食品与发酵工业 >

2024 , Vol. 50 >Issue 15: 97 - 103

DOI: https://doi.org/10.13995/j.cnki.11-1802/ts.036757

研究报告

基于蓝莓花青素的新鲜度指示膜制备及性能研究

  • 陈赛艳 ,
  • 刘红林 ,
  • 汤俊炀 ,
  • 赵正禾 ,
  • 冀俊杰
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  • 1(四川农业大学 食品学院,四川 雅安,625014)
    2(山东技师学院 文化创意学院,山东 济南,250200)
第一作者：博士,讲师(通信作者,E-mail:ssdj1102@163.com)

收稿日期: 2023-07-12

  修回日期: 2023-08-24

  网络出版日期: 2024-08-21

基金资助

大学生创新创业训练计划项目(202310626025);四川省科技厅项目(2020YFN0147);四川省科技创新苗子工程资助项目(2021106)

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Preparation and study of freshness indicator film based on blueberry anthocyanins

  • CHEN Saiyan ,
  • LIU Honglin ,
  • TANG Junyang ,
  • ZHAO Zhenghe ,
  • JI Junjie
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  • 1(College of Food Science, Sichuan Agricultural University, Ya’an 625014, China)
    2(College of Culture and Creativity, Shandong Technician Institute, Jinan 250200, China)

Received date: 2023-07-12

  Revised date: 2023-08-24

  Online published: 2024-08-21

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摘要

为提升pH指示膜的综合性能,以微晶纤维素(micro-crystalline cellulose, MCC)、马铃薯淀粉(potato starch, PS)、聚乙烯醇(polyvinyl alcohol, PVA)为原料,蓝莓花青素(blueberry anthocyanins, BA)为指示剂,采用流延法制备指示膜,对指示膜的性能进行分析。结果表明,当BA、MCC、PS和PVA的质量比为0.3∶0.2∶3∶0.3时,微晶纤维素提高了薄膜的拉伸强度(1.59 MPa至2.16 MPa)、断裂伸长率(35.83%至38.24%)、杨氏模量(8.25 GPa至25.65 GPa),降低了薄膜的含水率(34.85%至33.23%)和吸水率(122.97%至110.36%)。蓝莓花青素提高了薄膜的机械性能、阻隔性能,降低了耐水性,且与膜中各基质融合良好,指示膜结构均匀、致密。拉伸强度和杨氏模量分别升至2.19 MPa和37.12 GPa;透水率、含水率和吸水率分别降至1.45×10-12 g·cm/(cm2·s·Pa)、30.7%和87.52%。蓝莓花青素还赋予薄膜pH敏感性。在不同pH环境中,指示膜与花青素的颜色变化趋势一致,色差可视;同时环境稳定性佳,在不同温度和光照条件下,指示膜的颜色稳定超过14 d(ΔE≤2)。研究结果可为蓝莓花青素指示膜的制备提供参考。

关键词： 指示膜; 蓝莓花青素; 微晶纤维素; 马铃薯淀粉; 聚乙烯醇

本文引用格式

陈赛艳 , 刘红林 , 汤俊炀 , 赵正禾 , 冀俊杰 . 基于蓝莓花青素的新鲜度指示膜制备及性能研究[J]. 食品与发酵工业, 2024 , 50(15) : 97 -103 . DOI: 10.13995/j.cnki.11-1802/ts.036757

Abstract

To improve the overall performance of the pH indicator film, pH indicator film was synthesized with micro-crystalline cellulose (MCC), potato starch (PS), and polyvinyl alcohol (PVA) as raw materials and blueberry anthocyanins (BA) as indicator through casting method and analyzed.Results showed that when the mass ratio of BA∶MCC∶PS∶PVA was 0.3∶0.2∶3∶0.3, the tensile strength (1.59 MPa to 2.16 MPa), elongation at break (35.83% to 38.24%), and Young’s modulus (8.25 GPa to 25.65 GPa) of the film were increased by incorporating MCC.The moisture content and water absorption decreased, from 34.85% to 33.23%, and from 122.97% to 110.36%, respectively.After adding BA, the mechanical properties and barrier properties were improved, and the water resistance was decreased.Also, the excellent compatibility of BA with each compound in the film resulted in a uniform film structure.Tensile strength and Young’s modulus increased to 2.19 MPa and 37.12 GPa, respectively.The water permeability, water content, and water absorption decreased to 1.45×10-12g·cm/(cm2·s·Pa), 30.7%, and 87.52%, respectively.The film was also endowed with pH sensitivity by BA.In different pH environments, the trend of color change of indicator film was consistent with anthocyanins, and the color difference was visible (ΔE>5).At the same time, the film had excellent environmental stability, the color of the film was stable for more than 14 days under different temperature and light conditions (ΔE≤2).The results can provide a reference for the preparation of indicator film based on blueberry anthocyanins.

Key words： indicator film; blueberry anthocyanins; micro-crystalline cellulose; potato starch; polyvinyl alcohol

参考文献

[1] SHILLINGFORD C, RUSSELL C W, BURGESS I B, et al.Bioinspired artificial melanosomes As colorimetric indicators of oxygen exposure[J].ACS Applied Materials & Interfaces, 2016, 8(7):4314-4317.
[2] 蒋光阳, 肖力源, 王章英, 等.不同基材复配紫薯花青素制备智能指示膜及其应用[J].食品科学, 2019, 40(13):267-273.
JIANG G Y, XIAO L Y, WANG Z Y, et al.Development and application of intelligent indicator films using blended film-forming solutions combined with purple sweet potato anthocyanins[J].Food Science, 2019, 40(13):267-273.
[3] 封晴霞, 王利强.蓝莓花青素智能指示膜的制备及应用[J].中国食品学报, 2022, 22(2):281-290.
FENG Q X, WANG L Q.Preparation and application of blueberry anthocyanin intelligent indicator films[J].Journal of Chinese Institute of Food Science and Technology, 2022, 22(2):281-290.
[4] 郭娜, 朱桂兰, 张方艳, 等.结冷胶-沙蒿胶-蓝莓花青素可食性膜的制备及其性能分析[J].食品与发酵工业, 2020, 46(1):172-176.
GUO N, ZHU G L, ZHANG F Y, et al.Preparation and characteristics analysis of gellan gum-Artemisia sphaerocephala Krasch gum-blueberry anthocyanin edible film[J].Food and Fermentation Industries, 2020, 46(1):172-176.
[5] LI Y, HU Z X, HUO R B, et al.Preparation of an indicator film based on pectin, sodium alginate, and xanthan gum containing blueberry anthocyanin extract and its application in blueberry freshness monitoring[J].Heliyon, 2023, 9(3):e14421.
[6] CHEN J, LONG Z, WANG J H, et al.Preparation and properties of microcrystalline cellulose/hydroxypropyl starch composite films[J].Cellulose, 2017, 24(10):4449-4459.
[7] 张静贤, 龙柱, 覃程荣, 等.微晶纤维素/明胶对淀粉复合薄膜性能影响研究[J].功能材料, 2022, 53(12):12170-12176.
ZHANG J X, LONG Z, QIN C R, et al.Effect of microcystalline cellulose/gelatin on the properties of starch composite films[J].Journal of Functional Materials, 2022, 53(12):12170-12176.
[8] 王盛, 杨超, 倪忠进, 等.MCC接枝PVA/可溶性淀粉保鲜膜的制备[J].林业工程学报, 2023, 8(3):105-113.
WANG S, YANG C, NI Z J, et al.Preparation of MCC grafted PVA/soluble starch cling film[J].Journal of Forestry Engineering, 2023, 8(3):105-113.
[9] 封晴霞. 蓝莓花青素智能标签的研制及其在鲜肉包装中的应用[D].无锡:江南大学, 2021.
FENG Q X.Development of blueberry anthocyan in intelligent label and its application in fresh meat packaging[D].Wuxi:Jiangnan University, 2021.
[10] NOSHIRVANI N, HONG W, GHANBARZADEH B, et al.Study of cellulose nanocrystal doped starch-polyvinyl alcohol bionanocomposite films[J].International Journal of Biological Macromolecules, 2018, 107(Pt B):2065-2074.
[11] 冉锐敏, 王璐瑶, 何宾宾, 等.纳米氧化锌/葡萄皮红改性大豆分离蛋白膜的制备与性能研究[J].农业工程学报, 2021, 37(14):294-301.
RAN R M, WANG L Y, HE B B, et al.Preparation and characterization of soy protein isolate films modified by ZnO nanoparticles and grape-skin red[J].Transactions of the Chinese Society of Agricultural Engineering, 2021, 37(14):294-301.
[12] JIA X W, QIN Z Y, XU J X, et al.Preparation and characterization of pea protein isolate-pullulan blend electrospun nanofiber films[J].International Journal of Biological Macromolecules, 2020, 157:641-647.
[13] KUREK M, GALUS S, DEBEAUFORT F.Surface, mechanical and barrier properties of bio-based composite films based on chitosan and whey protein[J].Food Packaging and Shelf Life, 2014, 1(1):56-67.
[14] FARAHNAKY A, DADFAR S M M, SHAHBAZI M.Physical and mechanical properties of gelatin-clay nanocomposite[J].Journal of Food Engineering, 2014, 122:78-83.
[15] 邹小波, 张俊俊, 石吉勇, 等.基于玫瑰茄花青素的猪肉新鲜度智能指示膜研究[J].食品科学, 2017, 38(23):243-248.
ZOU X B, ZHANG J J, SHI J Y, et al.Development of intelligent indicator films based on Roselle anthocyanins for monitoring pork freshness[J].Food Science, 2017, 38(23):243-248.
[16] 贾代涛, 卢立新, 潘嘹, 等.改性花青素涂覆聚丙烯新鲜度指示膜的制备与研究[J].功能材料, 2019, 50(6):6211-6215.
JIA D T, LU L X, PAN L, et al.Preparation and study of modified Roselle anthocyanin coated polypropylene freshness indicator film[J].Journal of Functional Materials, 2019, 50(6):6211-6215.
[17] PRIETTO L, MIRAPALHETE T C, PINTO V Z, et al.pH-sensitive films containing anthocyanins extracted from black bean seed coat and red cabbage[J].LWT, 2017, 80:492-500.
[18] AHMED J, HIREMATH N, JACOB H.Antimicrobial, rheological, and thermal properties of plasticized polylactide films incorporated with essential oils to inhibit Staphylococcus aureus and Campylobacter jejuni[J].Journal of Food Science, 2016, 81(2):E419-E429.
[19] 张静贤, 陆俊, 陈杰, 等.APTES改性微晶纤维素对淀粉复合薄膜性能影响[J].包装工程, 2022, 43(7):95-102.
ZHANG J X, LU J, CHEN J, et al.Effects of APTES modified microcrystalline cellulose on properties of starch composite film[J].Packaging Engineering, 2022, 43(7):95-102.
[20] 黄伟江, 吕广福, 韦龙杰, 等.PBAT/微晶纤维素复合材料的制备及性能研究[J].塑料科技, 2021, 49(9):12-16.
HUANG W J, LYU G F, WEI L J, et al.Study on preparation and properties of PBAT/microcrystalline cellulose composites[J].Plastics Science and Technology, 2021, 49(9):12-16.
[21] WEI Y C, CHENG C H, HO Y C, et al.Active gellan gum/purple sweet potato composite films capable of monitoring pH variations[J].Food Hydrocolloids, 2017, 69:491-502.
[22] 钟生缘, 杨序平.改性木质素/PBAT复合材料的制备及其性能[J].西南科技大学学报, 2019, 34(2):8-13.
ZHONG S Y, YANG X P.Study on properties of PBAT composite filled with modified lignin[J].Journal of Southwest University of Science and Technology, 2019, 34(2):8-13.
[23] LIANG T Q, SUN G H, CAO L L, et al.A pH and NH3 sensing intelligent film based on Artemisia sphaerocephala Krasch.gum and red cabbage anthocyanins anchored by carboxymethyl cellulose sodium added as a host complex[J].Food Hydrocolloids, 2019, 87:858-868.
[24] 陈杰, 汪磊, 龙柱, 等.微晶纤维素增强热塑性淀粉塑料薄膜的研究进展[J].塑料科技, 2023, 51(1):124-128.
CHEN J, WANG L, LONG Z, et al.Research progress of microcrystalline cellulose reinforced thermoplastic starch plastic films[J].Plastics Science and Technology, 2023, 51(1):124-128.
[25] 李田田, 李洋, 张茜, 等.基于淀粉/聚乙烯醇/花青素的色敏指示标签的研究[J].食品科技, 2019, 44(9):342-347.
LI T T, LI Y, ZHANG X, et al.Study on color-sensitive indicator label based on starch/polyvinyl alcohol/anthocyanin[J].Food Science and Technology, 2019, 44(9):342-347.
[26] 翟晓松, 秦洋, 陆慧玲, 等.高直链玉米淀粉/羟丙基甲基纤维素可食性膜的制备及性能研究[J].中国粮油学报, 2019, 34(7):33-38.
ZHAI X S, QIN Y, LU H L, et al.Preparation and properties of edible films of high-amylose corn starch/HPMC (hydroxypropyl methylcellulose)[J].Journal of the Chinese Cereals and Oils Association, 2019, 34(7):33-38.
[27] JANCIKOVA S, JAMRÓZ E, KULAWIK P, et al.Furcellaran/gelatin hydrolysate/rosemary extract composite films as active and intelligent packaging materials[J].International Journal of Biological Macromolecules, 2019, 131:19-28.
[28] SHANKAR S, WANG L F, RHIM J W.Incorporation of zinc oxide nanoparticles improved the mechanical, water vapor barrier, UV-light barrier, and antibacterial properties of PLA-based nanocomposite films[J].Materials Science and Engineering:C, 2018, 93:289-298.
[29] AZIZI-LALABADI M, ALIZADEH-SANI M, DIVBAND B, et al.Nanocomposite films consisting of functional nanoparticles (TiO2 and ZnO) embedded in 4A-Zeolite and mixed polymer matrices (gelatin and polyvinyl alcohol)[J].Food Research International, 2020, 137:109716.
[30] QIN Y, LIU Y P, YONG H M, et al.Preparation and characterization of active and intelligent packaging films based on cassava starch and anthocyanins from Lycium ruthenicum Murr[J].International Journal of Biological Macromolecules, 2019, 134:80-90.
[31] EZATI P, RHIM J W.pH-responsive chitosan-based film incorporated with alizarin for intelligent packaging applications[J].Food Hydrocolloids, 2020, 102:105629.
[32] 赵伟, 黄佳琪.干燥方式对蓝莓花青素降解特性及抗氧化能力的影响[J].食品与机械, 2023, 39(2):147-152.
ZHAO W, HUANG J Q.Effects of different drying methods on degradation characteristics of anthocyanins and antioxidant capacity in blueberries[J].Food & Machinery, 2023, 39(2):147-152.
[33] 刘军波, 邹礼根, 赵芸.蓝莓花青素加工环境稳定性研究[J].食品与生物技术学报, 2018, 37(10):1073-1079.
LIU J B, ZOU L G, ZHAO Y.Study on the stability of blueberry anthocyanin in processing environment[J].Journal of Food Science and Biotechnology, 2018, 37(10):1073-1079.
[34] PERON D V, FRAGA S, ANTELO F.Thermal degradation kinetics of anthocyanins extracted from juara (Euterpe edulis Martius) and “Italia” grapes (Vitis vinifera L.), and the effect of heating on the antioxidant capacity[J].Food Chemistry, 2017, 232:836-840.
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