生产与科研应用

多粮清香型白酒酿造工艺的优化

  • 尹雅洁 ,
  • 王晓军 ,
  • 姜欣 ,
  • 王丽华 ,
  • 苏志华 ,
  • 栗伟 ,
  • 江伟 ,
  • 田福义 ,
  • 韩兴林 ,
  • 胡远亮
展开
  • 1(湖北师范大学 生命科学学院,食用野生植物保育与利用湖北省重点实验室,湖北 黄石,435002)
    2(中国食品发酵工业研究院,国家酒类品质与安全国际联合研究中心,北京,100015)
    3(承德大清猎苑酒业有限公司,河北 承德,068450)
    4(黑龙江省轻工科学研究院,黑龙江 哈尔滨,150001)
硕士研究生(胡远亮副教授为通讯作者,E-mail:yuanlianghu@yeah.net)

收稿日期: 2020-10-27

  修回日期: 2021-01-18

  网络出版日期: 2021-11-04

基金资助

国家自然科学基金项目(51965009);湖北师范大学研究生科研创新项目(20200139)

Process optimization for production of multi-grain light aroma type Baijiu

  • YIN Yajie ,
  • WANG Xiaojun ,
  • JIANG Xin ,
  • WANG Lihua ,
  • SU Zhihua ,
  • LI Wei ,
  • JIANG Wei ,
  • TIAN Fuyi ,
  • HAN Xinglin ,
  • HU Yuanliang
Expand
  • 1(Hubei Key Laboratory of Edible Wild Plants Conservation and Utilization,College of Life Sciences, Hubei Normal University,Huangshi 435002,China)
    2(International Joint Research Center of Quality and Safety of Alcoholic Beverages,China National Research Institute of Food and Fermentation Industries,Beijing 100015,China)
    3(Chengde Daqinglieyuan Liquor Co.Ltd.,Chengde 068450,China)
    4(Heilongjiang Institute of Light Industry Research Institute,Harbin 150001,China)

Received date: 2020-10-27

  Revised date: 2021-01-18

  Online published: 2021-11-04

摘要

酿酒原料对白酒的质量与品质有着重要的影响。以高粱为主要原料,承德市当地量产的特色黍米、玉米和莜麦等为辅料,对比研究了7种不同多粮配比的清香型白酒酒样,并结合气相色谱联用、香气活性阈值分析、感官品评和多元统计学分析了7种实验白酒的风味物质。单因素方差分析显示,每一种方案中的各种物质均存在显著性差异(P<0.001),其中方案6(高粱80%+玉米10%+黄米10%)的酒体酯类物质以乙酸乙酯含量较高(4 889.97 mg/L),醇类物质以异戊醇(393.21 mg/L)、异丁醇(262.53 mg/L)为主,总醛含量较高,且未检测出糠醛。香气活性阈值法、主成分分析载荷图均显示香气阈值较大(>1)的风味物质,如异丁醛、辛酸乙酯、戊酸乙酯、乙酸乙酯、乙酸异戊酯等对方案6的白酒酒体贡献较大;结合主成分分析发现,方案6的风味物质与其他方案的风味物质存在较大差异。通过感官品评,方案6的酒体酯香突出,酒体协调性好。

本文引用格式

尹雅洁 , 王晓军 , 姜欣 , 王丽华 , 苏志华 , 栗伟 , 江伟 , 田福义 , 韩兴林 , 胡远亮 . 多粮清香型白酒酿造工艺的优化[J]. 食品与发酵工业, 2021 , 47(19) : 140 -145 . DOI: 10.13995/j.cnki.11-1802/ts.026012

Abstract

The quality of Chinese Baijiu was greatly affected by raw materials. Sorghum was used as the main raw material, together with millet, corn and naked oats produced locally in Chengde city, light aroma type Baijiu made with different multi-grain ratio were compared and studied. One-way ANOVA showed that the main ester in scheme 6 (sorghum 80%, corn 10%, yellow rice 10%) were 4 889.97 mg/L of ethyl acetate; the alcohols were mainly 393.21 mg/L of isoamyl alcohol and 262.53 mg/L of isobutanol; the total aldehyde content was high, with no furfural detected. Aroma activity threshold method and principal component analysis showed that the flavor with higher aroma threshold contributed greatly to the liquor body of scheme 6, such as isobutyraldehyde, ethyl octanoate, ethyl valerate, ethyl acetate and isoamyl acetate. Combined with principal component analysis, it was found that the flavor substances of scheme 6 were quite different from others. Through sensory evaluation, the ester aroma in scheme 6 was outstanding and the coordination was good.

参考文献

[1] HAN X L,WANG D L,ZHANG W J,et al.The production of the Chinese baijiu from sorghum and other cereals[J].Journal of the Institute of Brewing,2017,123(4):600-604.
[2] 吕佳慧. 白酒酿酒和制曲原料中结合态风味物质的研究[D].无锡:江南大学,2017.
LYU J H.Bound aroma compounds of liquor-making and qu-making materials[D].Wuxi:Jiangnan University,2017.
[3] LIU H L,SUN B G.Effect of fermentation processing on the flavor of baijiu[J].Journal of Agricultural and Food Chemistry,2018,66(22):5 425-5 432.
[4] 吴海静, 钟继仁,田晓林,等.大黄米白酒高级醇产生规律的研究[J].中国酿造,2016,35(11):99-102.
WU H J,ZHONG J R,TIAN X L,et al.Regularity of higher alcohols production during fermentation of glutinous millet Baijiu[J].China Brewing,2016,35(11):99-102.
[5] 陈彬, 何宏魁,李安军,等.不同粮食品种对清香型大曲酒风味的影响[J].中国酿造,2017,36(7):22-26.
CHEN B,HE H K,LI A J,et al.Effect of different grain varieties on the flavor of Fen-flavour Daqu Baijiu (Chinese liquor)[J].China Brewing,2017,36(7):22-26.
[6] 江伟, 韦杰,李宝生,等.不同原料酿造单粮白酒风味物质特异性分析[J].食品科学,2020,41(14):234-238.
JIANG W,WEI J,LI B S,et al.Analysis of characteristic flavor compounds in single-grain Chinese Baijiu brewed from different raw materials[J].Food Science,2020,41(14):234-238.
[7] 吴幼茹, 刘诗宇,樊晓璐,等.GC-O-MS分析5种酿酒原料中蒸煮香气成分[J].食品科学,2016,37(24):94-98.
WU Y R,LIU S Y,FAN X L,et al.Analysis of aroma components of five different cooked grains used for Chinese liquor production by GC-O-MS[J].Food Science,2016,37(24):94-98.
[8] 彭智辅, 赵东,郑佳,等.利用AEDA比较五粮粉一次蒸煮与二次蒸煮中的香气活性成分[J].食品与发酵工业,2017,43(11):1-8.
PENG Z F,ZHAO D,ZHENG J,et al.Comparison of odor-active compounds in distillates of five grains between first time and second time distillation using AEDA[J].Food and Fermentation Industries,2017,43(11):1-8.
[9] 杨玉波, 倪德让,林琳,等.高粱蒸煮风味物质香气活力研究[J].食品与发酵工业,2018,44(5):222-226.
YANG Y B,Ni D R,LIN L,et al.Odor activity study on the aroma compounds of steamed sorghum[J].Food and Fermentation Industries,2018,44(5):222-226.
[10] 闫涵, 范文来,徐岩.单粮和多粮型白酒发酵过程的成分差异分析[J/OL].食品科学:1-7[2020-09-30].http://kns.cnki.net/kcms/detail/11.2206.TS.20200722.1426.110.html.
YAN H,FAN W L,XU Y.The differences in the composition of baijiu made by single grain and multiple grain[J/OL].Food Science,1-7[2020-09-30].http://kns.cnki.net/kcms/detail/11.2206.TS.20200722.1426.110.html.
[11] ZHU J C,WANG L Y,XIAO Z B,et al.Characterization of the key aroma compounds in mulberry fruits by application of gas chromatography-olfactometry (GC-O),odor activity value (OAV),gas chromatography-mass spectrometry (GC-MS) and flame photometric detection (FPD)[J].Food Chemistry,2018,245:775-785.
[12] 马宇. 基于风味组学策略研究酱香型白酒关键成分及其呈香呈味特性[D].贵阳:贵州大学,2019.
MA Y.Study on key components and flavor characteristics of Maotai-flavor liquor based on flavology strategy[D].Guiyang:Guizhou University,2019.
[13] ZHENG Y,SUN B G,ZHAO M M,et al.Characterization of the key odorants in Chinese Zhima aroma-type Baijiu by gas chromatography-olfactometry,quantitative measurements,aroma recombination,and omission studies[J].Journal of Agricultural and Food Chemistry,2016,64(26):5 367-5 374.
[14] 邢爽. 白酒发酵过程中酯类物质形成机理的研究[D].天津:天津科技大学,2018.
XING S.Research of the formation mechanism of esters in process of liquor fermentation[D].Tianjin:Tianjin University of Science and Technology,2018.
[15] 郭学武, 范恩帝,马冰涛,等.中国白酒中微量成分研究进展[J].食品科学,2020,41(11):267-276.
GUO X W,FAN E D,MA B T,t al.Research progress on trace components of Chinese Baijiu[J].Food Science,2020,41(11):267-276.
[16] KIM H M,YANG G,KIM J Y,et al.Simultaneous determination of volatile organic compounds in commercial alcoholic beverages by gas chromatography with flame ionization detection[J].Journal of AOAC INTERNATIONAL,2017,100(5):1 492-1 499.
[17] 格绒泽仁, 皇甫洁,韩兴林,等.浓香型白酒饮后不适感关键高级醇类物质关联性判定新方法[J].食品与发酵工业,2019,45(14):191-195.
GERONG Z R,HUANGFU J,HAN X L,et al.A method for determining associations between drinking discomforts and key higher alcohols in strong-aroma Baijiu[J].Food and Fermentation Industries,2019,45(14):191-195.
[18] 张卫卫, 刘建学,韩四海,等.白酒基酒中醛类物质的傅里叶变换近红外光谱检测[J].食品科学,2016,37(6):111-115.
ZHANG W W,LIU J X,HAN S H,et al.Determination of aldehydes in liquor base based on Fourier transform near-infrared spectroscopy[J].Food Science,2016,37(6):111-115.
[19] 张敏, 杨玉珍,李擎,等.白酒中主要醇类和醛类代谢途径与饮用健康的分析研究[J].酿酒科技,2017(1):124-128.
ZHANG M,YANG Y Z,LI Q,et al.Metabolic pathway of main alcohols and aldehydes in Baijiu and its relationship with health drinking[J].Liquor-Making Science and Technology,2017(1):124-128.
[20] 施珂, 孙啸涛,沈才洪,等.基于直接-气相色谱-嗅闻的整体感官评价模式分析泸香型白酒的关键香气成分[J].食品工业科技,2020,41(7):208-219.
SHI K,SUN X T,SHEN C H,et al.Study on the key aroma components of Luzhou-flavor Baijiu based on overall sensory evaluation model by direct-gas chromatography-olfaction[J].Science and Technology of Food Industry,2020,41(7):208-219.
[21] 范文来, 徐岩.白酒79个风味化合物嗅觉阈值测定[J].酿酒,2011,38(4):80-84.
FAN W L,XU Y.Determination of odor thresholds of volatile aroma compounds in Baijiu by a forced-choice ascending concentration series method of limits[J].Liquor Making,2011,38(4):80-84.
文章导航

/