分析与检测

基于香气活性值及感官属性对金银花尾酒酿造风味食醋特征的分析

  • 孙优兰 ,
  • 黄永光 ,
  • 唐东亚 ,
  • 吴兴琴
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  • 1贵州大学 酿酒与食品工程学院,贵州 贵阳,550025
    2贵州花酒酒业有限公司,贵州 镇远,557700
硕士研究生(黄永光研究员为通讯作者,E-mail:772566120@qq.com)。

网络出版日期: 2019-09-03

基金资助

贵州省科技支撑计划项目(黔科合支撑[2017]2542);贵州省重点基金项目(黔科合基础[2017]1405);贵州省科技平台及人才团队计划项目(黔科合平台人才[2016]5637)

Analysis offlavor characteristics of vinegar brewed by honeysuckle tail liquor based on odor activity value and sensory attributes

  • SUN Youlan ,
  • HUANG Yongguang ,
  • TANG Dongya ,
  • WU Xingqin
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  • 1College of Brewery and Food Engineering, Guizhou University, Guiyang 550025, China
    2Guizhou Huajiu Co. Ltd., Zhenyuan 557700, China

Online published: 2019-09-03

摘要

以金银花尾酒为主要原料,经醋酸发酵酿造特色金银花风味食醋。应用顶空固相微萃取结合气相色谱质谱联用,分析风味食醋中的挥发性风味物质,利用香气活性值探讨风味食醋的关键风味物质,通过化学检测结合感官定量,比较分析风味食醋与品牌醋的香气结构差异性。结果表明,从风味食醋中定性定量出主要挥发性风味物质62种,其中萜烯类物质是风味食醋中特有的一类物质;分析确定了风味食醋中关键风味化合物15种;与3种品牌醋相比,风味食醋中的特征风味物质有28种,含量较高的为芳樟醇、对乙基愈创木酚和α-松油醇,经感官分析发现,花香、青香和木香是风味食醋的主要特征香气。该研究为金银花尾酒资源化利用提供理论依据,同时为食醋风味研究提供技术支持。

本文引用格式

孙优兰 , 黄永光 , 唐东亚 , 吴兴琴 . 基于香气活性值及感官属性对金银花尾酒酿造风味食醋特征的分析[J]. 食品与发酵工业, 2019 , 45(15) : 233 -242 . DOI: 10.13995/j.cnki.11-1802/ts.021126

Abstract

This study aimed to investigate the components of the honeysuckle flavored vinegar, which is brewed by acetic acid fermentation with honeysuckle tail liquor. The volatile aroma compounds were analyzed by headspace solid phase microextraction and gas chromatography-mass spectrometry; And the key flavor substances of the flavored vinegar were investigated by the odor activity value; the differences between the flavored vinegar and the brand vinegar were analyzed by chemical analysis and sensory quantitative assessment. The results showed that 62 volatile flavor components were identified from the flavored vinegar, of which the terpenes were the unique substances in the flavored vinegar; 15 kinds key flavor substances identified by analysis from the flavored vinegar. Compared with the other three brands of vinegar, the flavored vinegar contained 28 kinds of compounds specially, of which the linalool, p-ethyl guaiacol and α-terpineol were the three most compounds. Sensory analysis indicated that the main aroma characteristics of the flavored vinegar included floral, green and woody. This study provides a theoretical basis for the resource utilization of honeysuckle tail wine, and provides technical support for the research of vinegar flavor.

参考文献

[1] 陈小林, 明聃. 浓香尾酒回收工艺的分析改进和综合应用探讨[J]. 酿酒科技, 2015(5): 98-100.
[2] 李跃, 姚元滋,徐效勇,等. 白酒发酵副产物对白酒调味的应用[J]. 酿酒科技, 2017(8): 121-123.
[3] 尹礼国, 容星,冯学愚,等. 气相色谱质谱联用内标法分析五粮浓香型大曲酒尾微量成分[J]. 酿酒科技, 2013(9): 96-98.
[4] 朱奇, 石海英,陈彦,等. 利用酒头、酒尾研制啤酒营养白醋[J]. 酿酒科技, 2004(1): 63-64.
[5] 廖湘萍, 易华蓉,王久增,等. 利用大曲酒尾、酒糟发酵生产食醋的研究[J]. 中国酿造, 2007(6): 56-58.
[6] ZHU Hong, ZHU Jie, WANG Lili, et al. Development of a SPME-GC-MS method for the determination of volatile compounds in Shanxi aged vinegar and its analytical characterization by aroma wheel[J]. Journal of Food Science and Technology, 2016, 53(1): 171-183.
[7] ZHANG Xin, WANG Peng, XU Dandan, et al. Aroma patterns of Beijing rice vinegar and their potential biomarker for traditional Chinese cereal vinegars[J]. Food Research International, 2019, 119(5): 398-410.
[8] ZHAO Dongrui, SHI Dongmei, SUN Jinyuan, et al. Characterization of key aroma compounds in Gujinggong Chinese Baijiu by gas chromatography-olfactometry, quantitative measurements, and sensory evaluation[J]. Food Research International, 2018, 105(5): 616-627.
[9] SHA Sha, CHEN Shuang, MICHAEL Qian, et al. Characterization of the typical potent odorants in Chinese roasted sesame-like flavor type liquor by headspace solid phase microextraction-aroma extract dilution analysis, with special emphasis on sulfur-containing odorants[J]. Journal of Agricultural and Food Chemistry, 2017, 65(1): 123-131.
[10] 秦伟军. 食醋感官特性及提升技术综述[J]. 中国调味品, 2018, 43(5): 200-206.
[11] HAUSCH B J, LORJAROENPHON Y, CADWALLADER K R. Flavor chemistry of lemon-lime carbonated beverages[J]. Journal of Agricultural and Food Chemistry, 2015, 63(1): 112-119.
[12] 黄丹, 刘有晴,倪月,等. 基于ROAV值的四川麸醋主体风味物质研究[J]. 食品工业, 2016,37(9): 288-292.
[13] 郑翠银,黄志清,刘志彬,等. 定量描述分析法感官评定红曲黄酒[J]. 中国食品学报, 2015,15(1): 205-213.
[14] 袁源, 范文来,徐岩. 液液萃取结合GC-O和GC-MS解析镇江香醋香气成分[J]. 食品与发酵工业,2018,44(7): 238-242.
[15] 范海燕, 范文来,徐岩. 应用GC-O和GC-MS研究豉香型白酒挥发性香气成分[J]. 食品与发酵工业, 2015,41(4): 147-152.
[16] 唐柯, 王茜,徐岩,等. 石榴酒发酵过程中香气动态变化规律[J]. 食品与发酵工业, 2019, 45(6): 197-202;214.
[17] ZHENG Jia, ZHAO Dong, PENG Zhifu, et al. Variation of aroma profile in fermentation process of Wuliangye, baobaoqu, starter[J]. Food Research International, 2018, 114(12): 64-71.
[18] LIANG Jingjing, XIE Jianchun, HOU Li, et al. Aroma Constituents in Shanxi Aged Vinegar before and after Aging[J]. Journal of Agricultural and Food Chemistry, 2016, 64(40): 1-34.
[19] ACENA Laura, VERA Luciano, GUASCH Josep, et al. Chemical Characterization of Commercial Sherry Vinegar Aroma by Headspace Solid-Phase Microextraction and Gas Chromatography-Olfactometry[J]. Journal of Agricultural and Food Chemistry, 2011, 59(8):4 062-4 070.
[20] 马宇, 黄永光,唐东亚,等. 金银花纯花固态发酵酒风味特征及活性功能成分分析[J]. 食品科学, 2018, 39(24): 249-255.
[21] 孙宝国, 陈海涛. 食用调香术[M]. 北京:化学工业出版社, 2015.
[22] 冯涛, 赵宇,张治文,等. L-阿拉伯糖与氨基酸美拉德反应挥发性风味物质分析与机理研究[J]. 食品科学, 2019,40(8): 213-217.
[23] RAQUEL M, CALLEJ N, LOURDES M, et al. Defining the typical aroma of sherry vinegar: sensory and chemical approach[J]. Journal of Agricultural and Food Chemistry, 2008, 56(17): 8 086-8 095.
[24] KHAIRALLAH R, ANDREW G R, AMY J B. Harvest date effects on aroma compounds in aged Riesling icewines[J]. Journal of the Science of Food & Agriculture, 2016, 96(13): 4 398-4 090.
[25] SHI Jiyong, ZOU Xiaobo, Huang Xiaowei, et al. Rapid detecting total acid content and classifying different types of vinegar based on near infrared spectroscopy and least-squares support vector machine[J]. Food Chemistry, 2013, 138(1): 192-199.
[26] WANG Zongmin, LU Zhenming, SHI Jinsong, et al. Exploring favour-producing core microbiota in multispecies solid-state fermentation of traditional Chinese vinegar[J]. Scientific Reports, 2016, 6(1): 1-10.
[27] MARRUFO-CURTIDO, CEJUDO-BASTANTE M J,DUR N-GUERRERO E, et al. Characterization and differentiation of high quality vinegars by stir bar sorptive extraction coupled to gas chromatography-mass spectrometry (SBSE-GC-MS)[J]. LWT - Food Science and Technology,2012, 47(2): 332-341.
[28] 孙宗保. 镇江香醋挥发性成分分析及醋龄的识别研究[D]. 江苏:江苏大学, 2014.
[29] WU Linhuan, LU Zhenming. ZHANG Xiaojuan et al. Metagenomics reveals favour metabolic network of cereal vinegar microbiota[J]. Food Microbiol,2016, 62(4): 23-31.
[30] 李沙. 传统岐山醋醋酸固态发酵过程中细菌群落动态演变与风味物质形成规律的研究[D]. 广州:华南理工大学, 2016.
[31] ZHU Yunping, ZHANG Feifei, ZHANG Chengnan, et al. Dynamic microbial succession of Shanxi aged vinegar and its correlation with flavor metabolites during different stages of acetic acid fermentation[J]. Scientific Reports, 2018, 8(1): 8 612.
[32] LUO Tao, FAN Wenlai, XU Yan. Characterization of volatile and semi-volatile compounds in Chinese rice wines by headspace solid phase microextraction followed by gas chromatography-mass spectrometry.[J]. Journal of the Institute of Brewing. 2008, 114(2): 172-179.
[33] 孙宗保, 尹俊玲,赵杰文,等. 杂环化合物在镇江香醋陈酿过程中的变化[J]. 中国食品学报, 2015, 15(6): 199-205.
[34] 蒋雅君, 张翀,吕旭聪,等. 固相微萃取条件优化及福建红曲醋特征挥发性风味物质分析[J]. 现代食品科技, 2019, 35(3): 154-160.
[35] XU Wei, XU Qingping, CHEN Jinghua, et al. Ligustrazine formation in Zhenjiang aromatic vinegar: changes during fermentation and storing process[J]. Journal of the Science of Food and Agriculture, 2011, 91(9): 1 612-1 617.
[36] FAN Wenlai, QIAN Michael C. Characterization of aroma compounds of Chinese “Wuliangye” and “Jiannanchun” liquors by aroma extract dilution analysis[J]. Journal of Agricultural & Food Chemistry, 2006,54(7): 2 695-2 704.
[37] 孙宗保, 邹小波,赵杰文. 几种中国传统名醋挥发性风味成分的比较研究[J]. 中国调味品, 2010, 35(9):34-37.
[38] 吕世明, 陈杖榴,陈建新,等. 丁香酚体外抑菌作用研究[J]. 食品科学, 2008, 29(9): 122-124.
[39] 史冬梅, 王松,赵东瑞,等. GC-MS/SIM法检测 103 种白酒中 6种酚类化合物[J]. 中国食品学报, 2019, 19(4): 235-248.
[40] 宗朕, 程磊,陈卓静,等. 食品用萜类化合物的生物合成研究进展[J]. 中国酿造, 2018, 37(9): 22-27.
[41] 李弘文, 王旭苹,杨小兰. 不同熏醅工艺对山西老陈醋香气成分的影响[J]. 食品科学, 2015, 36(20): 90-94.
[42] 朱宏. 山西老陈醋挥发性成分和流变性质的研究[D]. 北京:中国农业大学, 2016.
[43] WANG Aili, SONG Huanlu, RRN Changzhong, et al. Key aroma compounds in Shanxi aged tartary buckwheat vinegar and changes during its thermal processing[J]. Flavour And Fragrance Journal, 2012, 27: 47-53.
[44] 周钰欣, 张建新,许彦腾.5种固态发酵食醋香味物质的GC-MS分析[J].西北农业学报, 2014, 23(2):143-149.
[45] 许女, 张天震,樊玮鑫,等. 山西老陈醋酿造过程中香气成分的动态变化[J]. 中国食品学报, 2018, 18(11): 198-210.
[46] 刘超. 优质食醋发酵过程中的风味及安全性研究[D]. 天津:天津科技大学, 2012.
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