研究报告

聚乳酸-酪蛋白基复合膜性质及其在草莓保鲜中的应用

  • 梁慧光 ,
  • 甄晨波 ,
  • 杨敏 ,
  • 廖海周 ,
  • 柯发辉
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  • (甘肃农业大学 理学院,甘肃 兰州,730070)
第一作者:硕士,副教授(杨敏教授为通信作者,E-mail:yummy12@163.com)

收稿日期: 2023-06-17

  修回日期: 2023-10-28

  网络出版日期: 2024-10-14

基金资助

国家自然科学基金(32060549);甘肃省重点研发项目(23YFNA0017);甘肃农业大学伏羲杰出人才培育计划(Gaufx-02J02)

Properties of poly (lactic acid)-casein composite membrane and its application on strawberry preservation

  • LIANG Huiguang ,
  • ZHEN Chenbo ,
  • YANG Min ,
  • LIAO Haizhou ,
  • KE Fahui
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  • (College of Science, Gansu Agricultural University, Lanzhou 730070, China)

Received date: 2023-06-17

  Revised date: 2023-10-28

  Online published: 2024-10-14

摘要

以聚乳酸(poly lactic acid,PLA)、酪蛋白(casein,CN)为基质,利用静电纺丝技术制备了负载黄芩苷的复合膜,研究了CN和PLA不同配比下复合膜的微观结构、亲水性、降解性、溶胀性等,评价了复合膜包装对草莓果实硬度、可溶性固形物含量、失水率等指标的影响。结果显示,在PLA中添加CN后,复合膜纤维直径减小,成纤性能下降;当CN与PLA质量比为1∶1时,纤维直径均匀,成纤能力较好,为最佳配比。最佳条件下,复合膜的水接触角为(122.90±4.08) °,显著低于PLA膜;降解率为(45.31±3.35)%,显著高于PLA膜;吸水溶胀率约为150%,而PLA膜仅为(8.82±0.62)%。草莓保鲜试验表明,经复合膜包装后,草莓果实的硬度、可溶性固形物含量显著高于对照组。研究结果可为PLA、CN在果蔬保鲜材料制备中的应用提供参考依据。

本文引用格式

梁慧光 , 甄晨波 , 杨敏 , 廖海周 , 柯发辉 . 聚乳酸-酪蛋白基复合膜性质及其在草莓保鲜中的应用[J]. 食品与发酵工业, 2024 , 50(18) : 9 -15 . DOI: 10.13995/j.cnki.11-1802/ts.036500

Abstract

Poly (lactic acid) and casein (CN) were used to prepare composite membranes by using electrospinning technology to load baicalin.The microstructure, hydrophilicity, degradability, and swelling properties of composite membranes with different ratios of CN to PLA were analyzed.In addition, the composite membrane was used to package strawberries, the hardness, soluble solid content, and water loss rate of which during storage were measured.Results showed that the diameter of composite fiber decreased with the addition of CN in PLA, while its fiber-forming property deteriorated.However, when the mass ratio of CN to PLA was at 1∶1, the fiber-forming property of the mixture was excellent with the uniform diameter of composite fiber, which was the optimum ratio of composite membrane preparation based on CN and PLA.The water contact angle of the composite membrane at the optimum ratio was (122.90±4.08)°, which was lower than that of the PLA-based membrane significantly.The degradation rate of the optimum membrane was higher than that of the PLA-based membrane, which was (45.31±3.35)%.The water absorption of the optimum membrane was about 150%, which was (8.82±0.62)% for the PLA membrane.According to the results of strawberry preservation experiments, the samples packaged by composite membrane based on CN and PLA had higher hardness and soluble solid content than unpackaged strawberries.The results could provide references for the application of PLA and CN in packaging materials for fruit and vegetable preservation.

参考文献

[1] 苏代发, 童江云, 杨俊誉, 等.中国草莓属植物种质资源的研究、开发与利用进展[J].云南大学学报(自然科学版), 2018, 40(6):1261-1276.
SU D F, TONG J Y, YANG J Y, et al.Advances in research, exploitation and utilization of Fragaria spp. germplasm resources in China [J].Journal of Yunnan University (Natural Science Edition), 2018, 40(6):1261-1276.
[2] 钟秋夏, 郑海英, 朱燕丽, 等.百里香酚微胶囊的制备及其对草莓的保鲜效果[J].食品科学, 2023, 44(11):167-176.
ZHONG Q X, ZHENG H Y, ZHU Y L, et al.Preparation of thymol-containing microcapsules and its application in strawberry preservation [J].Food Science, 2023, 44(11):167-176.
[3] YANG J Y, LI M, ZHANG C L, et al.Pharmacological properties of baicalin on liver diseases:A narrative review[J].Pharmacological Reports, 2021, 73(5):1230-1239.
[4] 殷佳琦, 张晓虎, 高梦蝶.黄芩苷-姜辣素-海藻酸钠-蔗糖酯复合保鲜膜在鸡蛋保鲜中的应用[J].农学学报, 2020, 10(10):60-68.
YIN J Q, ZHANG X H, GAO M D.Application of baicalin-gingerol-sodium alginate-sucrose ester composite plastic film in egg preservation[J].Journal of Agriculture, 2020,10(10):60-68.
[5] 张晓虎, 白芳芳, 魏夏夏, 等.黄芩苷-Nisin复合保鲜液制备及在香蕉保鲜中的应用[J].陕西农业科学, 2020, 66(3):20-27.
ZHANG X H, BAI F F, WEI X X, et al.Preparation of baicalin-nisin composite fresh-keeping liquid and its application in banana preservation[J].Shaanxi Journal of Agricultural Sciences, 2020, 66(3):20-27.
[6] 魏夏夏, 张晓虎, 郑妍.低共熔溶剂提取黄芩苷及其复合保鲜液在鲜肉中的应用[J].中国农学通报, 2021, 37(13):127-134.
WEI X X, ZHANG X H, ZHENG Y.Application of eutectic solvent extraction of baicalin and its compound preservation solution in fresh meat[J].Chinese Agricultural Science Bulletin, 2021, 37(13):127-134.
[7] 陈婕, 梅林玉.聚乳酸/茶多酚复合包装膜的制备及性能[J].包装工程, 2021, 42(23):100-108.
CHEN J, MEI L Y.Preparation and properties of polylactic acid/tea polyphenol composite packaging film[J].Packaging Engineering, 2021, 42(23):100-108.
[8] HUANG H, SONG Y D, ZHANG Y Q, et al.Electrospun nanofibers:Current progress and applications in food systems[J].Journal of Agricultural and Food Chemistry, 2022, 70(5):1391-1409.
[9] HAN Y, JIA B, LIAN M F, et al.High-precision, gelatin-based, hybrid, bilayer scaffolds using melt electro-writing to repair cartilage injury [J].Bioactive Materials, 2021, 6(7):2173-2186.
[10] ZHANG L Y, HUANG C X, XU Y F, et al.Synthesis and characterization of antibacterial polylactic acid film incorporated with cinnamaldehyde inclusions for fruit packaging[J].International Journal of Biological Macromolecules, 2020, 164:4547-4555.
[11] YANG Y F, SHI Y Y, CAO X K, et al.Preparation and functional properties of poly(vinyl alcohol)/ethyl cellulose/tea polyphenol electrospun nanofibrous films for active packaging material[J].Food Control, 2021, 130:108331.
[12] 费燕娜, 潘宏, 李汶雨, 等.聚乳酸负载透明质酸复合电纺纤维膜的制备及性能[J].上海纺织科技, 2023, 51(3):27-30.
FEI Y N, PAN H, LI W Y, et al.Preparation of polylactic acid loaded hyaluronic acid composite electrospun fiber films and their properties[J].Shanghai Textile Science & Technology, 2023,51(3):27-30.
[13] 姚飞, 陈复生.花生分离蛋白-聚乳酸共混溶液性质及静电纺丝纳米纤维形貌的研究[J].河南工业大学学报(自然科学版), 2021, 42(2):50-55.
YAO F, CHEN F S.Study on properties of peanut protein isolate-polylactic acid blend solution and electrospun nanofiber morphology[J].Journal of Henan University of Technology(Natural Science Edition), 2021, 42(2):50-55.
[14] 刘晶晶, 张薇, 吴锦涛, 等.酪蛋白结构特性及应用研究进展[J].食品研究与开发, 2023, 44(1):197-201.
LIU J J, ZHANG W, WU J T, et al.Structural properties and application of casein:A review[J].Food Research and Development, 2023, 44(1):197-201.
[15] 甄晨波, 杨敏, 秦娟娟, 等.酪蛋白胶束/聚乳酸静电纺丝复合纤维膜性质及其对黄芩苷的负载性能研究[J].食品与发酵工业, 2024, 50(1):98-104.
ZHEN C B, YANG M, QIN J J, et al.Properties of casein micelle/poly (lactic acid) electrospinning composite fiber membrane and its loading capacity for baicalin[J].Food and Fermentation Industries, 2024, 50(1):98-104.
[16] GHORBANI M, MAHMOODZADEH F, YAVARI MAROUFI L, et al.Electrospun tetracycline hydrochloride loaded zein/gum tragacanth/poly lactic acid nanofibers for biomedical application[J].International Journal of Biological Macromolecules, 2020, 165:1312-1322.
[17] 张思远, 高晓平, 胡海娜, 等.酪蛋白/聚乙烯醇纳米纤维膜制备与性能研究[J].毛纺科技, 2022, 50(5):9-15.
ZHANG S Y, GAO X P, HU H N, et al.Research on the preparation and properties of casein /polyvinyl alcohol nanofiber membrane[J].Wool Textile Journal, 2022, 50(5):9-15.
[18] 安琪, 薛瑾, 李响, 等.共混聚乳酸对玉米醇溶蛋白基纤维膜的影响[J].粮食与油脂, 2023, 36(1):82-87.
AN Q, XUE J, LI X, et al.Effect of blended polylactide acid on Zein-based fiber membrane[J].Cereals & Oils, 2023, 36(1):82-87.
[19] ALTAN A, AYTAC Z, UYAR T.Carvacrol loaded electrospun fibrous films from zein and poly(lactic acid) for active food packaging[J].Food Hydrocolloids, 2018, 81:48-59.
[20] 崔心想, 王艳贺, 韩立彬, 等.聚乳酸/聚酯酰胺复合纳米纤维膜制备及性能[J].工程塑料应用, 2020, 48(3):14-21.
CUI X X, WANG Y H, HAN L B, et al.Preparation and properties of polylactic acid/polyesteramide composite nanofiber film[J].Engineering Plastics Application, 2020, 48(3):14-21.
[21] 王伟彬. 聚乳酸/壳聚糖-海藻酸复合纳米纤维膜材料的结构与性能研究[J].云南化工, 2020, 47(6):32-35.
WANG W B.Structure and properties of polylactic/chitosan-alginic composite nanofiber membrane[J].Yunnan Chemical Industry, 2020, 47(6):32-35.
[22] GONALVES R P, DA SILVA F F F, PICCIANI P H S, et al.Morphology and thermal properties of core-shell PVA/PLA ultrafine fibers produced by coaxial electrospinning[J].Materials Sciences and Applications, 2015, 6(2):189-199.
[23] MIN T T, SUN X L, YUAN Z P, et al.Novel antimicrobial packaging film based on porous poly(lactic acid) nanofiber and polymeric coating for humidity-controlled release of thyme essential oil[J].LWT-Food Science and Technology, 2021, 135:110034.
[24] LIU Y Y, DENG L L, ZHANG C, et al.Tunable physical properties of ethylcellulose/gelatin composite nanofibers by electrospinning[J].Journal of Agricultural and Food Chemistry, 2018, 66(8):1907-1915.
[25] 赵文哲, 陈修德, 邓文鹏, 等.外源硅处理对草莓果实果胶物质降解的影响[J].植物生理学报, 2021, 57(10):1926-1936.
ZHAO W Z, CHEN X D, DENG W P, et al.Effect of exogenous silicon treatment on pectin degradation of strawberry[J].Plant Physiology Journal, 2021, 57(10):1926-1936.
[26] 冯云霄, 程玉豆, 何近刚, 等.壳聚糖对草莓冷藏和货架期间品质的影响[J].保鲜与加工, 2015, 15(4):8-12.
FENG Y X, CHENG Y D, HE J G, et al.Effect of chitosan coating on the storage quality of strawberry during cold storage and shelf-life [J].Storage and Process, 2015, 15(4):8-12.
[27] 卢亚男, 赵美艳, 李立.聚乙烯抗菌膜的制备及其对草莓保鲜效果的研究[J].包装工程, 2023, 44(1):195-202.
LU Y N, ZHAO M Y, LI L.Preparation of antibacterial polyethylene films and their effect on strawberry preservation[J].Packaging Engineering, 2023, 44(1):195-202.
[28] 曹前荣, 孙建明, 李林林, 等.壳聚糖基涂膜技术在草莓贮藏保鲜中的应用[J].食品安全质量检测学报, 2023, 14(2):75-82.
CAO Q R, SUN J M, LI L L, et al.Application of chitosan-based coating technology in strawberry storage and preservation[J].Journal of Food Safety and Quality, 2023, 14(2):75-82.
[29] 王世芳, 韩平, 崔广禄, 等.SPXY 算法的西瓜可溶性固形物近红外光谱检测[J].光谱学与光谱分析, 2019, 39(3):738-742.
WANG S F, HAN P, CUI G L, et al.The NIR detection research of soluble solid content in watermelon based on SPXY algorithm[J].Spectroscopy and spectral analysis, 2019, 39(3):738-742.
[30] 蔡路昀, 吕艳芳, 李学鹏, 等.复合生物保鲜技术及其在生鲜食品中的应用研究进展[J].食品工业科技, 2014, 35(10):380-384.
CAI L Y, LYU Y F, LI X P, et al.Research progress in application of complex biological preservation technology in the fresh food[J].Science and Technology of Food Industry, 2014, 35(10):380-384.
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