食品与发酵工业 >

2020 , Vol. 46 >Issue 5: 284 - 291

DOI: https://doi.org/10.13995/j.cnki.11-1802/ts.022021

分析与检测

三种晚熟甜橙冷磨精油挥发性及主体香气成分的比较分析

  • 李贵节 ,
  • 张群琳 ,
  • 何雅静 ,
  • 谈安群 ,
  • 张腾辉 ,
  • 郭莉 ,
  • 张万超 ,
  • 钟世浚 ,
  • 谭祥 ,
  • 孙志高
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  • 1(西南大学 柑桔研究所,国家柑桔工程技术研究中心,重庆,400712)
    2(重庆市药物种植研究所,重庆,408435)
    3(重庆市功能性食品协同创新中心,重庆,400067)
    4(成都市华测检测技术有限公司,成都,610041)
    5(重庆文理学院 园林与生命科学学院,重庆,402160)
李贵节博士后和张群琳硕士研究生为共同第一作者(张万超助理研究员和孙志高副研究员为共同通讯作者,E-mail:boystory@163.com;cpro@cric.cn)

收稿日期: 2019-08-19

  网络出版日期: 2020-04-10

基金资助

国家柑桔工程技术研究中心开放课题(NCERC2019004);重庆市基础研究与前沿探索项目(cstc2019jcyj-bsh0122);高层次外国专家项目(WQ20135000161);国家重点研发计划“新型果蔬汁加工关键技术及装备研发”(2017YFD0400701-3)

收起

Comparative analysis of volatile and principal aroma components ofcold-pressed oil from three varieties of late-maturing sweet oranges

  • LI Guijie ,
  • ZHANG Qunlin ,
  • HE Yajing ,
  • TAN Anqun ,
  • ZHANG Tenghui ,
  • GUO Li ,
  • ZHANG Wanchao ,
  • ZHONG Shijun ,
  • TAN Xiang ,
  • SUN Zhigao
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  • 1(Citrus Research Institute of Southwest University, National Citrus Engineering Research Center, Chongqing 400712, China)
    2(Chongqing Institute of Medicinal Plant Cultivation, Chongqing 408435, China)
    3(Chongqing Collaborative Innovation Center for Functional Food, Chongqing 400067, China)
    4(Chengdu Centre Testing International Group Co., Ltd., Chengdu 610041, China)
    5(School of Landscape Architecture and Life Sciences, Chongqing University of Arts and Sciences, Chongqing 402160, China)

Received date: 2019-08-19

  Online published: 2020-04-10

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摘要

为研究重庆主栽晚熟甜橙精油的挥发性及主体香气物质的组成含量特点,采用顶空固相微萃取-气质联用技术和香气活度值(odor activity values, OAV)分析奥林达夏橙、五月红甜橙和晚熟血橙的果皮冷磨精油(cold-pressed oil, CPO)。3个品种中分别鉴定出53、54和52个挥发性物质,其中D-柠檬烯含量普遍较低;奥林达CPO醇酚类、醛酮类含量更高,五月红和晚熟血橙CPO含较高的萜类物质。OAV分析表明,3种CPO的主体香气贡献物质包括对伞花烃、癸醛、己醛、壬醛和芳樟醇等30个成分,体现柑橘香、花香、油脂香等8类主要香气属性;奥林达CPO中花香、脂香和甜香类物质OAV较高,晚熟血橙CPO中松香和木香类物质OAV较高。本地区3个晚熟甜橙冷磨油的主体香气属性各具特点,适合加工不同类型的低萜精油,提升晚熟甜橙的产品附加值。

关键词： 晚熟甜橙; 冷磨精油; 挥发性物质; 香气活度值; 主体香气成分

本文引用格式

李贵节 , 张群琳 , 何雅静 , 谈安群 , 张腾辉 , 郭莉 , 张万超 , 钟世浚 , 谭祥 , 孙志高 . 三种晚熟甜橙冷磨精油挥发性及主体香气成分的比较分析[J]. 食品与发酵工业, 2020 , 46(5) : 284 -291 . DOI: 10.13995/j.cnki.11-1802/ts.022021

Abstract

In order to develop the essential oil resources from major late-maturing sweet oranges cultivars in Chongqing, the volatile and principal aroma components of essential oil were studied for their composition and concentration characters. Techniques of headspace solid-phase micro-extraction-gas chromatography-mass spectrometry combined with odor activity values (OAV) were applied to analyze the cold-pressed oil (CPO) from Olinda Valencia Orange, Wuyuehong Orange and Late-maturing Blood Orange peel. The results showed that 53, 54 and 52 volatile components were respectively identified from the three varieties of CPO, among which D-limonene generally had comparatively low molar fraction. Olinda CPO contained higher concentration of hydroxyl (alcohols and phenols) and carbonyl (aldehydes and ketones) compounds while Wuyuehong and Late-maturing Blood Orange CPO contained higher concentrations of terpene volatiles. OAV analysis showed that 30 components including p-cymene, decanal, hexanal, nonanal and linalool were found as principal aroma contributors in the three CPOs. They form eight major aroma attributes such as citrusy, floral and lipid etc. Olinda CPO had higher OAVs of floral, lipid and sweet attributes while Late-maturing Blood Orange CPO had higher OAV of piney and woody attribute. In conclusion, the three local varieties of late-maturing sweet orange CPO exhibited varied characteristics. They are suitable for processing different types of low terpene essential oil, so as to enhance the added value of late-maturing sweet orange products.

Key words： late-maturing sweet orange; cold-pressed oil; volatile compounds; odor activity value; principal aroma components

参考文献

[1] IM S J, KIM J H, KIM M Y. Evaluation of bioactive components and antioxidant and anticancer properties of citrus wastes generated during bioethanol production[J]. Natural Product Communications, 2014, 9(4):483-486.
[2] VAIO D C, GRAZIANI G, GASPARI A, et al. Essential oils content and antioxidant properties of peel ethanol extract in 18 lemon cultivars[J]. Scientia Horticulturae(Amsterdam), 2010, 126(1):50-55.
[3] LI G, WANG G J, CHENG Y, et al. Prophylactic effects of polymethoxyflavone-rich orange peel oil on Nω-nitro-L-arginine-induced hypertensive rats[J]. Applied Sciences, 2018, 8(5):752-767.
[4] 杨蕾,洪林,李勋兰,等.重庆市柑桔产业发展现状及问题分析[J]. 中国果业信息, 2018, 35(11):13-16.
[5] NJOROGE S M, KOAZE H, KARANJA P N, et al. Essential oil constituents of three varieties of Kenyan sweet oranges (Citrus sinensis)[J]. Flavour & Fragrance Journal, 2010, 20(1):80-85.
[6] 谢练武, 郭亚平, 周春山, 等. 压榨法与蒸馏法提取柑橘香精油的比较研究[J]. 化学与生物工程, 2005, 22(5):15-17.
[7] SONG H, CADWALLADER K R, SINGH T K. Odor-active compounds of Jinhua ham[J]. Flavor & Fragrance Journal, 2005, 23(1):1-6.
[8] BUTTERY R G, SEIFERT R M, GUADAGNI D G, et al. Characterization of additional volatile components of tomato[J]. Journal of Agricultural and Food Chemistry, 1971, 19(3):524-529.
[9] 洪鹏, 陈峰, 杨远帆, 等. 三种柚子精油的香味特征及挥发性成分[J]. 现代食品科技, 2014,30(10): 274-281.
[10] MATTHEWS R F, BRADDOCK R J. Recovery and applications of essential oil from orange[J]. Food Technology, 1987, 41(1):57-61.
[11] MOOKDASANIT J, HIROTOSHI T, TAKUMI Y, et al. Trace volatile components in essential oil of citrus sudachi by means of modified solvent extraction method [J]. Food Science and Technology Research, 2003,9(1): 54-61.
[12] TAMURA H, FUKUDA Y, PADRAYUTTAWAT A. Characterization of citrus aroma quality by odor threshold values[J]. Biotechnology for Improved Foods and Flavors, 1996, 637:282-294.
[13] Flavor database [DB/OL]. Florda State, USA: Citrus Research and Education Center, University of Florida, 2002 [2012-12-7] http: //www.crec.ifas.ufl.edu/crec_websites/Rouseff/Website2002/Subpages/database_f_Frameset.html.
[14] Flavor net and human odor space [DB/OL]. Geneva, NewYork, USA: Cornell University, 2004 [2012-12-07]. http://www.flavornet.org/flavornet.html.
[15] 杨颖, 施迎春, 陈剑兵, 等. 分子蒸馏精制对葡萄柚精油理化性质及赋香性能的影响[J]. 中国食品学报, 2013, 13(3): 208-213.
[16] SAWAMURA M. Volatile components of essential oils of the citrus genus[J]. Recent Research Developments in Agricultural & Food Chemistry, 2000, 4(3-4):S32-S33.
[17] MOSHONAS M G, SHAW P E. Compounds new to essential orange oil from fruit treated with abscission chemicals[J]. Journal of Agricultural & Food Chemistry, 1978, 26(6):1 288-1 293.
[18] ROJAS L, JENNIFER P I, PERE A, et al. Obtencion of essential oils and pectins from by-products of citrus juice[J]. Vitae -revista De La Facultad De Quimica Parmaceutica, 2009, 16(1): 110-115.
[19] 肖作兵, 马胜涛, 牛云蔚, 等. 感官评价和GC-MS结合偏最小二乘回归法分析甜橙油中的风味物质[J].中国食品学报, 2017, 17(7): 284-290.
[20] 乔宇. 柑橘汁香气活性化合物的鉴定及其在加工和储藏中的变化[D]. 武汉:华中农业大学, 2008.
[21] CICCHETTI, ESMÉRALDA, DUROURE L, et al. Characterization of odoractive compounds in Timur (Zanthoxylum armatum DC.) fruits from Nepal [J]. Flavor and Fragrance Journal, 2017, 32(5):317-329.
[22] 牛云蔚, 姚征民, 肖作兵, 等. AEDA结合OAVs分析两种薰衣草精油中特征性香气成分[J]. 食品工业, 2016,37(12): 264-268.
[23] CHOI H S. Character impact odorants of Citrus Hallabong [(C. unshiu Marcov × C. sinensis Osbeck)×C. reticulata Blanco] cold-pressed peel oil[J]. Journal of Agricultural and Food Chemistry, 2003, 51(9):2 687-2 692.
[24] SRIWICHAI T. Aromatic profiling of Zanthoxylum myriacanthum (makwhaen) essential oils from dried fruits using different initial drying techniques[J]. Industrial Crops and Products, 2019, 133:284-291.
[25] GONZÁLEZ-MAS M C, RAMBLA J L, LÓPEZ-GRESA M P, et al. Volatile compounds in Citrus essential oils: A comprehensive review[J]. Frontiers in Plant Science, 2019, 10:1-12.
[26] BUETTNER A, SCHIEBERLE P. Evaluation of aroma differences between hand-squeezed juices from Valencia Late and Navel Oranges by quantitation of key odorants and flavor reconstitution experiments[J]. Journal of Agricultural and Food Chemistry, 2001, 49(5):2 387-2 394.
[27] BAXTER I A, EASTON K, SCHNEEBELI K, et al. High pressure processing of Australian navel orange juices: Sensory analysis and volatile flavor profiling[J]. Innovative Food Science and Emerging Technologies, 2005, 6(4):372-387.
[28] RODRÍGUEZ A, PERIS J E, REDONDO A, et al. Impact of D-limonene synthase up- or down-regulation on sweet orange fruit and juice odor perception[J]. Food Chemistry, 2017, 217:139-150.
[29] PLOTTO A, CARLOS A, MARGARÍA, et al. Odour and flavour thresholds for key aroma components in an orange juice matrix: terpenes and aldehydes[J]. Flavour and Fragrance Journal, 2004, 19(6):491-498.
[30] MACLEOD A J, MACLEOD G, SUBRAMANIAN G. Volatile aroma constituents of orange[J]. Phytochemistry, 1988, 27(7): 2 185-2 188.
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