研究报告

高铁酸钾联合表面活性剂去除紫甘蓝、生菜中农药残留的条件优化

  • 卫晓怡 ,
  • 徐涵瑜 ,
  • 张路遥 ,
  • 司晓晶 ,
  • 韩梅 ,
  • 崔琳琳
展开
  • (上海商学院 酒店管理学院食品系,上海,200235)
第一作者:博士,副教授(通信作者,E-mail:weixy@ sbs.edu.cn)

收稿日期: 2022-01-05

  修回日期: 2022-02-09

  网络出版日期: 2022-06-23

基金资助

上商启明星科研项目(11999-3061);上海市自然科学基金项目(20ZR1440200);上海商学院校级一流本科课程建设项目(SBS-2022-XJJK-01);上海商学院校级教育教学改革研究项目(SBS-2022-XJJG-02);上海商学院大学生创新创业项目;上商青年科研创新团队项目(14KY-QNTD05)

Optimization on removal conditions of pesticide residues in purple cabbage and lettuce using potassium ferrate combined with surfactant

  • WEI Xiaoyi ,
  • XU Hanyu ,
  • ZHANG Luyao ,
  • SI Xiaojing ,
  • HAN Mei ,
  • CUI Linlin
Expand
  • (Department of Food Science, College of Hospitality Management, Shanghai Business School, Shanghai 200235, China)

Received date: 2022-01-05

  Revised date: 2022-02-09

  Online published: 2022-06-23

摘要

该研究以鲜切蔬菜中常见的紫甘蓝和生菜为研究对象,通过浸泡毒死蜱、乐果、丁硫克百威、联苯菊酯等农药导致叶面吸附而模拟农残超标,以响应面法优化高铁酸钾(K2FeO4)的清洗条件,并添加表面活性剂椰子油脂肪酸二乙醇酰胺(coconut oil fatty acid diethanolamide,CDEA)以提高蔬菜叶面农残的去除效果。结果表明,在28 ℃、0.6 g/L的K2FeO4清洗15 min的最优条件下,添加20 g/L CDEA使毒死蜱、乐果、丁硫克百威在紫甘蓝中去除率达77.35%、73.56%、70.12%,在生菜中达82.34%、78.11%、79.58%;添加80 g/L CDEA使联苯菊酯在紫甘蓝和生菜中的去除率分别为70.57%、74.48%。研究表明,K2FeO4结合CDEA是一种高效的农残去除剂,可推广应用于鲜切蔬菜的加工处理。

本文引用格式

卫晓怡 , 徐涵瑜 , 张路遥 , 司晓晶 , 韩梅 , 崔琳琳 . 高铁酸钾联合表面活性剂去除紫甘蓝、生菜中农药残留的条件优化[J]. 食品与发酵工业, 2022 , 48(11) : 192 -199 . DOI: 10.13995/j.cnki.11-1802/ts.030717

Abstract

In this study, purple cabbage and lettuce were used as raw material and soaked in chlorpyrifos, dimethoate, carbofuran, bifenthrin pesticides resulting in leaf pesticide adsorption exceed the maximum residue limits. The washing treatment by potassium ferrate (K2FeO4) was optimized by using the response surface methodology and the best parameters for removing vegetable pesticide residues was determined. Moreover, as a surfactant, the coconut oil fatty acid diethanolamide (CDEA) was added to improve the removal effect of pesticide residues on vegetables. The results showed that under the optimal conditions of 28 ℃ and 0.6 g/L K2FeO4 cleaning for 15 min, the removal rates of chlorpyrifos, dimethoate and carbosulfan in purple cabbage could reach 77.35%, 73.56% and 70.12% by adding 20 g/L CDEA. In lettuce, the removal rates were 82.34%, 78.11% and 79.58%. While the removal rate of bifenthrin were 70.57% and 74.48% by the addition of 80 g/L of CDEA in purple cabbage and lettuce, respectively. Therefore, the results showed that potassium ferrate combined with the surfactant was an effective pesticide residue remover, which could be widely used in fresh cut vegetables processing.

参考文献

[1] 鲜切蔬菜市场规模持续增长,行业标准化程度需提升[EB/OL].(2 019-06-04)[2 019-07-18].http://www.newsijie.com/chanye/nongye/jujiao/2019/0604/11248229.html.
[2] LI C J, ZHU H M, LI C Y, et al.The present situation of pesticide residues in China and their removal and transformation during food processing[J].Food Chemistry, 2021, 354:129552.
[3] 李读兴, 阚延荣.2016年—2020年枣庄市市售蔬菜中农药残留污染状况和膳食暴露评估[J].中国卫生检验杂志, 2021, 31(20):2 545-2 550.
LI D X, KAN Y R.Assessment of pesticide residues pollution and dietary exposure in commercially available vegetables in Zaozhuang city from 2016 to 2020[J].Chinese Journal of Health Laboratory Technology, 2021, 31(20):2 545-2 550.
[4] AHN S, KIM K D, LEE J N, et al.Removal efficiency of pesticide residues in Chinese cabbage produced in highland by washing[J].Korean Journal of Horticultural Science & Technology, 2008, 26(4):400-405.
[5] YANG T X, DOHERTY J, ZHAO B, et al.Effectiveness of commercial and homemade washing agents in removing pesticide residues on and in apples[J].Journal of Agricultural and Food Chemistry, 2017, 65(44):9 744-9 752.
[6] MISRA N N.The contribution of non-thermal and advanced oxidation technologies towards dissipation of pesticide residues[J].Trends in Food Science & Technology, 2015, 45(2):229-244.
[7] F M NOWOWI M, A M ISHAK M, ISMAIL K, et al.Study on the effectiveness of five cleaning solutions in removing chlorpyrifos residues in cauliflower (Brassica oleracea)[J].Journal of Environmental Chemistry and Ecotoxicology, 2016, 8(7):69-72.
[8] TAN X M, JI F Y, LI S, et al.Preparation and characterization of potassium ferrate[J].Advanced Materials Research, 2011, 197-198:800-806.
[9] 刘红玉. 高铁酸钾对叶菜类蔬菜中3种有机磷农药的降解作用研究[D].青岛:中国海洋大学, 2009.
LIU H Y.Studies on the degradation of three organophosphorous pesticides in leafy vegetables by potassium ferrate[D].Qingdao:Ocean University of China, 2009.
[10] ARYANTI N, KHOIRIYAH L, HENY D R, et al.Synthesis cocamide DEA as green surfactant from virgin coconut oil[J].IOP Conference Series:Materials Science and Engineering, 2021, 1 053(1):012066.
[11] PRESLEY C L, MILITELLO M, BARBER C, et al.The history of surfactants and review of their allergic and irritant properties[J].Dermatitis:Contact, Atopic, Occupational, Drug, 2021, 32(5):289-297.
[12] 李刚森, 蔡立芳, 王培义, 等.十二烷基硫酸钠与非离子表面活性剂AEO9/6501复配体系表面活性及动态表面张力研究[J].轻工学报, 2016, 31(5):51-57.
LI G S, CAI L F, WANG P Y, et al.Study on surface active and dynamic surface tension of K12 and AEO9/6501 complex systems[J].Journal of Light Industry, 2016, 31(5):51-57.
[13] 卫晓怡, 楼文高, 王胜桥, 等.绿叶菜农药残留去除的清洗方法[J].食品与发酵工业, 2014, 40(10):90-96.
WEI X Y, LOU W G, WANG S Q, et al.Optimization on pesticide residues removing methods of green leafy vegetables[J].Food and Fermentation Industries, 2014, 40(10):90-96.
[14] 岳鹏莹. 市售蔬菜中有机磷及氨基甲酸酯类农药残留分析[J].中国食品工业, 2021(23):115-116;123.
YUE P Y.Analysis of organophosphorus and carbamate pesticide residues in commercial vegetables[J].China Food Industry, 2021(23):115-116;123.
[15] GE J, LU M X, WANG D L, et al.Dissipation and distribution of chlorpyrifos in selected vegetables through foliage and root uptake[J].Chemosphere, 2016, 144:201-206.
[16] ZHOU Q Z, BIAN Y L, PENG Q R, et al.The effects and mechanism of using ultrasonic dishwasher to remove five pesticides from rape and grape[J].Food Chemistry, 2019, 298:125007.
[17] 刘红玉, 陈振德, 汪东风, 等.高铁酸钾对菠菜中3种有机磷农药残留降解的影响[J].生态毒理学报, 2009, 4(2):282-288.
LIU H Y, CHEN Z D, WANG D F, et al.Effects of potassium ferrate on degradation of three organophosphorous pesticides in spinach[J].Asian Journal of Ecotoxicology, 2009, 4(2):282-288.
[18] 阳如春. 高铁酸钾去除农药残留及其杂菌消毒效果的研究[D].北京:北京化工大学, 2005.
YANG R C.Study on effect of potassium ferrate on degradating residuary pesticide and sterilizing[D].Beijing:Beijing University of Chemical Technology, 2005.
[19] 郭盈岑, 农馥俏, 杨剑, 等.高铁酸钾对甘蔗中有机磷农药特丁磷、乐果残留降解的影响[J].轻工科技, 2014, 30(1):24-25;63.
GUO Y C, NONG F Q, YANG J, et al.Effect of potassium ferrate on degradation of organophosphorus pesticides terbuthion and dimethoate residues in sugarcane[J].Light Industry Science and Technology, 2014, 30(1):24-25;63.
[20] 张铁锴. 水溶液中Fe(Ⅵ)化合物的稳定性和动力学研究[D].大庆:大庆石油学院, 2005.
ZHANG T K.Studies on stability and kinetics of Fe(Ⅵ) compounds in aqueous solution[D].Daqing:Daqing Petroleum Institute, 2005.
[21] 左珍光, 谢刚, 胡桂英, 等.毒死蜱在甘蓝和土壤中的残留消解动态研究[J].广东化工, 2019, 46(1):1-2;11.
ZUO Z G, XIE G, HU G Y, et al.Degradation dynamic study of chlorpyrifos in cabbage and soil[J].Guangdong Chemical Industry, 2019, 46(1):1-2;11.
[22] 姜慧梅, 孙慧, 顾黄辉, 等.40%乐果乳油在甘蓝和土壤中的残留及消解动态[J].农药, 2007, 46(4):254-255;257.
JIANG H M, SUN H, GU H H, et al.Residues and degradation dynamics of dimethoate 40% EC in cabbage and soils[J].Agrochemicals, 2007, 46(4):254-255;257.
[23] 秦冬梅, 龚勇.好年冬在甘蓝及土壤中残留动态[J].农药科学与管理, 2000, 21(1):21-23;33.
QIN D M, GONG Y.Study on the residue dynamics of marshal in the cabbage and soil[J].Pesticide Science and Administration, 2000, 21(1):21-23;33.
[24] 陈丽霞, 韩丙军, 彭黎旭.热带气候下联苯菊酯在甘蓝和土壤中的残留降解动态[J].现代农药, 2008, 7(5):32-35.
CHEN L X, HAN B J, PENG L X.Residue analysis and degradation of bifenthrin in cabbage and soil under tropical climate[J].Modern Agrochemicals, 2008, 7(5):32-35.
[25] 康燕玉. 联苯菊酯在土壤中残留动态以及相关降解影响因子的研究[J].农业环境与发展, 2013, 30(1):86-89.
KANG Y Y.Study on residue dynamics of bifenthrin in soil and related degradation factors[J].Agro-Environment & Development, 2013, 30(1):86-89.
[26] KAR A, MANDAL K, SINGH B.Decontamination of chlorantraniliprole residues on cabbage and cauliflower through household processing methods[J].Bulletin of Environmental Contamination and Toxicology, 2012, 88(4):501-506.
[27] WANG Z, HUANG J, CHEN J, et al.Effectiveness of dishwashing liquids in removing chlorothalonil and chlorpyrifos residues from cherry tomatoes[J].Chemosphere, 2013, 92(8):1 022-1 028.
[28] 刘炜, 刘行, 王艺多, 等.清洗方法对葡萄中四种农药残留的去除效果分析[J].湖北农业科学, 2021, 60(17):116-120.
LIU W, LIU X, WANG Y D, et al.Removal effect of five kinds of cleaning methods on four pesticide residues in grape[J].Hubei Agricultural Sciences, 2021, 60(17):116-120.
文章导航

/