生产与科研应用

发酵前咖啡酸和迷迭香酸添加对干红葡萄酒颜色与香气的影响

  • 李宁宁 ,
  • 张波 ,
  • 牛见明 ,
  • 史肖 ,
  • 马腾臻 ,
  • 韩舜愈
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  • 1(甘肃农业大学 食品科学与工程学院,甘肃 兰州,730070)
    2(甘肃省葡萄与葡萄酒工程学重点实验室,甘肃 兰州,730070)
    3(甘肃省葡萄与葡萄酒产业技术研发中心,甘肃 兰州,730070)
硕士研究生(张波副教授和韩舜愈教授为共同通讯作者,E-mail:zhangbo@gsau.edu.cn;hanshunyu@gsau.edu.cn)

收稿日期: 2019-12-11

  网络出版日期: 2020-06-17

基金资助

国家自然科学基金地区科学基金项目(31560451);甘肃省商务厅葡萄酒产业发展专项资金项目(2017010);甘肃省葡萄与葡萄酒工程学重点实验室开放课题项目(GSPTJ-2017-03)

The influence of pre-fermentative addition of caffeic acid and rosmarinic acid on the color and aroma compounds of dry red wines

  • LI Ningning ,
  • ZHANG Bo ,
  • NIU Jianming ,
  • SHI Xiao ,
  • MA Tengzhen ,
  • HAN Shunyu
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  • 1(College of Food Science and Engineering, Gansu Agricultural University, Lanzhou 730070, China)
    2(Gansu Key Laboratory of Viticulture and Enology, Lanzhou 730070, China)
    3(Research and Development Center of Wine Industry in Gansu Province, Lanzhou 730070, China)

Received date: 2019-12-11

  Online published: 2020-06-17

摘要

该试验通过在赤霞珠干红葡萄酒发酵前分别进行150 mg/L咖啡酸和迷迭香酸2种添加处理,并在陈酿6个月后利用超高效液相色谱-质谱以及气相色谱-质谱联用对各样品的颜色参数和香气物质进行测定分析。结果表明,处理可使样品的颜色参数L*值降低0.9~1.5 a.u.,a*值升高1.0~1.3 a.u.,且迷迭香酸处理样品效果较好。处理后的酒样其平均总花色苷和总酚质量浓度显著增加了约70和580 mg/L,而超高效液相色谱-质谱结果表明,尽管供试样品的各类花色苷物质在种类上无差异,但添加酚类物质可明显提高其质量浓度,特别是迷迭香酸处理后的酰化花色苷类型。对供试样品的香气成分分析后发现,咖啡酸处理可增加酒中酯类、酸类和萜烯类化合物含量,而迷迭香酸处理的样品中除酯类化合物含量升高外,其他类型的香气物质含量均有所降低。

本文引用格式

李宁宁 , 张波 , 牛见明 , 史肖 , 马腾臻 , 韩舜愈 . 发酵前咖啡酸和迷迭香酸添加对干红葡萄酒颜色与香气的影响[J]. 食品与发酵工业, 2020 , 46(10) : 132 -140 . DOI: 10.13995/j.cnki.11-1802/ts.023059

Abstract

In this study, the pre-fermentative addition of 150 mg/L of caffeic acid and rosmarinic acid in Cabernet Sauvignon red winemaking was performed. The influence of phenolic compounds addition on wine color parameters and aroma components was monitored after 6 months of aging using UPLC-MS and GC-MS technologies. The results showed that the L* value of the treated samples was decreased by 0.9-1.5 a.u. and the a* value was increased by 1.0-1.3 a.u.. Among them, the rosmarinic acid treatment had a better effect. Meanwhile, the results showed that the mean total anthocyanin and total phenol concentrations of the treated samples increased significantly by about 70 and 580 mg/L, respectively. The results of UHPLC-MS showed that although there was no difference in the types of anthocyanins in the tested samples, the addition of phenolic compounds could significantly improve their content, especially the type of acylated anthocyanins after rosmarinic acid treatment. The analysis of aroma components showed that caffeic acid treatment increased the content of esters, acids and terpenes in wine, while rosmarinic acid treatment increased the content of esters and decreased the concentration of other types of aroma components.

参考文献

[1] BIMPILAS A, PANAGOPOULOU M, TSIMOGIANNIS D, et al. Anthocyanin copigmentation and color of wine: The effect of naturally obtained hydroxycinnamic acids as cofactors[J]. Food Chemistry, 2016, 197: 39-46.
[2] 刘丽媛, 刘延琳, 李华. 葡萄酒香气化学研究进展[J]. 食品科学, 2011,32 (5): 310-316.
[3] PAMÉLA N, CHARLÈNE M, ANGERS P, et al. Co-fermentation of red grapes and white pomace: A natural and economical process to modulate red hybrid wine composition[J]. Food Chemistry, 2017, 242: 481-490.
[4] 张波, 祝霞, 盛文军, 等. 红葡萄酒中花色苷辅色化反应研究进展[J]. 中国农业科技导报, 2017,19(8): 92-104.
[5] HERAS-ROGER J, ROMERO C D, DARIAS-MARTIN J. What gives a wine its strong red color? Main correlations affecting copigmentation[J]. Journal of Agricultural and Food Chemistry, 2016, 64(34): 6 567-6 574.
[6] LAMBERT S G, ASENSTORFER R E, WILLIAMSON N M, et al. Copigmentation between malvidin-3-glucoside and some wine constituents and its importance to colour expression in red wine[J]. Food Chemistry, 2011, 125(1):106-115.
[7] ZHANG B, HE F, LIU Y, et al. Impact of adding ellagic acid to red grapes on the phenolic composition and chromatic quality of Cabernet Sauvignon wines from a warm climate[J]. Journal of Food Processing and Preservation, 2017, 41(4): e13 080.
[8] GÒMEZ-MÍGUEZ, M, GONZÁLEZ-MANZANO, S, ESCRIBANO-BAILóN, M T, et al. Influence of different phenolic copigments on the color of malvidin 3-glucoside[J]. Journal of Agricultural and Food Chemistry, 2006, 54(15):5 422-5 429.
[9] TEIXEIRA N, CRUZ L, BRÁS N F, et al. Structural features of copigmentation of oenin with different polyphenol copigments[J]. Journal of Agricultural and Food Chemistry, 2013, 61(28):6 942-6 948.
[10] DUFOUR C, BAYONOVE C L. Interactions between wine polyphenols and aroma substances. An insight at the molecular level[J]. Journal of Agricultural and Food Chemistry, 1999, 47(2): 678-684.
[11] ARONSON J, EBELER S E. Effect of polyphenol compounds on the headspace volatility of flavors[J]. American Journal of Enology and Viticulture, 2004, 55(1): 13-21.
[12] ESCALONA H, HOMMAN-LUDIYE M, PIGGOTT J R, et al. Effect of potassium bitartrate, (+)catechin and wood extracts on the volatility of ethyl hexanaote and octanal in ethanol/water solutions[J]. LWT-Food Science and Technology, 2001, 34(2): 76-80.
[13] CHENG Y, HUYNH-BA T, BLANK I, et al. Temporal changes in aroma release of longjing tea infusion: Interaction of Volatile and nonvolatile tea components and formation of 2-butyl-2-octenal upon aging[J]. Journal of Agricultural and Food Chemistry, 2008,4 156(6): 2 160-2 169.
[14] CHEN K, ESCOTT C, LOIRA I, et al. The effects of pre-fermentative addition of oenological tannins on wine components and sensorial qualities of red wine[J]. Molecules, 2016, 21(11): 1 445-1 452.
[15] VILLAMOR R R, ROSS C F. Wine matrix compounds affect perception of wine aromas[J]. Annual Review of Food Science and Technology, 2013, 4(1):1-20.
[16] 糜川清. 感官分析及仪器分析在葡萄酒香气研究中的应用[J]. 食品科学, 2012, 33(23):351-355.
[17] 王昶森, 杨志伟, 刘亚新, 等. UHPLC-MS/MS方法在葡萄酒花色苷鉴定过程中对两种锦葵色素同分异构体的分离[J]. 酿酒科技, 2018, 288(6): 63-66.
[18] 曹鹏, 张波, 张欣珂, 等. 陈酿前添加咖啡酸对干红葡萄酒颜色品质及多酚构成的影响[J]. 中国食品学报, 2019, 19(7): 153-160.
[19] 张明霞, 吴玉文, 段长青. 葡萄与葡萄酒香气物质研究进展[J]. 中国农业科学, 2008,41(7): 227-233.
[20] BOULTON R. The copigmentation of anthocyanins and its role in the color of red wine: A critical review[J]. American Journal of Enology and Viticulture, 2001, 522(2): 98-165.
[21] 陈欣然, 张波, 张欢,等. 红葡萄酒中花色苷的超高效液相色谱串联三重四级杆质谱检测方法建立[J]. 食品与发酵工业, 2019, 45(7): 262-268.
[22] 鲁榕榕, 马腾臻, 张波, 等. 不同澄清剂对起泡葡萄酒原酒的澄清作用及对香气品质的影响[J]. 食品科学, 2018, 39(12): 146-153.
[23] ZHANG B, WANG Q, ZHOU P P. et al. Copigmentation evidence of oenin with phenolic compounds: A comparative study of spectrographic, thermodynamic and theoretical data[J]. Food Chemistry, 2020, 313: 126 163.
[24] GORDILLO B, RODRÍGUEZ-PULIDO F J, ESCUDERO-GILETE M L, et al. Comprehensive colorimetric study of anthocyanic copigmentation in model solutions. Effects of pH and molar ratio[J]. Journal of Agricultural and Food Chemistry, 2012, 60(11): 2 896-2 905.
[25] 张波, 韩舜愈, 马腾臻, 等. 红葡萄酒中花色苷衍生物结构研究进展[J]. 食品科学, 2018, 39(5): 284-295.
[26] ALCALDE-EON C, BOIDO E, CARRAU F, et al. Pigment profiles in monovarietal wines produced in Uruguay[J]. American Journal of Enology and Viticulture, 2006, 57 (4): 449-459.
[27] 王玉华, 盛文军, 李敏, 等. 耐热克鲁维酵母和粟酒裂殖酵母顺序接种发酵对美乐干红葡萄酒品质的影响[J]. 食品科学, 2019, 40(8): 102-111.
[28] 牛见明, 张波, 史肖, 等. 三种澄清方式对‘美乐’甜型桃红葡萄酒品质的影响[J]. 食品与发酵工业, 2019, 45(16): 129-138.
[29] LI Y K, MARIO P, MARIROSA T, et al. Oenin and quercetincopigmentation: Highlights from density functional theory[J]. Frontiers in Chemistry, 2018, 6: 245.
[30] FIGUEIREDO-GONZÁLEZ M, CANCHOGRANDE B, SIMAL-GÁNDARA. Effects on colour and phenolic composition of sugar concentration processes in dried-on- or dried-off-vine grapes and their aged or not natural sweet wines[J]. Trends in Food Science & Technology, 2013, 31(1): 36-54.
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