Aqueous synchronous extraction of oil and protein from walnut milk residues was investigated.Through single factor experiment,the best process conditions was: pH 11.5,ratio of solid to liquid 1∶8,lixiviated at 50℃ for 5h.Under the above conditions,the oil yield was 26.05%,the protein yield was 10.72%.Freezing and thawing demulsification was used to increased oil yield.The average yield of the free oilⅡ after demulsification was 43.05%.