分析与检测

多指标成分定量结合化学计量法综合评价新疆主要核桃仁品种品质及加工适宜性

  • 韩蓉 ,
  • 牛逍瞳 ,
  • 王莹 ,
  • 孟新涛 ,
  • 许铭强 ,
  • 张健 ,
  • 张婷 ,
  • 马燕
展开
  • (新疆维吾尔自治区农业科学院,农产品加工研究所,新疆 乌鲁木齐,830091)
第一作者:硕士研究生(马燕研究员为通信作者,E-mail:282568949@qq.com)

收稿日期: 2024-10-11

  修回日期: 2024-11-28

  网络出版日期: 2025-08-22

基金资助

国家重点研发计划项目(2022-YFD-1000104,2022-YFD-1000104-02);自治区科技成果转化示范专项—乡村振兴产业发展科技行动计划项目(2022-NC-032)

Comprehensive evaluation of quality and processing suitability of major walnut kernel varieties in Xinjiang by combining quantitative and chemometric methods with multi-indicator components

  • HAN Rong ,
  • NIU Xiaotong ,
  • WANG Ying ,
  • MENG Xintao ,
  • XU Mingqiang ,
  • ZHANG Jian ,
  • ZHANG Ting ,
  • MA Yan
Expand
  • (Xinjiang Uygur Autonomous Region Academy of Agricultural Sciences,Agricultural Products Processing Research Institute, Urumqi 830091, China)

Received date: 2024-10-11

  Revised date: 2024-11-28

  Online published: 2025-08-22

摘要

为探究新疆主要核桃仁品种的品质差异和加工适宜性,主要应用高效液相色谱-紫外检测法、气质联用色谱法、电感耦合等离子体质谱法和气相色谱-离子迁移谱法定量分析不同核桃仁品种的理化、营养成分及挥发性化合物等多维品质指标,并结合主成分分析、聚类分析和正交偏最小二乘判别分析等化学计量法识别不同核桃仁品种中的挥发性特征组分、综合评价其品质及加工适宜性。结果表明,不同核桃仁品种品质差异显著。其中‘温185'核桃仁的粗脂肪(63.90 g/100 g)和总膳食纤维(34.10 g/100 g)含量最高,适宜加工功能性油脂或高膳食纤维产品;‘温81'核桃仁的蛋白质(18.78 g/100 g)最高,可加工核桃蛋白饮品;‘新新2'核桃仁整体表现出较好的表观品质,适宜鲜食或加工即食休闲产品;‘新早丰'核桃仁总酚(0.25 g/100 g)和铁还原/抗氧化能力(2 311.62 μmol Trolox/mL)最高,‘新萃丰'核桃仁的总黄酮含量(0.55 g/100 g)和ABTS阳离子自由基清除率(78.77%)最高,均可鲜食或加工营养功能型产品。6个品种核桃仁中共鉴定出挥发性物质45种,其中‘扎343'核桃仁的挥发性物质含量较高,适宜作为风味食品加工辅料。‘扎343'核桃仁的综合得分最高(1.623分),适宜鲜食或全营养产品的综合开发。研究为发挥新疆核桃品种的资源优势,建立新疆不同核桃仁的优质营养组分及加工适宜评价体系,明确加工产品精准定位,提升核桃产品利用价值提供了一定的理论参考依据。

本文引用格式

韩蓉 , 牛逍瞳 , 王莹 , 孟新涛 , 许铭强 , 张健 , 张婷 , 马燕 . 多指标成分定量结合化学计量法综合评价新疆主要核桃仁品种品质及加工适宜性[J]. 食品与发酵工业, 2025 , 51(15) : 321 -331 . DOI: 10.13995/j.cnki.11-1802/ts.041270

Abstract

To investigate the quality differences and processing suitability of major walnut kernel varieties in Xinjiang, high-performance liquid chromatography-UV detection, gas chromatography inductively coupled plasma mass spectrometry, and gas chromatography-ion mobility spectroscopy were used to quantitatively analyze the physicochemical, nutrient and volatile compounds of different varieties of walnut kernels.Results showed that the quality of different walnut kernel varieties differed significantly.The crude fat (63.9 g/100 g) and total dietary fiber (34.10 g/100 g) contents of ‘Wen 185' walnut kernels were the highest, which were suitable for processing functional fats and oils or products high in dietary fiber, the protein (18.78 g/100 g) of ‘Wen 81' walnut kernels were the highest, which was suitable for processing walnut kernel protein products.‘XinXin2' walnut kernels showed overall better apparent quality, which was suitable for fresh or processing ready-to-eat recreational products.‘XinZhaoFeng' walnut kernels had the highest total phenol (0.25 g/100 g) and ferric reducing/antioxidant power (2 311.62 μmol Trolox/mL) were the highest, and the total flavonoid content (0.55 g/100 g) and ABTS cationic radical scavenging rate (78.77%) of ‘Xincui Feng' walnut kernel were the highest, which could be processed as eaten fresh or processed for nutritional functionality.45 kinds of volatile substances were identified in the six non-varieties of walnut kernels, among which ‘Zha 343' walnut kernels had a higher content of volatile substances, which was suitable for use as a flavor food processing auxiliary material.The ‘Zha 343' walnut kernel had the highest composite score (1.623), which was suitable for the comprehensive development of fresh food or whole-nutrition products.The study provides a certain theoretical reference basis for giving full play to the resource advantages of walnut varieties in Xinjiang, establishing a high-quality nutritional component and processing suitability evaluation system for different walnut kernels in Xinjiang, clarifying the precise positioning of processed products, and enhancing the utilization value of walnut products.

参考文献

[1] 李斌, 杨星宇, 刘向新, 等.核桃机械化收获装置研究现状与展望[J].中国农机化学报, 2024, 45(8):1-7;42.
LI B, YANG X Y, LIU X X, et al.Research status and prospect of mechanized harvesting device for walnut[J].Journal of Chinese Agricultural Mechanization, 2024, 45(8):1-7;42.
[2] 李源, 马文强, 朱占江, 等.新疆核桃产业发展现状及对策建议[J].农学学报, 2019, 9(7):80-86.
LI Y, MA W Q, ZHU Z J, et al.Xinjiang walnut industry:The development status and countermeasures[J].Journal of Agriculture, 2019, 9(7):80-86.
[3] 孟新涛, 许铭强, 张婷, 等.基于GC-IMS技术分析新疆不同品种核桃油挥发性物质的差异[J].中国油脂, 2025,50(3):102-109.
MENG X T, XU M Q, ZHANG T, et al.Differences of volatile components of different varieties of walnut oils in Xinjiang using gas chromatography-ion mobility spectrometry[J].China Oils and Fats, 2025,50(3):102-109.
[4] 张鹏, 杨旭昆, 米艳华, 等.云南不同品种核桃果实品质分析与综合评价[J].食品工业科技, 2024, 45(14):245-252.
ZHANG P, YANG X K, MI Y H, et al.Fruit quality analysis and comprehensive evaluation of different varieties walnuts and pecan in Yunnan[J].Science and Technology of Food Industry, 2024, 45(14):245-252.
[5] 金银春, 任波, 胡定林, 等.凉山州14个核桃品种主要经济指标及脂肪酸组成分析[J].中国油脂, 2025,50(1):135-140.
JIN Y C, REN B, HU D L, et al.Analysis of main economic indexes and fatty acid composition of 14 walnut cultivars in Liangshan Prefecture[J].China Fats and Oils, 2025,50(1):135-140.
[6] 宋岩, 王小红, 张锐, 等.新疆核桃仁品种间品质差异比较[J].中国粮油学报, 2019, 34(8):91-97.
SONG Y, WANG X H, ZHANG R, et al.Comparison of quality differences among varieties of walnut from Xinjiang[J].Journal of the Chinese Cereals and Oils Association, 2019, 34(8):91-97.
[7] 孙翠, 李永涛, 王明林, 等.核桃仁维生素E含量分析研究[J].中国粮油学报, 2011, 26(6):45-51.
SUN C, LI Y T, WANG M L, et al.The analysis for tocopherol content of kernel in juglans[J].Journal of the Chinese Cereals and Oils Association, 2011, 26(6):45-51.
[8] 赵鑫丹. 核桃仁内种皮抗氧化成分的提取分离及其活性研究[D].杨凌:西北农林科技大学, 2021.
ZHAN X D.Extraction and isolation of antioxidant components of walnut endocarp and their activity[D].Yangling:Northwest A&F University, 2021.
[9] 杨旭昆, 汪禄祥, 叶艳萍, 等.7种云南产核桃中17种氨基酸含量测定与必需氨基酸模式分析[J].食品安全质量检测学报, 2020, 11(6):1889-1894.
YANG X K, WANG L X, YE Y P, et al.Quantitative determination of 17 kinds of amino acids and pattern analysis of essential amino acids in 7 local walnut varieties in Yunnan province[J].Journal of Food Safety & Quality, 2020, 11(6):1889-1894.
[10] 中国林业科学研究院林业研究所, 国家林业和草原局造林绿化管理司, 国家林业和草原局国有林场和林木种苗工作总站, 等.核桃 第8部分:核桃坚果质量及检测[M].北京:国家林业和草原局,2018:12.
Institute of Forestry, China Academy of Forestry Sciences, Department of Afforestation and Greening Management, State Forestry and Grassland Administration, State Forestry and Grassland Administration State Forestry and Forest Tree Seedling Workstation, et al.Walnut Part 8:Quality and Testing of Walnut Nuts[M].Beijing:State Forestry and Grassland Administration,2018:12.
[11] SHIRMOHAMMADI M, CHARRAULT E, BLENCOWE A.Micromechanical properties of almond kernels with various moisture content levels[J].International Journal of Food Properties, 2018, 21(1):1820-1832.
[12] 邓加林, 潘庆牧, 刘安萱.国内16个核桃品种主要营养成分特性研究[J].食品与发酵科技, 2023, 59(3):111-115.
DENG J L, PAN Q M, LIU A X.Analysis on nutritional composition of 16 domestic walnut varieties[J].Food and Fermentation Science & Technology, 2023, 59(3):111-115.
[13] RODRÍGUEZ G, SQUEO G, ESTIVI L, et al.Changes in stability, tocopherols, fatty acids and antioxidant capacity of Sacha inchi (Plukenetia volubilis) oil during French fries deep-frying[J].Food Chemistry, 2021, 340:127942.
[14] PYCIA K, KAPUSTA I, JAWORSKA G, et al.Antioxidant properties, profile of polyphenolic compounds and tocopherol content in various walnut (Juglans regia L.) varieties[J].European Food Research and Technology, 2019, 245(3):607-616.
[15] BOU ABDALLAH I, TLILI N, MARTINEZ-FORCE E, et al.Content of carotenoids, tocopherols, sterols, triterpenic and aliphatic alcohols, and volatile compounds in six walnuts (Juglans regia L.) varieties[J].Food Chemistry, 2015, 173:972-978.
[16] RAI S, KUREEL A K, DUTTA P K, et al.Phenolic compounds based conjugates from dextran aldehyde and BSA:Preparation, characterization and evaluation of their anti-cancer efficacy for therapeutic applications[J].International Journal of Biological Macromolecules, 2018, 110:425-436.
[17] 周高兴, 伊再提古丽·加帕尔, 李欣, 等.新疆核桃与域外核桃品种果实总多酚差异分析[J].北方园艺, 2023(22):31-37.
ZHOU G X, IZAITIGULI G P R, LI X, et al.Analysis of fruit total polyphenol differences between Xinjiang walnut and extra-territorial walnut varieties[J].Northern Horticulture, 2023(22):31-37.
[18] JIA X D, LUO H T, XU M Y, et al.Dynamic changes in phenolics and antioxidant capacity during pecan (Carya illinoinensis) kernel ripening and its phenolics profiles[J].Molecules, 2018, 23(2):435.
[19] 王亚萍, 姚小华, 曹永庆, 等.6种植物油料油脂的品质及氧化稳定性研究[J].中国油脂, 2024, 49(9):50-58;65.
WANG Y P, YAO X H, CAO Y Q, et al.Quality and oxidation stability of the oils from six vegetable oilseeds[J].China Oils and Fats, 2024, 49(9):50-58;65.
[20] SENA-MORENO E, PARDO J E, PARDO-GIMÉNEZ A, et al.Differences in oils from nuts extracted by means of two pressure systems[J].International Journal of Food Properties, 2016, 19(12):2750-2760.
[21] WOOD L G, GARG M L.Macadamia Nuts (Macadamia integrifolia and tetraphylla) and Their Use in Hypercholesterolemic Subjects[M].Nuts and Seeds in Health and Disease Prevention.Amsterdam:Elsevier, 2011:717-725.
[22] CHEN J, LIU Y, YANG M, et al.Analysis of the differences in volatile organic compounds in different rice varieties based on GC-IMS technology combined with multivariate statistical modelling[J].Molecules, 2023, 28(22):7566.
[23] AQUINO-BOLAÑOS E N, MAPEL-VELAZCO L, MARTÍN-DEL-CAMPO S T, et al.Fatty acids profile of oil from nine varieties of macadamia nut[J].International Journal of Food Properties, 2017, 20(6):1262-1269.
[24] MAO X Y, HUA Y F, CHEN G G.Amino acid composition, molecular weight distribution and gel electrophoresis of walnut (Juglans regia L.) proteins and protein fractionations[J].International Journal of Molecular Sciences, 2014, 15(2):2003-2014.
[25] LI F N, YIN Y L, TAN B, et al.Leucine nutrition in animals and humans:MTOR signaling and beyond[J].Amino Acids, 2011, 41(5):1185-1193.
[26] ANTORA S A, HO K V, LIN C H, et al.Quantification of vitamins, minerals, and amino acids in black walnut (Juglans nigra)[J].Frontiers in Nutrition, 2022, 9:936189.
[27] WOŃNIAK M, WAŚKIEWICZ A, RATAJCZAK I.The content of phenolic compounds and mineral elements in edible nuts[J].Molecules, 2022, 27(14):4326.
[28] FUKASAWA R, MIYAZAWA T, ABE C, et al.Quantification and comparison of nutritional components in oni walnut (Juglans ailanthifolia Carr.), Hime walnut (Juglans subcordiformis Dode.), and cultivars[J].Horticulturae, 2023, 9(11):1221.
[29] WANG D, ZHANG J, ZHU Z S, et al.Effect of ageing time on the flavour compounds in Nanjing water-boiled salted duck detected by HS-GC-IMS[J].LWT, 2022, 155:112870.
[30] HU D H, WANG Y L, KONG F S, et al.Analysis of volatile aroma components in different parts of shiitake mushroom (Lentinus edodes) treated with ultraviolet C light-emitting diodes based on gas chromatography-ion mobility spectroscopy[J].Molecules, 2024, 29(8):1872.
[31] ROBERTO THEWES F, BOTH V, BRACKMANN A, et al.Dynamic and static drying temperatures for ‘Barton' pecans:Impacts on the volatile compounds profile and kernel color[J].LWT, 2022, 161:113393.
[32] 赵竞伊, 张鹏, 曹森, 等.不同品种番茄采后品质和挥发性物质差异分析[J].食品工业科技, 2024, 45(15):274-282.
ZHAO J Y, ZHANG P, CAO S, et al.Analysis of postharvest quality and volatile substances of different tomato varieties[J].Science and Technology of Food Industry, 2024, 45(15):274-282.
[33] HUANG X W, ZHAO L H, PANG S, et al.Effects of varieties, cultivation methods, and origins of Citrus sinensis ‘Hongjiang' on volatile organic compounds:HS-SPME-GC/MS analysis coupled with OPLS-DA[J].Agriculture, 2022, 12(10):1725.
[34] 李欢康, 杨佳玮, 刘文玉, 等.不同工艺核桃油挥发性物质比对及关键香气成分表征[J].食品科学, 2021, 42(16):185-192.
LI H K, YANG J W, LIU W Y, et al.Comparison of volatile components and characterization of key aroma components of walnut oil produced by different processes[J].Food Science, 2021, 42(16):185-192.
[35] HAO J, XU X L, JIN F, et al.HS-SPME GC-MS characterization of volatiles in processed walnuts and their oxidative stability[J].Journal of Food Science and Technology, 2020, 57(7):2693-2704.
[36] MUKWEVHO P L, KASEKE T, FAWOLE O A.Optimisation using response surface methodology of quality, nutritional and antioxidant attributes of ‘Wichita' pecan nuts roasted by microwaves[J].Processes, 2023, 11(8):2503.
[37] LIANG X H, DENG G M, YAN B.Fruit and vegetable nutrition value assessment and replacement based on the principal component analysis and cluster analysis[J].Applied Mathematics, 2015, 6(9):1620-1629.
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