樱桃番茄属于呼吸跃变型果蔬,采后易受乙烯影响加速果实的呼吸作用和后熟进程,严重缩短果实货架期。因此,开发可清除樱桃番茄采后环境中乙烯的包装材料,对于减少果实采后因乙烯催熟而引起的经济损失有重要的现实意义。该研究采用煅烧法制得一种在可见光照射条件下具有光催化活性的铁掺杂二氧化钛光催化剂(Fe-TiO2),与纯二氧化钛(TiO2)纳米颗粒相比,Fe-TiO2禁带宽度减小、光生电子-空穴对复合率降低,在LED灯光照条件下乙烯降解率大幅度提高。将其通过涂膜处理应用于樱桃番茄采后保鲜中,以果实表面色泽的变化判断其后熟进程,探究在LED灯光照条件下Fe-TiO2对樱桃番茄采后后熟的影响。结果表明,与对照组相比,LED灯光照下,Fe-TiO2负载于聚乙烯醇中的涂膜处理有效减缓樱桃番茄绿熟果实转红的速度,约推迟4 d,显著延缓果实采后后熟进程,初步展示光催化降解乙烯在果蔬采后保鲜上的应用前景。
[1] LI S, CHEN K S, GRIERSON D.Molecular and hormonal mechanisms regulating fleshy fruit ripening[J].Cells, 2021, 10(5):1136.
[2] 严涵, 郝全洋, 艾祥, 等.乙烯对果蔬成熟作用研究进展[J].中国果菜, 2020, 40(10):1-8.
YAN H, HAO Q Y, AI X, et al.Research progress of ethylene on mature of fruits and vegetables[J].China Fruit & Vegetable, 2020, 40(10):1-8.
[3] 朱孝扬, 李秋棉, 罗均, 等.粉蕉后熟过程中香气品质变化及其关键基因表达特性[J].食品科学, 2019, 40(17):96-103.
ZHU X Y, LI Q M, LUO J, et al.Evolution of aroma components and key gene expression during postharvest ripening of banana(Musa ABB pisang awak)[J].Food Science, 2019, 40(17):96-103.
[4] WEI H Y, SEIDI F, ZHANG T W, et al.Ethylene scavengers for the preservation of fruits and vegetables:A review[J].Food Chemistry, 2021, 337:127750.
[5] 王超, 杨子明, 何祖宇, 等.乙烯清除剂在果蔬保鲜中的研究进展[J].保鲜与加工, 2022, 22(9):82-88.
WANG C, YANG Z M, HE Z Y, et al.Research progress of ethylene scavengers for the preservation of fruits and vegetables[J].Storage and Process, 2022, 22(9):82-88.
[6] GAIKWAD K K, SINGH S, NEGI Y S.Ethylene scavengers for active packaging of fresh food produce[J].Environmental Chemistry Letters, 2020, 18(2):269-284.
[7] ZHANG C, LI Y, LI M Q, et al.Continuous photocatalysis via photo-charging and dark-discharging for sustainable environmental remediation:Performance, mechanism, and influencing factors[J].Journal of Hazardous Materials, 2021, 420:126607.
[8] 曹英寒, 武鹏程, 吴可量, 等.Co-CNNS/CdS/CoP复合催化剂的制备及光催化产氢性能研究[J].化学研究与应用, 2023, 35(5):1132-1138.
CAO Y H, WU P C, WU K L, et al.Preparation of Co-CNNS/CdS/CoP composite catalyst and photocatalytic performance for hydrogen production[J].Chemical Research and Application, 2023, 35(5):1132-1138.
[9] SHI Q L, YE J T.Deracemization enabled by visible-light photocatalysis[J].Angewandte Chemie (International Ed.in English), 2020, 59(13):4998-5001.
[10] ESTRADA-FLORES S, PÉREZ-BERUMEN C M, FLORES-GUIA T E, et al.Mechanosynthesis of mesoporous Bi-doped TiO2:The effect of bismuth doping and ball milling on the crystal structure, optical properties, and photocatalytic activity[J].Crystals, 2022, 12(12):1750.
[11] 王婷婷, 黄巧红, 林鑫鑫, 等.不同单次剂量中波紫外线照射对大鼠角膜的影响[J].中国医学物理学杂志, 2023, 40(4):473-479.
WANG T T, HUANG Q H, LIN X X, et al.Effects of different single doses of wltraviolet B on cornea of rats[J].Chinese Journal of Medical Physics, 2023, 40(4):473-479.
[12] XIANG Q S, FAN L M, ZHANG R, et al.Effect of UVC light-emitting diodes on apple juice:Inactivation of Zygosaccharomyces rouxii and determination of quality[J].Food Control, 2020, 111:107082.
[13] KODITHUWAKKU P, JAYASUNDARA D R, MUNAWEERA I, et al.A review on recent developments in structural modification of TiO2 for food packaging applications[J].Progress in Solid State Chemistry, 2022, 67:100369.
[14] MUGUNDAN S, PRAVEEN P, SRIDHAR S, et al.Sol-gel synthesized Barium doped TiO2 nanoparticles for solar photocatalytic application[J].Inorganic Chemistry Communications, 2022, 139:109340.
[15] WANG H D, WANG L, YE S Y, et al.Construction of Bi2WO6-TiO2/starch nanocomposite films for visible-light catalytic degradation of ethylene[J].Food Hydrocolloids, 2019, 88:92-100.
[16] CHENG L, QIU S F, CHEN J R, et al.A practical pathway for the preparation of Fe2O3 decorated TiO2 photocatalyst with enhanced visible-light photoactivity[J].Materials Chemistry and Physics, 2017, 190:53-61.
[17] SONG C Y.Enhancing photocatalytic degradation of hydrolyzed polyacrylamide in oilfield wastewater using BiVO4/TiO2 heterostructure nano-photocatalyst under visible light irradiation[J].International Journal of Electrochemical Science, 2023, 18(12):100363.
[18] LIU Z Y, ZHU J L, WEI P, et al.Candidate for magnetic doping agent and high-temperature thermoelectric performance enhancer:Hard magnetic M-type BaFe12O19 nanometer suspension[J].ACS Applied Materials & Interfaces, 2019, 11(49):45875-45884.
[19] RUZIMURADOV O, MUSAEV K, MAMATKULOV S, et al.Structural and optical properties of sol-gel synthesized TiO2 nanocrystals:Effect of Ni and Cr (co)doping[J].Optical Materials, 2023, 143:114203.
[20] 张敏, 郭晨晨, 王瑜, 等.金红石型纳米二氧化钛/聚二甲基硅氧烷复合改性制备多功能胶原海绵[J].高分子材料科学与工程, 2023, 39(2):26-35.
ZHANG M, GUO C C, WANG Y, et al.Preparation of multifunctional collagen sponge by composite modification of rutile-type titanium dioxide/polydimethylsiloxane[J].Polymer Materials Science & Engineering, 2023, 39(2):26-35.
[21] OVIEDO A M, TRUONG THI H, VAN Q C, et al.Physicochemical properties of Fe-doped TiO2 and the application in Dye-sensitized solar cells[J].Optical Materials, 2023, 137:113587.
[22] SUKHADEVE G K, BANDEWAR H, JANBANDHU S Y, et al.Photocatalytic hydrogen production, dye degradation, and antimicrobial activity by Ag-Fe Co-doped TiO2 nanoparticles[J].Journal of Molecular Liquids, 2023, 369:120948.
[23] 康晨, 吴珏, 姜安泽, 等.贮藏温度对 “黄妃” 樱桃番茄果实品质的影响[J].中国食品学报, 2023, 23(4):295-304.
KANG C, WU J, JIANG A Z, et al.The effects of storage temperature on the quality of ‘Huangfei' cherry tomato[J].Journal of Chinese Institute of Food Science and Technology, 2023, 23(4):295-304.