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蛋白质基Pickering乳液的研究进展

  • 姜曼
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  • 济宁职业技术学院 生物与化学工程系,山东 济宁,272037
硕士,讲师(通讯作者,E-mail:158098484@qq.com)

收稿日期: 2020-07-31

  修回日期: 2020-08-18

  网络出版日期: 2021-03-08

Advance in protein-based Pickering emulsion

  • JIANG Man
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  • Biological and Chemical Engineering, Jining Vocational and Technical College, Jining 272037, China

Received date: 2020-07-31

  Revised date: 2020-08-18

  Online published: 2021-03-08

摘要

由于Pickering乳液的优良环保性、抗聚结稳定性以及在生物活性药物输送方面的潜在应用,其在化妆品、食品等领域受到广泛关注。相比较于传统乳液,Pickering乳液不含任何表面活性剂,具有安全稳定的特性。考虑到毒性和食品安全问题,无机粒子和合成粒子的应用受到很大限制。在稳定乳液方面,Pickering粒子在界面处的吸附几乎是不可逆的,因此,有必要寻找更合适的食品级Pickering粒子。该文综述了Pickering乳液的稳定机制,包括粒子润湿性、三相接触角、粒子形成的空间位阻,以及近年来蛋白质和蛋白质基的Pickering颗粒及其稳定Pickering乳液的生产、表征及稳定性等方面的最新进展,并讨论其发展方向,为进一步扩大蛋白质纳米粒子在食品领域中的应用奠定基础。

本文引用格式

姜曼 . 蛋白质基Pickering乳液的研究进展[J]. 食品与发酵工业, 2021 , 47(3) : 259 -264 . DOI: 10.13995/j.cnki.11-1802/ts.025230

Abstract

Due to the excellent environmental-friendly, stability against coalescence and potential applications in the delivery of bioactive drugs of Pickering emulsions, great progress has been made in cosmetics, industry, food and other fields. Compared with traditional emulsions, Pickering emulsion does not contain any surfactants, and it is safe and stable. The application of inorganic particles and synthetic particles are also been greatly restricted when considering its toxicity and food safety issues. In terms of stable emulsion, the adsorption of Pickering particles at the interface is almost irreversible. Therefore, it is necessary to find more suitable food-grade particles as Pickering emulsion stabilizers. This article reviews the stability mechanism of Pickering emulsions, including particle wettability, three-phase contact angle, steric hindrance of particle formation. And this review also summarizes the latest developments in the production, characterization and stability of protein and protein-based Pickering particles stabilized Pickering emulsions in recent years, and point out its development direction. This article will lay a foundation for further expanding the application of protein nanoparticles in the food field.

参考文献

[1] MUNARI B J V,THAIS D P S J,NICOLETTI V R.SPI microgels applied to Pickering stabilization of O/W emulsions by ultrasound and high-pressure homogenization:Rheology and spray drying[J].Food Research International,2019,122:383-391.
[2] KACI M,ARAB-TEHRANY E,DESJARDINS I,et al.Emulsifier free emulsion:Comparative study between a new high frequency ultrasound process and standard emulsification processes[J].Journal of Food Engineering,2017,194:109-118.
[3] JIANG H,SHENG Y,NGAI T.Pickering emulsions:Versatility of colloidal particles and recent applications[J].Current Opinion in Colloid & Interface Science,2020,49:1-15.
[4] PICKERING S U.CXCVI.—Emulsions[J].J.Chem.Soc.Trans,1907,91:2 001-2 021.
[5] MORRIS V J.Emerging roles of engineered nanomaterials in the food industry[J].Trends in Biotechnology,2011,29 (10):509-516.
[6] 李海明, 杨盛,韦何雯,等.食品级Pickering乳液的研究进展[J].食品科学,2015,36(19):265-270.
LI H M,YANG S,WEI H W,et al.Food grade pickering emulsion:A review[J].Food Science,2015,36(19):265-270.
[7] XIAO J,LI Y,HUANG Q.Recent advances on food-grade particles stabilized Pickering emulsions:Fabrication,characterization and research trends[J].Trends in Food Science & Technology,2016,55(9):48-60.
[8] BINKS B P.Particles as surfactants—similarities and differences[J].Current Opinion in Colloid & Interface Science,2002,7(1-2):21-41.
[9] DICKINSON E.Use of nanoparticles and microparticles in the formation and stabilization of food emulsions[J].Trends in Food Science & Technology,2012,24(1):4-12.
[10] XIAO J,WANG X,GONZALEZ A J P,et al.Kafirin nanoparticles-stabilized Pickering emulsions:Microstructure and rheological behavior[J].Food Hydrocolloids,2016,54:30-39.
[11] SHI A,FENG X,WANG Q,et al.Pickering and high internal phase Pickering emulsions stabilized by protein-based particles:A review of synthesis,application and prospective[J].Food Hydrocolloids,2020.
[12] LEUNISSEN M E,BLAADEREN A V,HOLLINGSWORTH A D,et al.Electrostatics at the oil-water interface,stability,and order in emulsions and colloids[J].Proceedings of the National Academy of Sciences of the United States of America,2007,104(8):2 585-2 590.
[13] WHITBY C P,SCARBOROUGH H,NGOTHAI Y.Drying oil-in-water Pickering emulsions to make redispersible powders[J].Advanced Powder Technology,2017,28(11):2 940-2 946.
[14] TAVERNIER I,WIJAYA W,VAN DER MEEREN P,et al.Food-grade particles for emulsion stabilization[J].Trends in Food ence & Technology,2016,50:159-174.
[15] PAUNOV V N,CAYRE O J,NOBLE P F,et al.Emulsions stabilised by food colloid particles:Role of particle adsorption and wettability at the liquid interface[J].Journal of Colloid & Interface Science,2007,312(2):381-389.
[16] HARMAN C L G,PATEL M A,GULDIN S,et al.Recent developments in pickering emulsions for biomedical applications[J].Current Opinion in Colloid & Interface Science,2019,39:173-189.
[17] JIANG Y,ZHU Y Z,LI F,et al.Antioxidative pectin from hawthorn wine pomace stabilizes and protects Pickering emulsions via forming zein-pectin gel-like shell structure[J].International Journal of Biological Macromolecules,2020,151:193-203.
[18] LI M F,HE Z Y,LI G Y,et al.The formation and characterization of antioxidant pickering emulsions:Effect of the interactions between gliadin and chitosan[J].Food Hydrocolloids,2018,90:482-489.
[19] 邓苏梦,王健,邹立强,等.食品级纳米粒子的合成及其应用[J].食品工业科技,2017,38(7):365-370.
DENG S,WANG J,ZOU L Q,et al.Synthesis and applications of nanoparticles in food[J]. Science and Technology of Food Industry,2017,38(7):365-370.
[20] YANG H,SU Z W,MENG X H,et al.Fabrication and characterization of Pickering emulsion stabilized by soy protein isolate-chitosan nanoparticles[J].Carbohydrate Polymers,2020,247:116 712.
[21] VINCENZO C,COURTENAY J C C,EDLER K J,et al.Pickering emulsions stabilized by naturally derived or biodegradable particles[J].Current Opinion in Green and Sustainable Chemistry,2018,12(4):83-90.
[22] REN C,TANG L,ZHANG M,et al.Structural characterization of heat-induced protein particles in soy milk[J].Journal of Agricultural & Food Chemistry,2009,57(5):1 921-1 926.
[23] LAM S,VELIKOV K P,VELEV O D.Pickering stabilization of foams and emulsions with particles of biological origin[J].Current Opinion in Colloid & Interface Science,2014,19(5):490-500.
[24] LIANG H N,TANG C H.Pea protein exhibits a novel Pickering stabilization for oil-in-water emulsions at pH 3.0[J].LWT Food Science & Technology,2014,58(2):463-469.
[25] 张远红.大豆肽基纳米颗粒的制备、界面行为及功能性输送的研究[D].广州:华南理工大学,2018.
ZHANG Y H.Preparation,interfacial behavior and functional transport of soybean peptide based nanoparticles[D].Guangzhou:South China University of Technology,2018.
[26] ZHU X F,ZHANG N,LIN W F,et al.Freeze-thaw stability of pickering emulsions stabilized by soy and whey protein particles[J].Food Hydrocolloids,2017,69:173-184.
[27] ZHU X F,ZHENG J,LIU F,et al.Freeze-thaw stability of Pickering emulsions stabilized by soy protein nanoparticles.Influence of ionic strength before or after emulsification[J].Food Hydrocolloids,2017,74:37-45.
[28] LIU F,OU S Y,TANG C H.Ca2+-induced soy protein nanoparticles as pickering stabilizers:Fabrication and characterization[J].Food Hydrocolloids,2017,65:175-186.
[29] 金蓓, 官金敏,许佳音,等.光催化大豆蛋白纳米颗粒皮克林乳液的制备及稳定性研究[J].中国食品学报,2018,18(1):162-168.
JIN B,GUAN J M,XU J Y,et al.Studies on preparation and stability of pickering emulsion of soy protein nanoparticle obtained through photocatalysis[J].Journal of Chinese Institude of Food Science and Technology,2018,18(1):162-168.
[30] XIN S L,XIAO L,DONG X P,et al.Preparation of chitosan/curcumin nanoparticles based zein and potato starch composite films for Schizothorax prenati fillet preservation[J].Biological Macromolecules,2020,164:211-221.
[31] RUTKEVICIUS M,ALLRED S,VELEV O D,et al.Stabilization of oil continuous emulsions with colloidal particles from water-insoluble plant proteins[J].Food Hydrocolloids,2018,82:89-95.
[32] 刘瑞琦, 唐文婷,蒲传奋.玉米醇溶蛋白肽-丁香酚纳米复合粒子稳定的皮克林乳液的制备及性质[J].粮食与油脂,2019,32(3):45-49.
LIU R Q,TANG W T,PU C F.Preparation and properties of Pickering emulsion stabilized by zein peptide-eugenol nanocomposite particle[J].Cereals and Oils,2019,32(3):45-49.
[33] ZHAO Z J,LU M W,MOA E,et al.Modulation of interfacial phenolic antioxidant distribution in Pickering emulsions via interactions between zein nanoparticles and gallic acid[J].International Journal of Biological Macromolecules,2020,152:223-233.
[34] 吴滋灵, 周福珍,尹艳,等.超声处理制备小麦醇溶蛋白胶体颗粒Pickering乳液及其表征[J].现代食品科技,2018,34(7):129-133;263.
WU Z L,ZHOU F Z,YIN Y,et al.Preparation and characterization of pickering emulsion of wheat gliadin colloidal particles by ultrasonic treatment[J].Modern Food Science and Technology,2018,34(7):129-133;263.
[35] 刘兴丽, 赵双丽,肖乃勇,等.马铃薯蛋白微凝胶对皮克林乳液乳化特性的影响[J].轻工学报,2019,34(5):1-9.
LIU X L,ZHAO S L,XIAO N Y,et al.Effect of potato protein microgel on emulsifying properties of Pickering emulsion[J].Journal of Light Industry,2019,34(5):1-9.
[36] BI A Q,GUO Y,DU M,et al.Ultrasound pre-fractured casein and in-situ formation of high internal phase emulsions[J].Ultrasonics Sonochemistry,2020,64(3):104 916.
[37] CHEN S S,ZHANG L M.Casein nanogels as effective stabilizers for Pickering high internal phase emulsions[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2019,579:123 662.
[38] WANG P,CHEN C,GUO H,et al.Casein gel particles as novel soft Pickering stabilizers:The emulsifying property and packing behaviour at the oil-water interface[J].Food Hydrocolloids,2018,77:689-698.
[39] DICKINSON E,PARKINSON EL.Heat-induced aggregation of milk protein-stabilized emulsions:Sensitivity to processing and composition[J].International Dairy Journal,2003,14(7):635-645.
[40] ZHANG W,ZHONG Q.Microemulsions as nanoreactors to produce whey protein nanoparticles with enhanced heat stability by thermal pretreatment[J].Food Chemistry,2010,119(4):1 318-1 325.
[41] WU J,SHI M,LI W,et al.Pickering emulsions stabilized by whey protein nanoparticles prepared by thermal cross-linking[J].Colloids Surf B Biointerfaces,2015,127:96-104.
[42] LV P,WANG D,DAI L,et al.Pickering emulsion gels stabilized by high hydrostatic pressure-induced whey protein isolate gel particles:Characterization and encapsulation of curcumin[J].Food Research International,2019,132(6):109 032.
[43] XU Y T,YANG T,LIU L L,et al.One-step fabrication of multifunctional high internal phase pickering emulsion gels solely stabilized by a softer globular protein nanoparticle:S-Ovalbumin[J].Journal of Colloid and Interface Science,2020,580:515-527.
[44] ZANG X D,WNAG J W,YU G P,et al.Addition of anionic polysaccharides to improve the stability of rice bran protein hydrolysate-stabilized emulsions[J].LWT,2019,111:573-581.
[45] SANTOS J,ALCAIDE-GONZALEZ A M,TRUJILLO-CAYADO A L,et al.Development of food-grade Pickering emulsions stabilized by a biological macromolecule (xanthan gum) and zein[J].International Journal of Biological Macromolecules[J].2020,153:747-754.
[46] ZHANG Z K,XIAO J X,HUANG G Q.Pickering emulsions stabilized by ovalbumin-sodium alginate coacervates[J].Colloids and Surfaces A Physicochemical and Engineering Aspects,2020,595:124712.
[47] ZHANG X,LUO X,WANG Y,et al.Concentrated O/W Pickering emulsions stabilized by soy protein/cellulose nanofibrils:Influence of pH on the emulsification performance[J].Food Hydrocolloids,2020,108:106 025.
[48] 陈雨桐. 小麦醇溶蛋白/单宁酸复合物稳定的皮克林乳液体系的构建及应用[D].武汉:华中农业大学,2019.
CHEN Y T.Construction and application of stable Pickering emulsion system of wheat gliadin/tannin complex[D].Wuhan:Huazhong Agricultural University,2019.
[49] 鞠梦楠, 祝钢,刘英杰,等.大豆分离蛋白-花青素共价复合物制备纳米颗粒及其Pickering乳液特性分析[J].食品科学,2019,40(20):8-13.
JU M N,ZHU G,LIU Y J,et al.Fabrication and characterization of pickering emulsions stabilized by covalent composite nanoparticles of soy protein isolate and anthocyanins[J].Food Science,2019,40(20):8-13.
[50] ZEMBYLA M,MURRAY B S,RADFORD S J,et al.Water-in-oil pickering emulsions stabilized by an interfacial complex of water-insoluble polyphenol crystals and protein[J].Journal of Colloid and Interface Science,2019,548:88-99.
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