研究报告

二醛基纤维素/羧甲基纤维素复合薄膜的制备及在鸡蛋保鲜中的应用

  • 田玥 ,
  • 徐昊洋 ,
  • 康晓鸥 ,
  • 赵敏孜 ,
  • 阮长晴
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  • 1(西南大学 食品科学学院,重庆,400715)
    2(西南大学食品贮藏与物流研究中心,重庆,400715)
第一作者:本科生(阮长晴副教授为通信作者,E-mail:changqing.r@hotmail.com)

收稿日期: 2021-07-09

  修回日期: 2021-09-18

  网络出版日期: 2022-10-01

基金资助

国家自然科学青年基金项目(32001752);川菜发展研究中心科研项目(CC21Z04)

Preparation of dialdehyde cellulose/carboxymethyl cellulose composite film and its application in egg preservation

  • TIAN Yue ,
  • XU Haoyang ,
  • KANG Xiaoou ,
  • ZHAO Minzi ,
  • RUAN Changqing
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  • 1(College of Food Science, Southwest University, Chongqing 400715, China)
    2(Food Storage and Logistics Research Center, Southwest University, Chongqing 400715, China)

Received date: 2021-07-09

  Revised date: 2021-09-18

  Online published: 2022-10-01

摘要

为寻求绿色、安全的天然高分子涂膜应用于鸡蛋保鲜,选取二醛基纤维素(cellulose,DAC)和羧甲基纤维素(carboxymethyl cellulose,CMC)2种天然高分子材料进行复合,对鸡蛋进行涂膜保鲜。利用高碘酸钠氧化纤维素制备DAC,加热使其成为水溶性DAC后与CMC进行交联制备复合薄膜,并对其力学性能、阻隔性能、亲水性进行表征;然后将复合涂膜剂应用于鸡蛋保鲜,考察60 d内其对鸡蛋感官品质、失重率、哈氏单位、蛋黄系数和蛋清pH的影响。结果表明,DAC的添加有利于提高复合膜的拉伸强度,增强复合膜对水蒸气和氧气的阻隔性,降低复合膜的亲水性。在对鸡蛋保鲜效果的考察中,发现复合涂膜剂对鸡蛋的失重率、哈氏单位、蛋黄系数、蛋清pH等指标的降低均有良好的抑制效果,其中DAC添加量占CMC干重12%,pH为5的复合涂膜剂的保鲜效果最佳。研究所得的高分子复合材料在绿色包装材料领域、可食性涂膜保鲜方面有重要应用价值。

本文引用格式

田玥 , 徐昊洋 , 康晓鸥 , 赵敏孜 , 阮长晴 . 二醛基纤维素/羧甲基纤维素复合薄膜的制备及在鸡蛋保鲜中的应用[J]. 食品与发酵工业, 2022 , 48(17) : 207 -213 . DOI: 10.13995/j.cnki.11-1802/ts.028558

Abstract

To seek green and safe natural polymer coating film applied to egg preservation, two natural polymer materials, dialdehyde cellulose (DAC) and carboxymethyl cellulose (CMC) were selected to prepare composite films which were applied in coating eggs for fresh-keeping. Firstly, DAC oxidized from cellulose by sodium periodate was heated to make it water-soluble, and then cross-linked with CMC to prepare the composite film (DAC/CMC). The mechanical properties, barrier properties, and hydrophilicity of DAC/CMC were characterized. Furthermore, DAC/CMC was applied as a coating agent for the preservation of the egg, and its effects on the organoleptic quality, weight loss rate, Hastelloy unit, yolk coefficient and pH of the egg white within 60 d were investigated. The results showed that the addition of DAC improved the tensile strength of composite film and further inhibited water vapor and oxygen. It also reduced the hydrophilicity of the composite film. The coating agent had a good inhibitory effect on the reduction of weight, huff unit, yolk coefficient, and pH of egg white. The coating agent with DAC accounting for 12% of the dry weight of CMC and pH 5 was the best condition for fresh-keeping. The polymer composite material has a promising application in green packaging material and the preservation of edible coating film.

参考文献

[1] 陈春霞, 刘筱霞.浅谈鲜鸡蛋的保鲜包装加工一体化工艺[J].包装与食品机械, 2009, 27(1):63-65.
CHEN C X, LIU X X.The procedures of fresh eggs packaging and processing incorporation[J].Packaging and Food Machinery, 2009, 27(1):63-65.
[2] 刘磊, 郑江霞, 秦宇辉, 等.“涂膜保鲜”技术在鸡蛋加工领域的应用及效果分析[J].中国畜牧杂志, 2014, 50(6):69-74.
LIU L, ZHENG J X, QIN Y H, et al.Application and evaluation of egg oiling on keeping eggs freshness in processing industry[J].Chinese Journal of Animal Science, 2014, 50(6):69-74.
[3] 王晶. 壳聚糖及其复合涂膜对鸡蛋的保鲜效果[D].重庆:西南大学, 2018.
WANG J.The effect of chitosan and its composite coating on egg preservation[D].Chongqing:Southwest University, 2018.
[4] 黄静, 罗吉庆, 罗丹, 等.鸡蛋贮藏保鲜的优化研究[J].食品与发酵科技, 2019, 55(6):39-45;54.
HUANG J, LUO J Q, LUO D, et al.Optimization research of egg fresh preservation[J].Food and Fermentation Sciences & Technology, 2019, 55(6):39-45;54.
[5] 陈玲. 海藻酸钠涂膜鸡蛋的保鲜效果[J].食品安全导刊, 2017(6):147-149.
CHEN L.The fresh-keeping effect of sodium alginate coated eggs[J].China Food Safety Magazine, 2017(6):147-149.
[6] 戴宏民, 戴佩燕.绿色包装发展的新趋势[J].包装学报, 2016, 8(1):82-89.
DAI H M, DAI P Y.New trends in the development of green packaging[J].Packaging Journal, 2016, 8(1):82-89.
[7] PLAPPERT S F, QURAISHI S, PIRCHER N, et al.Transparent, flexible, and strong 2, 3-dialdehyde cellulose films with high oxygen barrier properties[J].Biomacromolecules, 2018, 19(7):2 969-2 978.
[8] 李健, 刘雅南, 刘宁, 等.羧甲基纤维素的制备研究及应用现状[J].食品工业科技, 2014, 35(8):379-382.
LI J, LIU Y N, LIU N, et al.Study on the preparation and application status of carboxymethyl cellulose[J].Science and Technology of Food Industry, 2014, 35(8):379-382.
[9] 丁婷婷, 李倩, 金贞福, 等.纳米化竹粉/羧甲基纤维素复合膜材料制备及性能研究[J].林业工程学报, 2017, 2(5):90-94.
DING T T, LI Q, JIN Z F, et al.Preparation and properties of bamboo nano powder/carboxymethyl cellulose composite film[J].Journal of Forestry Engineering, 2017, 2(5):90-94.
[10] KIM U J, WADA M, KUGA S.Solubilization of dialdehyde cellulose by hot water[J].Carbohydrate Polymers, 2004, 56(1):7-10.
[11] KIM U J, LEE Y R, KANG T H, et al.Protein adsorption of dialdehyde cellulose-crosslinked chitosan with high amino group contents[J].Carbohydrate Polymers, 2017, 163:34-42.
[12] 高庞业. 双醛化纤维素的制备及其抗菌性能研究[D].秦皇岛:燕山大学, 2019.
GAO P Y.Preparation of dialdehyde cellulose and evaluation of its antibacterial properties[D].Qinhuangdao:Yanshan University, 2019.
[13] PARALIKAR S A, SIMONSEN J, LOMBARDI J.Poly(vinyl alcohol)/cellulose nanocrystal barrier membranes[J].Journal of Membrane Science, 2008, 320(1-2):248-258.
[14] MÜNSTER L, VÍCHA J, KLOFÁČ J, et al.Stability and aging of solubilized dialdehyde cellulose[J].Cellulose, 2017, 24(7):2 753-2 766.
[15] 李欢. 羧甲基纤维素复合薄膜的制备及其抗菌性能研究[D].西安:西安理工大学, 2020.
LI H.Study on preparation of carboxymethyl cellulose composite film and its antibacterial performance[D].Xi'an:Xi'an University of Technology, 2020.
[16] EL MIRI N, ABDELOUAHDI K, BARAKAT A, et al.Bio-nanocomposite films reinforced with cellulose nanocrystals:Rheology of film-forming solutions, transparency, water vapor barrier and tensile properties of films[J].Carbohydrate Polymers, 2015, 129:156-167.
[17] 叶佩尧, 余煌, 董存军, 等.纸浆的高碘酸钠选择性氧化及其性能研究[J].包装工程, 2018, 39(5):87-91.
YE P Y, YU H, DONG C J, et al.Selective oxidation of pulp with sodium periodate and its properties[J].Packaging Engineering, 2018, 39(5):87-91.
[18] ALMASI H, GHANBARZADEH B, ENTEZAMI A A.Physicochemical properties of starch-CMC-nanoclay biodegradable films[J].International Journal of Biological Macromolecules, 2010, 46(1):1-5.
[19] AZEREDO H M C, MATTOSO L H C, AVENA-BUSTILLOS R J, et al.Nanocellulose reinforced chitosan composite films as affected by nanofiller loading and plasticizer content[J].Journal of Food Science, 2010, 75(1):N1-N7.
[20] 康星雅, 贺艺美, 丁艳红, 等.纤维素纳米晶/羧甲基纤维素复合膜的制备及性能[J].纤维素科学与技术, 2020, 28(3):32-38.
KANG X Y, HE Y M, DING Y H, et al.Preparation and properties of cellulose nanocrystalline/carboxymethyl cellulose composite film[J].Journal of Cellulose Science and Technology, 2020, 28(3):32-38.
[21] 王锋棚. 可食性复合膜的制备及在包装中的应用[D].天津:天津科技大学, 2014.
WANG F P.The preparation and packaging application of edible composite films[D].Tianjin:Tianjin University of Science & Technology, 2014.
[22] 种晓, 雷桥, 郄梓含.静态超高压处理对抗菌复合蛋白薄膜的改性研究[J].食品工业科技, 2018, 39(22):50-55;62.
CHONG X, LEI Q, QIE Z H.Research on modification of antimicrobial composite protein films by static ultra-high pressure processing[J].Science and Technology of Food Industry, 2018, 39(22):50-55;62.
[23] 杜丹萌, 王风诺, 王世平.鸡蛋新鲜度随储藏条件变化规律的研究[J].食品科技, 2014, 39(5):26-29;33.
DU D M, WANG F N, WANG S P.The laws of the egg freshness change with storage conditions[J].Food Science and Technology, 2014, 39(5):26-29;33.
[24] 顾凤兰, 章建浩, 马磊, 等.不同涂膜材料对清洁鸡蛋的保鲜效果[J].农业工程学报, 2015, 31(1):303-310.
GU F L, ZHANG J H, MA L, et al.Fresh-keeping effect of different coating materials on clean egg[J].Transactions of the Chinese Society of Agricultural Engineering, 2015, 31(1):303-310.
[25] 戴赛男. 鸡蛋在不同贮藏温度下品质指标变化规律研究[D].长沙:湖南农业大学, 2017.
DAI S N.Study on the change rule of egg's physical and chemical indicators under different storage conditions[D].Changsha:Hunan Agricultural University, 2017.
[26] WARDY W, TORRICO D D, NO H K, et al.Edible coating affects physico-functional properties and shelf life of chicken eggs during refrigerated and room temperature storage[J].International Journal of Food Science & Technology, 2010, 45(12):2 659-2 668.
[27] 袁晓龙, 高婧娴, 杜颖, 等.气调储藏中不同平衡气体对鸡蛋保鲜品质的影响[J].食品工业科技, 2014, 35(2):300-303;307.
YUAN X L, GAO J X, DU Y, et al.Effect of the balance gas of modified atmosphere packaging on the shelf-life of eggs[J].Science and Technology of Food Industry, 2014, 35(2):300-303;307.
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