食品与发酵工业 >

2021 , Vol. 47 >Issue 22: 55 - 62

DOI: https://doi.org/10.13995/j.cnki.11-1802/ts.026467

研究报告

不同高粱酿造性能与单粮清香型白酒品质的关联性研究

  • 李宝生 ,
  • 杨凯环 ,
  • 苏建如 ,
  • 江伟 ,
  • 董建辉 ,
  • 相里加雄 ,
  • 赵向东 ,
  • 王富贵 ,
  • 柯涛
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  • 1(南阳师范学院 生命科学与技术学院,河南 南阳,473061)
    2(中国食品发酵工业研究院有限公司,国家酒类品质与安全国际联合研究中心,北京,100015)
    3(山西杏花村汾酒集团有限责任公司,山西 汾阳,032205)
    4(贵州民族大学 生态环境工程学院,贵州 贵阳,550025)
硕士研究生(江伟高级工程师为通讯作者,E-mail:jiangweigyig@163.com)

收稿日期: 2020-12-16

  修回日期: 2021-03-18

  网络出版日期: 2021-12-16

基金资助

国家现代农业(大麦青稞)产业技术体系建设专项(CARS-05);中国酒业协会白酒产业技术战略创造联盟项目(20160919A)

收起

Correlation between the brewing performance of different sorghum varieties and the quality of single grain light-aroma Baijiu

  • LI Baosheng ,
  • YANG Kaihuan ,
  • SU Jianru ,
  • JIANG Wei ,
  • DONG Jianhui ,
  • XIANGLI Jiaxiong ,
  • ZHAO Xiangdong ,
  • WANG Fugui ,
  • KE Tao
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  • 1(School of Life Science and Technology, Nanyang Normal University, Nanyang 473061, China)
    2(International Joint Research Center of Quality and Safety of Alcoholic Beverages, China National Research Institute of Food and Fermentation Industries, Beijing 100015, China)
    3(Shanxi Xinghua village Fenjiu Group Co.Ltd., Fenyang 032205, China)
    4(Eco-Environment Engineering College, Guizhou Minzu University, Guiyang 550025, China)

Received date: 2020-12-16

  Revised date: 2021-03-18

  Online published: 2021-12-16

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摘要

优质原料的筛选是酿造优质白酒的重要因素。基于5种不同高粱的酿造性能分析包括水分、蛋白质、脂肪、淀粉、支链淀粉、直链淀粉、单宁、糊化率和吸水率9项指标,经主成分分析和聚类分析发现,5种高粱均符合酿造需求。其中高粱G1与其他4种高粱的酿造性能差异最大,其次是G3差异较大,而G2、G4和G5的性能最为相似,归为同一类。将5种高粱品种进行酿造,应用气相色谱技术测定分析了42种挥发性风味化合物,且每种风味物质均存在不同程度的显著性差异,相对标准偏差为2.49%~113.35%。应用主成分分析手段发现白酒G2和G4最为接近,但白酒G5、G1和G3与前两者也存在着明显差异。可见在酿造工艺相同的情况下,高粱品种的相似性在一定程度上可反映出酒体的相似性。同时,相关性分析发现支链淀粉含量对出酒率有着重要的正面影响,且脂肪与高级脂肪酸乙酯存在着中偏低的正相关关系。结合感官品评和风味数据,发现G3白酒的清香型风格最为典型,综合得分最高,因此确定高粱G3最适合单粮清香型白酒工艺,研究结果为清香型白酒的生产及质量调控提供了有效的科技支撑。

关键词： 酿酒性能; 气相色谱法; 聚类分析; 主成分分析; 相关性分析; 高级脂肪酸乙酯

本文引用格式

李宝生 , 杨凯环 , 苏建如 , 江伟 , 董建辉 , 相里加雄 , 赵向东 , 王富贵 , 柯涛 . 不同高粱酿造性能与单粮清香型白酒品质的关联性研究[J]. 食品与发酵工业, 2021 , 47(22) : 55 -62 . DOI: 10.13995/j.cnki.11-1802/ts.026467

Abstract

The screening of high-quality raw materials is an important factor in the brewing of high-quality Baijiu. Nine indicators of brewing performance for sorghum, including moisture, protein, coarse fat, starch, branch chain starch, straight chain starch, canonin, paste rate and water absorption rate were determined. According to the principal component analysis and clustering analysis, five different sorghum varieties were selected for the production of Baijiu. Among them, the difference among sorghum G1 and the other four varieties was the largest, followed by G3. The performance of G2, G4 and G5 was the most similar, and were classified into the same category. Five kinds of Baijiu were brewed from these five kinds of sorghum. Forty-two volatile flavor compounds were found in Baijiu by gas chromatography, and each flavor substance had differences, with a relative standard deviation between 2.49% and 113.35%. Baijiu G2 and G4 were the most similar according to the result of principal component analysis, but there were significant differences between Baijiu G5, G1, G3 and the former two. Under the same brewing process, the similarity of sorghum varieties can reflect the similarity of Baijiu to some extent. Branch-chain starch content had an important positive effect on the yield of alcohol. There was a positive correlation between crude fat and high fatty acid ethyl ester. Combined with sensory evaluation and flavor data, it was found that liquor fragrance style of Baijiu G3 was the most typical, and had the highest comprehensive score. Sorghum G3 is most suitable for single grain fragrance liquor process, which provides effective scientific and technological support for the production and quality control of Chinese Baijiu.

Key words： brewing performance; gas chromatography; clustering analysis; principal component analysis; correlation analysis; higher fatty acid ethyl esters

参考文献

[1] 陈翔, 滕抗,胡海洋, 等.白酒酿造原料对酒体风味影响的试验及讨论[J].酿酒, 2008, 35(1):19-22.
CHEN X, TENG K, HU H Y, et al.Experiment and discussion on effect of liquor flavor by liquor-making materials[J].Liquor Making, 2008, 35(1):19-22.
[2] 肖美兰, 吴生文, 刘建文.不同酿酒原料在特香型白酒生产中的应用[J].酿酒科技, 2015(11):81-84.
XIAO M L, WU S W, LIU J W.Application of different liquor-making raw materials in Texiang Baijiu (liquor) production[J].Liquor-Making Science & Technology, 2015(11):81-84.
[3] 陈彬, 何宏魁, 李安军, 等.不同粮食品种对清香型大曲酒风味的影响[J].中国酿造, 2017, 36(7), 22-26.
CHEN B, HE H K, LI A J, et al.Effect of different grain varieties on the flavor of Fen-flavour Daqu Baijiu (Chinese liquor)[J].China Brewing, 2017, 36(7), 22-26.
[4] 吴幼茹, 刘诗宇, 樊晓璐, 等.GC-O-MS分析5种酿酒原料中蒸煮香气成分[J].食品科学, 2016, 37(24):94-98.
WU Y R, LIU S Y, FAN X L, et al.Analysis of aroma components of five different cooked grains used for Chinese liquor production by GC-O-MS[J].Food Science, 2016, 37(24):94-98.
[5] 江伟, 韦杰, 李宝生, 等.不同原料酿造单粮白酒风味物质特异性分析[J].食品科学, 2020, 41(14):234-238.
JIANG W, WEI J, LI B S, et al.Analysis of characteristic flavor compounds in single-grain Chinese Baijiu brewed from different raw materials[J].Food Science, 2020, 41(14):234-238.
[6] 王雪薇, 江伟, 孙志伟, 等.藏区传统青稞发酵酒的风味特征剖析[J].食品与发酵工业, 2018, 44(11):286-291.
WANG X W, JIANG W, SUN Z W, et al.Analysis of flavor characteristics of traditional highland barley in Tibetan area[J].Food and Fermentation Industries, 2018, 44(11):286-291.
[7] 李颖星. 清香型白酒香气成分研究[D].太原:山西大学, 2020.
LI Y X.Study on aroma components of Fen-flavor Chinese Baijiu[D].Taiyuan:Shanxi University, 2020.
[8] LI R Y, ZHENG X W, ZHANG X, et al.Characterization of bacteria and yeasts isolated from traditional fermentation starter (Fen-Daqu) through a 1H NMR-based metabolomics approach[J].Food Microbiology, 2018, 76:11-20.
[9] 谢军, 甄攀, 罗惠波, 等.汾酒酿造室土壤真菌群落结构研究[J].食品与发酵科技, 2018, 54(3):113-116.
XIE J, ZHEN P, LUO H B, et al.Research the fungal community structure of soil in Fen wine brewing room[J].Food and Fermentation Science Technology, 2018, 54(3):113-116.
[10] 甄攀, 郭瑾, 郝希桐, 等.汾酒酿造微生物来源分析[J].酿酒, 2017, 44(6):46-49.
ZHEN P, GUO J, HAO X T, et al.Research the source of microbial in Fen wine brewing[J].Liquor Making, 2017, 44(6):46-49.
[11] ZHU J C, WANG L Y, XIAO Z B, et al.Characterization of the key aroma compounds in mulberry fruits by application of gas chromatography-olfactometry (GC-O), odor activity value (OAV), gas chromatography-mass spectrometry (GC-MS) and flame photometric detection (FPD)[J].Food Chemistry, 2018, 245:775-785.
[12] MOZA J, GUJRAL H S.Starch digestibility and bioactivity of high altitude hulless barley[J].Food Chemistry, 2016, 194:561-568.
[13] ABDULLA H, BASS J J, STOKES T, et al.The effect of oral essential amino acids on incretin hormone production in youth and ageing[J].Endocrinology, Diabetes & Metabolism, 2019, 2(4):e00085.
[14] 曹苗文, 相里加雄, 曹瑞红, 等.高粱性质对酿造清香型白酒的影响[J].酿酒科技, 2020(5):53-59.
CAO M W, XIANGLI J X, CAO R H, et al.Effects of sorghum properties on the fermentation of Qingxiang Baijiu[J].Liquor-Making Science & Technology, 2020(5):53-59.
[15] LIU H L, SUN B G.Effect of fermentation processing on the flavor of Baijiu[J].Journal of Agricultural and Food Chemistry, 2018, 66(22):5 425-5 432.
[16] 中华人民共和国国家卫生和计划生育委员会. GB 5009.3—2016 食品安全国家标准 食品中水分的测定[S].北京:中国标准出版社, 2016.
State Health and Family Planning Commission of the people's Republic of China.GB 5009.3—2016 National food safety standard Determination of moisture in foods[S].Beijing:China Standards Press, 2016.
[17] 中华人民共和国商业部. GB/T 5497—1985 粮食、油料检验水分测定方法[S].北京:中国标准出版社, 1985.
Ministry of Commerce of the People's Republic of China.GB/T 5497—1985 Inspection of grain and oilseeds methods for determination of moisture content[S].Beijing:China Standards Press, 1985.
[18] 中华人民共和国国家卫生和计划生育委员会, 国家食品药品监督管理总局.GB 5009.5—2016 食品安全国家标准 食品中蛋白质质的测定[S].北京:中国标准出版社, 2016.
State Health and Family Planning Commission of the people's Republic of China, China Food and Drug Administration.GB 5009.5—2016 National food safety standard Determination of protein in foods[S].Beijing:China Standards Press, 2016.
[19] 中华人民共和国国家质量监督检验检疫局, 中国国家标准化管理委员会.GB/T 7416—2008 啤酒大麦[S].北京:中国标准出版社, 2008.
State Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, China National Standardization Administration Committee.GB/T 7416—2008 Malting barley[S].Beijing:China Standards Press, 2008.
[20] 中华人民共和国国家卫生和计划生育委员会, 国家食品药品监督管理总局.GB 5009.9—2016 食品安全国家标准 食品中淀粉的测定[S].北京:中国标准出版社, 2016.
State Health and Family Planning Commission of the people's Republic of China, China Food and Drug Administration.GB 5009.5—2016 National food safety standard Determination of starch in foods[S].Beijing:China Standards Press, 2016.
[21] 中华人民共和国国家质量监督检验检疫局, 中国国家标准化管理委员会.GB/T 15686—2008 高粱 单宁含量的测定[S].北京:中国标准出版社, 2008.
State Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, China National Standardization Administration Committee.GB/T 15686—2008 Sorghum-Determination of tannin content [S].Beijing:China Standards Press, 2008.
[22] 中华人民共和国海关总署. SN/T 0800.10—2019 进出口粮食、饲料 大豆粉吸水率检验方法[S].北京:中国标准出版社, 2019.
General Administration of Customs of the People's Republic of China.SN/T 0800.10—2019 Determination of water absorption of cereals and feedstuffs soybean flour for import and export [S].Beijing:China Standards Press, 2019.
[23] 中华人民共和国国家卫生和计划生育委员会, 国家食品药品监督管理总局.GB 5009.9—2016 食品安全国家标准 食品中脂肪的测定[S].北京:中国标准出版社, 2016.
State Health and Family Planning Commission of the people's Republic of China, China Food and Drug Administration.GB 5009.5—2016 National food safety standard Determination of fat in foods[S].Beijing:China Standards Press, 2016.
[24] 郭旭凯, 杨玲, 张福耀, 等.高粱子粒理化特性与清香型大曲白酒酿造关系的研究[J].中国酿造, 2016, 35(12):40-43.
GUO X K, YANG L, ZHANG F Y, et al.Relationship between physicochemical properties of sorghum and Fen-flavor Daqu Baijiu fermentation[J].China Brewing, 2016, 35(12):40-43.
[25] 李大和, 李国红.浓香型曲酒酿造生产工艺要素(一)[J].酿酒, 2010, 37(4):5-10.
LI D H, LI G H.Key factors in Luzhou-flavor liquor production technology (Ⅰ)[J].Liquor Making, 2010, 37(4):5-10.
[26] 孙金旭, 王立召, 李长文.不同加曲量对酱香型白酒中杂油醇影响探讨[J].中国酿造, 2009,28(11):105-108;126.
SUN J X, WANG L Z, LI C W.Effect of different amount of Qu on fusel oils in Sauce-flavor hquor[J].China Brewing, 2009,28(11):105-108;126.
[27] 邰克东, 高彦祥, 袁芳.天然风味物质生物技术制备方法研究现状及展望[J].中国食品添加剂, 2016(1):152-158.
TAI K D, GAO Y X, YUAN F.Research status and prospect of natural flavors produced by biotechnology[J].China Food Additives, 2016(1):152-158.
[28] 冯兴垚, 杨文斌, 罗惠波, 等.三种酿酒高粱的理化特性与基酒风味分析[J].中国酿造, 2017, 36(8):76-79.
FENG X Y, YANG W B, LUO H B, et al.Physicochemical property of three varieties of sorghum for Baijiu-making and flavor of base liquor[J].China Brewing, 2017, 36(8):76-79.
[29] 田新惠,唐玉明,任道群,等.南北方酿酒高粱淀粉理化特性比较[J].食品与发酵工业,2017,43(1):91-95.
TIAN X H, TANG Y M, REN D Q, et al. Comparison of physicochemical properties of brewing sorghum starch in South and North China [J]. Food and Fermentation Industry, 2017,43 (1): 91-95.
[30] 焦少杰, 王黎明, 姜艳喜, 等.高粱与固态白酒关系的研究综述[J].酿酒, 2015, 42(1):13-16.
JIAO S J, WANG L M, JIANG Y X, et al.Research overview of the relationship between sorghum and solid liqueur[J].Liquor Making, 2015, 42(1):13-16.
[31] HAN X L, WANG D L, ZHANG W J, et al.The production of the Chinese Baijiu from sorghum and other cereals[J].Journal of the Institute of Brewing, 2017, 123(4):600-604.
[32] CAO M W, JIA T, MI J, et al.Relative roles of niche and neutral processes on turnover of plant, fungal and bacterial communities in arid and semi-arid areas at the regional scale[J].Basic & Applied Ecology, 2019, 40:43-54.
[33] 陈英, 余雄伟, 龚文发, 等.植物酵素发酵特性及风味物质变化的研究[J].饮料工业, 2015, 18(2):9-12.
CHEN Y, YU X W, GONG W F, et al.Study on fermentation property and the change of flavor substances of plant enzyme[J].The Beverage Industry, 2015, 18(2):9-12.
[34] KIM H M, YANG G, KIM J Y, et al.Simultaneous determination of volatile organic compounds in commercial alcoholic beverages by gas chromatography with flame ionization detection[J].Journal of AOAC International, 2017, 100(5): 1 492-1 499.
[35] 邢爽. 白酒发酵过程中酯类物质形成机理的研究[D].天津:天津科技大学, 2018.
XING S.Research of the formation mechanism of esters in process of liquor fermentation[D].Tianjin:Tianjin University of Science and Technology, 2018.
[36] 王青松, 王卫东, 谢玉球, 等.酒醅发酵过程中高级醇的变化规律[J].酿酒科技, 2018(1):65-68.
WANG Q S, WANG W D, XIE Y Q, et al.Change rules of higher alcohols in the fermentation process of fermented grains[J].Liquor-Making Science & Technology, 2018(1):65-68.
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