纳米铜和经3-氨丙基三乙氧基硅烷((3-Aminopropyl)triethoxysilane, KH550)处理的纳米铜分别添加到PP-B、PP-R和PP-H母粒中制备成相应的纳米铜/PP复合膜。在20、40和70 °C下,将复合膜浸泡在食品模拟物中进行迁移实验。结果表明:铜向食品模拟物的迁移率随着时间和温度的增加而增大直至平衡。酸性食品模拟物中迁移平衡时,在20 ℃,纳米铜/PP-B复合膜中铜的迁移率最大,PP-R和PP-H中铜的迁移率无显著性差异;40 ℃时,纳米铜/PP-H中铜的迁移率最大,PP-B和PP-R中铜的迁移率无显著性差异;而在70 ℃时,仍然是PP-H中铜的迁移率最大,PP-R次之,PP-B中铜的迁移率最小。

本文引用格式

石玉杰, 胡长鹰, 姜紫薇 , 等 . 不同结构纳米铜 /PP 复合膜中铜向食品模拟物的迁移[J]. 食品与发酵工业, 2018 , 44(1) : 92 . DOI: 10.13995/j.cnki.11-1802/ts.014440

Abstract

This paper mainly explores the influence of temperature, exposure time, food simulants, oxygen, and three kinds of structure (PP-B, PP-R and PP-H) on the migration of copper from nanocopper/PP composite films into food simulants. Nanocopper and modified nanocopper by (3-Aminopropyl) triethoxysilane (KH550) were mixed with PP granules, new granules containing nanocopper and modified nanocopper were added into the composite films by a film-blowing machine. The films were exposured to food simulants at 20, 40 and 70 ℃. The results showed that with the increase of exposure time and temperature, the release of copper increased. When equilibrium is reached in acidic food simulants, copper migration does not appear to be significant in the case of PP-R and PP-H compared with nanocopper/PP-B with a maximum value at 20 ℃; copper migration does not appear to be significant in the case of PP-B and PP-R compared with PP-H with a maximum value at 40 ℃; the migration of copper in PP-H is greater than PP-R, the migration of copper in the PP-B is minimum at 70 ℃.
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