研究报告

湿热处理对木薯淀粉凝胶3D打印性能的影响

  • 徐静蕾 ,
  • 陈梦珂 ,
  • 温纪平 ,
  • 申玉翔 ,
  • 敖天芳
展开
  • (河南工业大学 粮油食品学院, 河南 郑州, 450001)
第一作者:硕士研究生(温纪平教授为通信作者,E-mail:wjp1380@163.com)

收稿日期: 2025-07-22

  修回日期: 2025-10-24

  网络出版日期: 2026-06-24

基金资助

“十四五”国家重点研发计划课题项目(2021YFD2100901)

Effect of moist heat treatment on 3D printing properties of cassava starch gel

  • XU Jinglei ,
  • CHEN Mengke ,
  • WEN Jiping ,
  • SHEN Yuxiang ,
  • AO Tianfang
Expand
  • (College of Food Science and Engineering, Henan University of Technology, Zhengzhou 450001, China)

Received date: 2025-07-22

  Revised date: 2025-10-24

  Online published: 2026-06-24

摘要

该研究以木薯淀粉为原料,采用不同水分含量(15%、20%、25%、30%)湿热处理对木薯淀粉进行物理改性,探究湿热处理对木薯淀粉凝胶品质特性和3D打印性能的影响。结果表明:湿热处理后木薯淀粉凝胶的储能模量(G′)和损耗模量(G″)增加,损耗因子(tanδ)减小,淀粉的凝胶强度增强,所有样品表现出弹性为主的凝胶特性,淀粉凝胶的稳定性提高,有利于保持3D打印产品的形状;淀粉凝胶体系的黏度、回生值、硬度、咀嚼性降低,黏度最高降低419 mPa·s,回生值最高降低了454 mPa·s;淀粉分子与羟基的结合能力增加,淀粉的持水性增加;孔径减小,多孔网状组织致密均匀,提高了淀粉凝胶维持形状的能力。当湿热处理水分含量为20%时,样品的G′和G″增加,打印样品表面纹理清晰,打印误差最小,凝胶体系的打印效果最佳。

本文引用格式

徐静蕾 , 陈梦珂 , 温纪平 , 申玉翔 , 敖天芳 . 湿热处理对木薯淀粉凝胶3D打印性能的影响[J]. 食品与发酵工业, 2026 , 52(11) : 205 -211 . DOI: 10.13995/j.cnki.11-1802/ts.044002

Abstract

This study used cassava starch as the raw material and modified it through wet heat treatment with different moisture contents (15%, 20%, 25%, and 30%).The effects of wet heat treatment on the gel properties and 3D printing performance of cassava starch were investigated.The results showed that after wet heat treatment, the storage modulus (G′) and loss modulus (G″) of cassava starch gels increased, while tanδ decreased.The gel strength of the starch was enhanced, and all samples exhibited gel characteristics dominated by elasticity, improving the stability of the starch gel and facilitating the maintenance of the shape of 3D printed products.The viscosity, retrogradation value, hardness, and chewiness of the starch gel system decreased, with the viscosity dropping by up to 419 mPa·s and the retrogradation value by up to 454 mPa·s.The binding ability of starch molecules with hydroxyl groups increased, and the water-holding capacity of the starch improved.The pore size decreased, and the porous network structure became denser and more uniform, enhancing the ability of the starch gel to maintain its shape.When the moisture content for wet heat treatment was 20%, the G′ and G″ of the samples increased, the surface texture of the printed samples was clear, and the printing error was the smallest, resulting in the best printing effect of the gel system.

参考文献

[1] RONG L Y, CHEN X X, SHEN M Y, et al.The application of 3D printing technology on starch-based product:A review[J].Trends in Food Science & Technology, 2023, 134:149-161.
[2] WICKRAMASINGHE S, MANALO A, ALAJARMEH O, et al.Advancing polymer composites in civil infrastructure through 3D printing[J].Automation in Construction, 2025, 177:106311.
[3] PASHA S, ONG J, GUO Y N, et al.Approaching ocular risks during spaceflight with 3D printing:Technical strategies to protect astronaut vision[J].Life Sciences in Space Research, 2025, 47:98-104.
[4] AMIRFATTAHI S, GHAZALI H S, HONARYAR H, et al.Application of lipid-stabilized liquid-liquid interfaces in 3D printing of biomaterials[J].Journal of Colloid and Interface Science, 2025, 699(Pt 2):138111.
[5] GODOI F C, PRAKASH S, BHANDARI B R.3 d printing technologies applied for food design:Status and prospects[J].Journal of Food Engineering, 2016, 179:44-54.
[6] ZHU F.Composition, structure, physicochemical properties, and modifications of cassava starch[J].Carbohydrate Polymers, 2015, 122:456-480.
[7] MANIGLIA B C, LIMA D C, MATTA M D Jr, et al.Hydrogels based on ozonated cassava starch:Effect of ozone processing and gelatinization conditions on enhancing 3D-printing applications[J].International Journal of Biological Macromolecules, 2019, 138:1087-1097.
[8] MALEKI S, AARABI A, FAR F A, et al.Heat moisture treatment and ultrasound-induced hydrothermal wheat starch modification:Techno-functional, microstructural and quality 3D printed characteristics[J].International Journal of Biological Macromolecules, 2024, 276:133992.
[9] ZHENG L Y, ZHANG Q R, YU X Z, et al.Effect of annealing and heat-moisture pretreatment on the quality of 3D-printed wheat starch gels[J].Innovative Food Science & Emerging Technologies, 2023, 84:103274.
[10] 陈梦珂, 温纪平, 徐静蕾, 等.湿热处理对甘薯淀粉理化结构及其凝胶3D打印性能的影响[J].食品与发酵工业, 2026, 52(2):108-116.
CHEN M K, WEN J P, XU J L, et al.Effects of moist heat treatment on physicochemical properties of sweet potato starch and its gel 3D printing performance[J].Food and Fermentation Industries, 2026, 52(2):108-116.
[11] 季圣阳. 3D打印用木薯淀粉复合凝胶体系的构建及其4D打印程序化变形研究[D].杭州:浙江大学, 2025.
JI S Y.Construction of cassava starch composite gel system for 3D printing and study on its programmed deformation for 4D printing[D].Hangzhou:Zhejiang University, 2025.
[12] JI S Y, XU T, LI Y, et al.Effect of starch molecular structure on precision and texture properties of 3D printed products[J].Food Hydrocolloids, 2022, 125:107387.
[13] 王宏伟, 丁江涛, 张艳艳, 等.湿热处理对薏米淀粉聚集态结构及糊化特性的影响[J].食品科学, 2020, 41(17):111-117.
WANG H W, DING J T, ZHANG Y Y, et al.Impact of heat moisture treatment on the aggregation structure and pasting behavior of adlay starch[J].Food Science, 2020, 41(17):111-117.
[14] SHI S Y, WEN J P, GENG H, et al.Physicochemical properties, structural properties and gels 3D printing properties of wheat starch[J].International Journal of Biological Macromolecules, 2024, 261(P2):129885.
[15] 王艳, 张煜松, 刘兴丽, 等.湿热处理对绿豆淀粉结构及理化特性的影响[J].轻工学报, 2022, 37(3):36-42.
WANG Y, ZHANG Y S, LIU X L, et al.Effect of heat moisture treatment on the structural and physicochemical properties of mung bean starch[J].Journal of Zhengzhou University of Light Industry (Natural Science Edition), 2022, 37(3):36-42.
[16] ZHAO Z L, WANG Q, YAN B W, et al.Synergistic effect of microwave 3D print and transglutaminase on the self-gelation of surimi during printing[J].Innovative Food Science & Emerging Technologies, 2021, 67:102546.
[17] CHEN L L, DAI Y Y, HOU H X, et al.Effect of high pressure microfluidization on the morphology, structure and rheology of sweet potato starch[J].Food Hydrocolloids, 2021, 115:106606.
[18] BATISTA A P, NUNES M C, RAYMUNDO A, et al.Microalgae biomass interaction in biopolymer gelled systems[J].Food Hydrocolloids, 2011, 25(4):817-825.
[19] YANG R Z, CHENG Z, ZHAO Y D, et al.Peanut oil body as a food-grade ink for 3D printing:Preparation, characterization and performance[J].Food Research International, 2025, 212:116486.
[20] BAI Y H, LI J R, LIU J, et al.Rapid synthesis and additive manufacturing of Y3Si2C2 ceramics:Ultrafast high-temperature sintering combined with direct ink writing[J].Journal of the European Ceramic Society, 2025, 45(15):117610.
[21] HAMAYUN M, AHMED E, WEDAMULLA N, et al.Next-gen nutrition:Challenges, innovations and opportunities in 3D food printing with probiotics[J].Future Foods, 2025, 11:100620.
[22] FANG Y, NI X X, GAO Y, et al.Optimizing 3D printing and post-processing with sustainable bio-based inks:A comparative study on formulations enriched with brewer’s spent grain protein, oleaginous yeast and soy protein isolate[J].International Journal of Biological Macromolecules, 2025, 315:144209.
[23] WU X L, WU X X, ZHANG X J, et al.Low digestibility characteristics of white kidney bean protein hydrolysate-corn starch complex:Structural and functional transformations induced by heat-moisture treatment[J].International Journal of Biological Macromolecules, 2025, 304:141051.
[24] 马丽苹, 焦昆鹏, 罗磊, 等.怀山药抗性淀粉理化性质及体外消化性研究[J].食品与机械, 2017, 33(11):41-46.
MA L P, JIAO K P, LUO L, et al.Study on physicochemical properties and digestibility of the resistant starch from Dioscorea opposite Thunb.cv.Huaiqing[J].Food & Machinery, 2017, 33(11):41-46.
[25] 宫冰. 反复/连续湿热处理对不同晶型淀粉结构和理化性质的影响机制[D].杨凌:西北农林科技大学, 2019.
GONG B.The effects of repeated/continuous heat-moisture treatments on structural and physicochemical properties of different crystal types of starches[D].Yangling:Northwest A&F University, 2019.
[26] FAN H Z, ZHANG M, LIU Z B, et al.Effect of microwave-salt synergetic pre-treatment on the 3D printing performance of SPI-strawberry ink system[J].LWT, 2020, 122:109004.
[27] LIN J R, LIANG C H, LIN T, et al.Optimizing 3D food printing inks:The impact of polysaccharides on camellia seed protein emulsion gels[J].Food Hydrocolloids, 2025, 166:111337.
[28] CHEN Y Y, ZHANG M, BHANDARI B.3D printing of steak-like foods based on textured soybean protein[J].Foods, 2021, 10(9):2011.
[29] KOTESWARA REDDY C, VIDYA P V, HARIPRIYA S.Effect of chemical modification on molecular structure and functional properties of musa AAB starch[J].International Journal of Biological Macromolecules, 2015, 81:1039-1045.
[30] 陈诚, 魏春菊, 陈艺芳, 等.湿热处理对杂粮淀粉消化特性的影响[J].食品与发酵工业, 2025, 51(17):280-288.
CHEN C, WEI C J, CHEN Y F, et al.Effects of heat-moisture treatment on the digestive properties of multigrain starch[J].Food and Fermentation Industries, 2025, 51(17):280-288.
文章导航

/

〈 〉