研究报告

笋壳醋酸木质素吸附重金属Cr(VI)的特性及机制

  • 胡子聪 ,
  • 房翠兰 ,
  • 李升 ,
  • 叶发银 ,
  • 赵国华
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  • 1(西南大学 食品科学学院,重庆,400715)
    2(重庆市九龙坡区疾病预防控制中心,重庆,400039)
    3(重庆市特色食品工程技术研究中心,重庆,400715)
硕士研究生(赵国华教授为通讯作者,E-mail:zhaoguohua1971@163.com)

收稿日期: 2020-02-06

  网络出版日期: 2020-06-24

基金资助

国家重点研发计划资助(2016YFD0400204-2)

Properties and mechanisms of Cr(VI) adsorption on acetic acidlignin from bamboo shoot shells

  • HU Zicong ,
  • FANG Cuilan ,
  • LI Sheng ,
  • YE Fayin ,
  • ZHAO Guohua
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  • 1(College of Food Science, Southwest University, Chongqing 400715, China)
    2(Centre for Disease Control and Prevention of Jiulongpo, Chongqing 400039, China)
    3(Chongqing Engineering Research Center for Regional Foods, Chongqing 400715, China)

Received date: 2020-02-06

  Online published: 2020-06-24

摘要

研究笋壳醋酸木质素(bamboo shoot shell acetic acid lignin, BSS-AL)对Cr(VI)的吸附性能和机制。通过批量吸附实验研究pH、BSS-AL添加量、接触时间和Cr(VI)的初始浓度对吸附过程的影响并建立吸附模型,利用傅里叶变换红外光谱(fourier transform infrared spectroscopy,FTIR)和X射线光电子能谱(X-ray photoelectron spectroscopy,XPS)比较吸附前后BSS-AL的官能团及元素组成来探究吸附机制。结果表明,BSS-AL能有效吸附重金属Cr(VI),在含Cr(VI)的体系中暴露240 min后,BSS-AL对Cr(VI)的清除率已超过97%,其动力学模型符合准二级动力学模型。BSS-AL对Cr(VI)的最大吸附量能达到14.908 mg/g,吸附等温模型符合Langmuir模型。FTIR和XPS分析技术阐释了BSS-AL吸附Cr(VI)的机制,即静电相互作用、离子交换和还原后再吸附。综上,BSS-AL在去除食品中的有毒重金属污染物Cr(VI)中具有很大潜力。

本文引用格式

胡子聪 , 房翠兰 , 李升 , 叶发银 , 赵国华 . 笋壳醋酸木质素吸附重金属Cr(VI)的特性及机制[J]. 食品与发酵工业, 2020 , 46(11) : 52 -60 . DOI: 10.13995/j.cnki.11-1802/ts.023531

Abstract

This study aimed to evaluate the adsorption capacity and potential adsorption mechanisms of Cr (VI) by bamboo shoot shell acetic acid lignin (BSS-AL). The effects of pH, addition amount of BSS-AL, contact time and initial Cr(VI) concentration were studied through batch adsorption experiments. And the adsorption models were also been established. Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) were used to detect the functional groups and element composition of BSS-AL before and after adsorption in order to explore the adsorption mechanisms. The results showed that BSS-AL exhibited high-efficiency adsorption capacity of Cr (VI) and the removal rate of Cr (VI) could reach 97% in four hours. Furthermore, the pseudo-second-order kinetic model could be matched with the adsorption behavior over the whole range of adsorption process. Moreover, the adsorption of Cr (VI) by BSS-AL could be described well by Langmuir model and the maximum adsorption capacity reached 14.908 mg/g. The adsorption mechanisms could be explained by FTIR and XPS spectra: electrostatic interaction, ion exchange and re-adsorption after reduction. And BSS-AL has great potential to remove toxic pollutant Cr(VI) from food.

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